Modelling river water temperature using deterministic,empirical, and hybrid formulations in a Mediterranean stream

River water temperature is a common target of water quality models at the watershed scale, owing to its principal role in shaping biogeochemical processes and in stream ecology. Usually, models include physically‐based, deterministic formulations to calculate water temperatures from detailed meteorological information, which usually comes from meteorological stations located far from the river reaches. However, alternative empirical approaches have been proposed, that usually depend on air temperature as master variable. This study explored the performance of a semidistributed water quality application modelling river water temperature in a Mediterranean watershed, using three different approaches. First, a deterministic approach was used accounting for the different heat exchange components usually considered in water temperature models. Second, an empirical approximation was applied using the equilibrium temperature concept, assuming a linear relationship with air temperature. And third, a hybrid approach was constructed, in which the temperature equilibrium concept and the deterministic approach were combined. Results showed that the hybrid approach gave the best results, followed by the empirical approximation. The deterministic formulation gave the worst results. The hybrid approach not only fitted daily river water temperatures, but also adequately modelled the daily temperature range (maximum–minimum daily temperature). Other river water features directly dependent on water temperature, such as river intrusion depth in lentic systems (i.e. the depth at which the river inflow plunges to equilibrate density differences with lake water), were also correctly modelled even at hourly time steps. However, results for the different heat fluxes between river and atmosphere were very unrealistic. Although direct evidence of discrepancies between meteorological drivers measured at the meteorological stations and the actual river microclimate was not found, the use of models including empirical or hybrid formulations depending mainly on air temperature is recommended if only meteorological data from locations far from the river reaches are available. Copyright © 2008 John Wiley & Sons, Ltd.     

A microscale three-dimensional urban energy balance model for studying surface temperatures

A microscale three-dimensional (3-D) urban energy balance model, Temperatures of Urban Facets in 3-D (TUF-3D), is developed to predict urban surface temperatures for a variety of surface geometries and properties, weather conditions, and solar angles. The surface is composed of plane-parallel facets: roofs, walls, and streets, which are further sub-divided into identical square patches, resulting in a 3-D raster-type model geometry. The model code is structured into radiation, conduction and convection sub-models. The radiation sub-model uses the radiosity approach and accounts for multiple reflections and shading of direct solar radiation. Conduction is solved by finite differencing of the heat conduction equation, and convection is modelled by empirically relating patch heat transfer coefficients to the momentum forcing and the building morphology. The radiation and conduction sub-models are tested individually against measurements, and the complete model is tested against full-scale urban surface temperature and energy balance observations. Modelled surface temperatures perform well at both the facet-average and the sub-facet scales given the precision of the observations and the uncertainties in the model inputs. The model has several potential applications, such as the calculation of radiative loads, and the investigation of effective thermal anisotropy (when combined with a sensor-view model).     

MAPGIS和AtuoCAD间的数据转换问题

简要介绍了MAPGIS和AutoCAD的基本特点,详细分析了两者数据特点和数据转换过程中要注意的问题,重点阐述了AutoCAD的DXF和DWG两种数据格式与MAPGIS的MPJ数据格式之间转换的实现过程与方法,最后总结了对AutoCAD数据和其他GIS软件间的数据转换的参考意义,从而达到数据资源的共享。     

天山乌鲁木齐河融雪和河川径流的水文化学过程

研究结果表明, 含 Ｃａ Ｃ Ｏ３矿物的溶解作用在乌鲁木齐河源区居主导地位 尽管融雪径流的 “离子脉冲”作用可以释放峰值强度达 ３～４ 倍的 Ｓ Ｏ２４ 和 Ｎ Ｏ－３ 流, 并且引起了总控断面河川径流与之相像的“离子脉冲”现象,但河川径流仍然呈现弱碱性;河源区强烈的含 Ｓ矿物的氧化溶解作用,产生大量的 Ｈ＋ ,被含 Ｃａ Ｃ Ｏ３矿物的溶解作用所缓冲, 未引起河川径流的酸化乌鲁木齐河以冰川站为界, 以上地区的水文化学过程为矿物的侵蚀－ 溶解过程,以下则发生部分矿物的沉淀,如 Ｃａ Ｃ Ｏ３的沉淀 Ｃａ Ｃ Ｏ３ 的沉淀作用一定程度上又增强了河流的酸缓冲力      

青藏高原净生态系统碳交换量的遥感评估模型研究

青藏高原作为世界海拔最高的区域,是全球气候变化的敏感区之一。定量估算这一区域的净生态系统碳交换量（NEE）有利于理解陆地生态系统碳平衡对未来气候变化的响应。本文构建了一个模拟该地区NEE动态变化的净碳收支模型（NCBM）。该模型由来源于MODIS影像的增强型植被指数（EVI）、陆地表面水分指数（LSWI）以及来源于地面观测的空气温度和短波辐射共同驱动,并利用青藏高原地区的3种植被类型（包括高寒灌丛、高寒湿地和高寒草甸）的碳通量长期观测数据对模型进行了校准和验证。结果表明,在模型校准站点年,NCBM模型可以模拟NEE观测值81%的变化,均方根误差（RMSE）为0.03molC/m2/d,模型效率（EF）为0.81。在模型验证站点年,NCBM模型可以预测NEE观测值84%的变化,RMSE为0.03molC/m2/d,EF为0.81。在大多数情况下,NCBM模型可以清晰地模拟各植被类型的NEE季节和年际变化。此外,NCBM模型因为结构简单,模型驱动变量易于获取等优势,具有在区域尺度上模拟NEE时空变化的潜力。但是该模型还需要进一步的改进和发展,特别需要提高对植被非常稀疏地区NEE变化的模拟能力。     

天然膨润土中蒙脱石丰度的定量方法研究

基于膨润土中蒙脱石的基本结构单元在X射线衍射空间的相干散射的分布和总量是一不变量,同一膨润土矿中单位质量蒙脱石的阳离子交换容量和层电荷密度专一性的特点,本研究提出了阳离子交换容量／层电荷密度、阳离子交换容量和X射线衍射多相Rietveld分析三种蒙脱石丰度的定量方法,并测定了我国不同产地、矿物组成和物化性质各异的10种天然膨润土中蒙脱石丰度,分析了可能的干扰因素。结果表明,三种方法测得的蒙脱石丰度值在3％范围内吻合良好,且具有一致的自相关性。     

透明胞外聚合颗粒物碳输运新途径

目前大家普遍认为,透明胞外聚合颗粒物(Transparent Exopolymer Particles,TEP)因其独特的凝聚效应导致碳通量向海底输出。但是,近几年的研究表明TEP不仅影响了碳沉降途径,其本身能够悬浮甚至向海水表层迁移,导致其在海洋微表层(Surface Micro-layer, SML)积累,最终显著影响海洋表层碳通量。TEP和其他颗粒物聚集形成凝聚物后,其运动趋势则由凝聚物中TEP的含量占比,即最终颗粒物密度所决定。一个新的值得注意的现象是,密度低的TEP通过与其他微粒聚合形成表面活性物质(Surface-active Substances, SAS),会在海洋–大气界面形成薄膜,显著影响海–气CO₂交换通量,甚至对全球气候变化造成影响。     

海水中磷酸盐在固体粒子上阴离子交换作用 海水中磷酸盐-固体粒子相互作用的台阶型等温线

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。     

离子交换与吸附研究方法

综合文献资料，结合本人研究实践，对离子交换与吸附研究的一些方法做专门介绍．     

水库运行对漫湾库区洲滩水热交换影响

以澜沧江漫湾水库库区洲滩为研究对象,依据水库运行导致的水位波动特征,同步监测洲滩内部水位、水温变化过程,核算洲滩侧向潜流交换量,建立水温与水位之间的响应关系,分析潜流交换水流路径上溶解氧、溶解性碳素变化。结果表明:水库运行引起洲滩水位周期性波动,侧向潜流交换加强,洲滩水位最大变幅达2.2 m,水库一次蓄泄过程进出洲滩的水量达3 956 m^3,洲滩边缘区潜流交换量为中心区的4~5倍;在涨水过程中,洲滩水温下降,中底层温度梯度较大,而在落水过程中,洲滩水温上升,中表层温度梯度较大;溶解氧、溶解性有机碳和无机碳在河流至洲滩潜流交换路径上同步递减,分别从3.27 mg/L、7.3 mg/L和66.0 mg/L下降至0.17 mg/L、2.4mg/L和40.6 mg/L。水库运行导致的水位波动加强了库区洲滩潜流交换,对河流物质循环产生潜在影响。