TBP－（X－5）反相色谱分离m－NPF分光光度法测定铀

本文研究了以磷酸三丁酯为固定相，大孔聚乙烯苯（Ｘ－５型）为担体的浸渍树脂、垂直型反相色谱柱，对铀分离富集的基本性能，以及铀（Ⅳ）－间硝基苯基萤光酮（ｍ－ＮＰＦ）一氨三乙酸（ＮＴＡ）－吐温－８０显色体系的反应条件，提出了ＴＢＰ（Ｘ－５）分离，ｍ－ＮＰＦ－ＮＴＡ－吐温－８０光度法测定铀，经标准样品验证，结果满意。     

Efficiency of heavy liquid separation to concentrate magnetic particles

Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na₆[H₂W₁₂O₄₀], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.     

非定常不稳定液固两相流动中旋涡对颗粒运动影响的数值研究

构建起双向耦合的液固两相流动旋涡动力学模型与数值方法;应用离散涡方法,计算非定常不稳定水流场;采用Lagrange方法模拟颗粒运动,颗粒对流体的反作用通过修正涡泡运动速度来实现。利用所建模型,计算了两种St数的泥沙粒子在圆柱绕流场中的运动。结果证明了液固两相流动中颗粒运动与旋涡存在着明确的相关结构:(1)当水沙混合物中的泥沙颗粒碰上旋涡时,泥沙颗粒被卷入旋涡中,被卷入旋涡中的泥沙颗粒在运动过程中始终分布于旋涡区;(2)均匀水沙混合物绕圆柱流动,由于流体流过圆柱时产生剧烈分离流动,使得在尾迹流内中等St数 (St～o (1))的泥沙颗粒从均匀水沙混合物中分离出来而往旋涡区聚集。     

氯化钠存在下氯化亚锡—罗丹明B—水体系浮选分离铱

研究了Ir（Ⅲ）在NaCl存在下SnCl2－罗丹明B－水体系中的浮选行为，在1.0mol/L HCl介质中，Ir（Ⅲ）与Pd,Pt,Rh,Au同时被浮选，Ir（Ⅲ）的浮选率为99.2％，并与常见贱金属离子分离，被浮选分离的Ir可采用原子吸收法测定，结果与火试金分离富集法相符。精密度试验，相对标准偏差（RSD，n＝5）＜3％。     

彩色地图图像分色的研究及算法实现

研究了目前国内外现有的彩色地图图像分色算法 ,并在此基础上提出一种新的彩色地图图像自动分色算法。该算法直接利用彩色地图图像的颜色特点 ,并充分考虑图像的空间相关信息进行自动分色 ,最终可得到理想的分版图。     

The Impact Of Air-Flow Separation On The Drag Of The Sea Surface

An approach that allows assessment ofthe impact of air-flow separation (AFS) fromwave breaking fronts on the sea-surface drag is presented. Wave breaking fronts are modelled by the discontinuities of the sea-surface slope. It is assumedthat the dynamics of the AFS from wave breaking crests is similar to thatfrom the backward facing step. The form drag supported by an individualbreaker is described by the action of the pressure drop distributed alongthe forward face of the breaking front. The total stress due to the AFS isobtained as a sum of contributions from breaking fronts of different scales.Outside the breaking fronts the drag of the sea surface is supported by theviscous surface stress and the wave-induced stress. To calculate the stressdue to the AFS and the wave-induced stress a physical model of the wind-wavespectrum is used. Together with the model of the air flow described in termsof surface stresses it forms a self-consistent dynamical system for the seasurface-atmosphere where the air flow and wind waves are strongly coupled.Model calculations of the drag coefficient agree with measurements. It is shownthat the dimensionless Charnock parameter (roughness length normalized onthe square of the friction velocity and the acceleration of gravity)increases with the increase of the wind speed in agreement with fieldmeasurements. The stress due to the AFS normalized on the square of thefriction velocity is proportional to the cube of wind speed. At low windsthe viscous surface stress dominates the drag. The role of the form drag,which is the sum of the stress due to the AFS and the wave-induced stress, isnegligible. At moderate and high winds the form drag dominates. At windspeeds higher than 10 m s^-1 the stress supported by the AFS becomescomparable to the wave-induced stress and supports up to 50% of the totalstress.     

等离子体发射光谱法分析毒砂单矿物

研究了大孔膦酸树脂对毒砂中主、次和痕量元素的吸附行为及洗脱条件,结合巯基棉和TBP柱分离技术,建立了两个分离流程。在J-A1160型多道直读光谱仪上实现了毒砂单矿物中包括主量元素Fe和As在内的20个元素测定。主量元素As和Fe的相对标准偏差(n为5～10)分别为1.03％和0.9％,其它元素在5％～11％范围。流程经实际试样分析验证,结果与化学法相符。     

岩矿中稀土元素离子交换分离富集的改进及ICP—AES测定

本文通过对离子交换柱的规格改进,提高了分离效率,加快了分离速度(流速v/(ml·min~(-1)))可达1.0—1.5.结合分离富集条件的选择及ICP-AES测定方法的联用,使本法不分析周期短、所耗试剂省,且检测限低、精密度和准确度较高.经标样检验和矿样实测对比,其结果均令人满意.     

卤水中铷铯的分离与提取

在查阅大量国内外文献的基础上,对采用沉淀法、离子交换法和溶剂萃取法从卤水中分离提取铷、铯进行了较为系统的评述。