全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.     

滇西北地区富碱岩体(脉)地质学及岩石化学特征

喜山期富碱岩体广布于滇西北地区 ,通过对其地质学和岩石化学特征的研究 ,认为富碱岩体 (脉 )由正长 (斑 )岩、二长斑岩、花岗斑岩及相关的火山岩组成 ,具有多次活动的特征 ,并形成区内富有特色的岩浆岩系列 ;该系列岩浆岩以富碱高钾为突出特点 ,具有正常的岩浆演化趋势 ,不同岩带岩石地质学和岩石化学方面有区域性变化规律。     

成矿流体演化与成矿物理化学

成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。     

野外简易脱气装置简介

根据水力学原理结合水氡在实验室分析中水样鼓泡脱气的方法 ,进行了大量的野外试验 ,研制开发了野外简易脱气装置。通过几个月的试观测 ,脱气装置气流稳定 ,脱气效率高 ,完全可以满足自动化观测仪器对气量的需求。该装置解决了地下水化学在野外冷水泉无法进行气体观测的难题 ,而且制作简单、费用低廉 ,非常便于推广。     

不同浓度Li2SO4水溶液结构的X射线衍射研究

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。     

Focused ion beam technique and transmission electron microscope studies of microdiamonds from the Saxonian Erzgebirge, Germany

A focused ion beam of Ga ions is a relatively new technique that has been developed for microelectronic industries. Now researchers of the Earth sciences find it to be a promising tool for studying various geological materials. Using the FIB technique and an FEI Strata DB 235 dual beam system, we have successfully prepared several electron-transparent foils, which crossed μm-sized diamonds included in host minerals such as zircon and garnet from quartzofeldspathic rocks of the Saxonian Erzgebirge, Germany. Scanning and transmission electron microscopy applied to these foils revealed that the diamonds contain crystalline nanometric inclusions. These inclusions consist of minerals of known stoichiometries such as SiO₂ and Al₂SiO₅, whereas others are characterized by different combinations of Si, K, P, Ti, and Fe in the presence of oxygen (stoichiometries are not clear at this stage of research). One suite of inclusions is assumed to be represented by archerite, KH₂PO₄, which is known to be stable at pressures of 4–22 GPa, and one nanocrystal containing Pb, oxygen and carbon is interpreted to be Pb_xO_y or PbCO₃. Along with solid crystalline inclusions, the diamonds contain cavities filled by liquid/gas that escaped during sample preparation. These are associated with dislocations of diamond growth. Our data are consistent with the concept of diamond crystallization from a COH-rich multicomponent supercritical fluid and suggest that the composition of such a fluid is more consistent with a local crustal source rather than that of a mantle origin.     

Application of visual,statistical and artificial neural network methods in the differentiation of water from the exploited aquifers in Kuwait

The ability of artificial neural network to differentiate water samples from the two aquifers of Kuwait on the basis of their major ion chemistry has been demonstrated. The major ion concentration distribution in the groundwater of the Kuwait Group and the Dammam Formation aquifers of Kuwait appears very similar. Cross-plots, supported by the discriminant function analysis of the data, however, suggest that there are some subtle differences in the overall composition of the water from the two aquifers that make it possible to differentiate the water from the two aquifers in almost 80% of the cases. An artificial neural network improved the differentiation capability to 90% of the cases. It is also possible to estimate the fraction of Kuwait Group water in the flow stream of dually completed wells with the help of an artificial neural network developed for this purpose. Electronic Publication     

新疆盐渍土分散性研究

通过研究分析盐渍土及改变盐渍含量对分散性试验的影响,认为土块试验、针孔试验对受高钠离子影响的盐渍土分散性评价是较为有效的方法。新疆土料石膏发育,环境水中Ca2+离子丰富,分散性评价最好在工程实际情况下进行。     

塑膜温室油桃休眠期的温度变化

本文详尽分析了冰岛低压和大西洋高压的长期变化规律，发现两者均具有明显的阶段性变化，而且冰岛低压和大西洋高压的强度具有明显的反相关。同时，还分析了大西洋高压和冰岛低压与我国气候的关系，发现大西洋高压与我国冬季气温基本呈正相关，而冰岛低压与我国气温大致呈反相关，但均没有显著影响，所以两者都不是影响我国气候变化的重要天气系统。     

环电流区中性原子观测特性模拟研究

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.