罗布泊红柳沙包落叶阳离子含量及环境指示意义

 红柳沙包沉积纹层是恢复古环境序列的一种新方法。通过对罗布泊地区红柳沙包沉积纹层中红柳落叶阳离子含量以及与环境变化关系研究表明：K+、Na+、Ca2+、Mg2+等4种阳离子平均含量分别为3.70 mg/g、40.33 mg/g、13.67 mg/g和8.08 mg/g,变化幅度排序为Ca2+ > K+ > Mg2+ > Na+。4种阳离子含量年际变化都较为明显,且变化规律较为一致,4种阳离子含量变化间的相关系数为0.653 0 ~ 0.813 8,表现为良好的正相关关系;各种阳离子与4种阳离子总量变化的相关系数为0.814 4 ~ 0.959 9,其中Na+含量与4种阳离子总量变化的相关系数最高,表明可以用Na+含量的变化或阳离子总量的变化分析变化趋势。阳离子含量与气温变化呈良好的正相关、与年降水量和湖水面积变化呈负相关;地下水水位降低、水质变差时,土壤水质也变差,阳离子含量增加;反之,地下水水位升高、水质变好时,土壤水质变好,阳离子含量降低。红柳落叶有机质阳离子含量的变化进一步验证了利用红柳沙包沉积纹层计年的可靠性和对罗布泊环境变化的可行性。     

黄河上游云凝结核观测研究

分析了2001、2001年8月在黄河上游的玛曲－河南县利用美国Mee公司的130型云凝结核计数器观测的资料，讨论了凝结核的谱型，浓度随饱和度、天气状况及一些气象要素变化的关系，通过与其它地方观测结果的比较，可以看出在地表植被较好的黄河上游牧区，人类活动、污染较少，其自然凝结核少，浓度与青岛的测值相近，与海洋过饱和核谱型接近。     

数字指示式调速搅拌仪的研制

采用调速稳速集成电路通过电位调节买现自反馈电子稳速，克服了实验过程中溶液阻尼变化对电机转速的影响，并利用高精度时钟信号与十进制记数器完成光电测速过程。     

环电流区中性原子观测特性模拟研究

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.     

Analytical laboratory comparison of major and minor constituents in an active crater lake

The crater lake water from Maly Semiachik volcano in Kamchatka was used for the international analytical laboratory comparison of major and minor elements, and hydrogen, sulfur, and oxygen isotope data. Eight institutions participated in this program, giving analytical results of 9 major and 20 minor elements mainly by using ICP-AES for cations and IC for anions. Among the major elements, Na, Mg and Si showed coefficients of variation (CV) of 10% or more, whereas B, Al, Fe, Mn had coefficients less than 7%. The CV% of the minor elements Co, Cu, P, Cr, Pb was much greater (>30%) while the V analyses agreed well (<10%). Ti, Sr, Zn, and F were intermediate (between 10 and 20 CV%). The errors observed for these constituents are inherent to the methods applied: large dilutions and spectrometric interferences. Even the major anions such as Cl (>2000 ppm) and SO₄ (>5000 ppm) gave considerable ranges (5.1 and 8.8 CV%, respectively) as did the obtained pH values (22 CV%). The measured δ¹⁸O of the water samples and δ³⁴S of sulfate are in excellent agreement but the δD values had CV% of 8. Technical recommendations are presented to improve the analytical results for these elements with significant deviations from the mean values.     

离子迁移谱现场观测渤海和北黄海二甲基硫的研究

渤海、黄海是高产二甲基硫（Dimethyl Sulfide, DMS）的大陆架海区。该海区DMS的现场调查研究有助于准确评估海洋DMS释放量及其对全球气候变化的负反馈作用。目前,无论是基于模型还是直接测量法的通量估算均以表层海水或低层大气DMS浓度为基础,因此,先进的检测技术对其通量估算的准确度具有决定性作用。气相色谱法、质谱法、化学发光法以及卫星遥感技术是现在常用的观测技术,而本文则基于苯辅助光电离离子迁移谱技术进一步提出了一种可在海域现场观测海水中DMS的方法。通过结合动态气提-Nafion管在线除水进样系统,消除环境水汽的干扰;在最优条件下,基于DMS两个产物离子峰,可以实现0.10～120 nmol/L之间DMS的定量分析,检测限低至0.065 nmol/L;然后将所建方法应用于2019年秋季渤海、北黄海海水中DMS的现场观测。结果表明,表层海水中DMS的浓度为0.080～0.96 nmol/L（平均值为（0.44±0.34）nmol/L）,其海气通量为0.12～17.75 μmol/（m²·d）（平均值为（ 3.23±4.02）μmol/（m²·d））;通过结合实验室检测结果、环境因子和浮游植物群落结构讨论了海水样品低温储存条件下DMS的变化和影响因素,结果显示,营养盐成分及浮游植物群落结构是影响储存样品中DMS浓度显著增加的主要因素,进一步表明了现场观测方法的建立对海洋DMS释放量的准确评估具有重要意义。     

An Acetic Acid‐Based Extraction Protocol for the Recovery of U,Th and Pb from Calcium Carbonates for U‐(Th)‐Pb Geochronology

A new method for the simultaneous recovery of U, Th and Pb from ca. 0.5 g calcium carbonate samples for the purpose of U‐(Th)‐Pb geochronometry is presented. The protocol employs ion‐exchange chromatography. Standard anion exchange resin (AG 1‐X8 100–200 mesh) was used as the static phase, and 90% acetic acid was used as the mobile phase to elute the unwanted matrix components; dilute nitric acid was used to elute the U, Th and Pb. Blanks of 1.8 pg Th, 6.4 pg Pb and 8.4 pg U were obtained. The protocol was evaluated by determining the isotopic composition of U‐Th‐Pb separates obtained from an in‐house reference material (prepared from a natural speleothem) by MC‐ICP‐MS. An independently dated speleothem was also reanalysed. Based on these tests, the extraction protocol had an acceptable blank and produced a Pb separate sufficiently free of matrix‐induced instrumental biases to be appropriate for U‐Th‐Pb chronology.     

柱撑蒙脱石制备与表征

本文采用多种方法制备keggin离子，并探索出制备稳定keggin离子的适宜酸碱度，用此柱化剂制备出层间距为2．4～2．5nm的柱撑蒙脱石。应用X射线走向衍射技术、红外光谱、差热分析对往撑蒙脱石进行表征，用BET、吡啶吸附考察了其表面物理化学性质。结果表明，用Keggin离子制备出的柱撑蒙脱石其层间距在自然状态下为2．4～2．5nm，350C灼烧，层间距稳℃定在1．8nm，且具有耐热性能好、较大的比表面积和较强的Lewis酸位中心等特点．     

液体闪烁计数技术测氡在铀矿勘查中的应用研究

在火山岩、花岗岩地区和中新生代盆地铀矿勘查中进行了大量的液体闪烁测氡工作，发现该方法探测效率高、抗干扰能力强、重复性好、异常清晰，取得了较好的地质找矿效果，证实了该方法的有效性和可行性。     

Substorm associated radar auroral surges: a statistical study and possible generation model

Substorm-associated radar auroral surges (SARAS) are a short lived (15–90 minutes) and spatially localised (5° of latitude) perturbation of the plasma convection pattern observed within the auroral E-region. The understanding of such phenomena has important ramifications for the investigation of the larger scale plasma convection and ultimately the coupling of the solar wind, magnetosphere and ionosphere system. A statistical investigation is undertaken of SARAS, observed by the Sweden And Britain Radar Experiment (SABRE), in order to provide a more extensive examination of the local time occurrence and propagation characteristics of the events. The statistical analysis has determined a local time occurrence of observations between 1420 MLT and 2200 MLT with a maximum occurrence centred around 1700 MLT. The propagation velocity of the SARAS feature through the SABRE field of view was found to be predominately L-shell aligned with a velocity centred around 1750 ms^–1 and within the range 500 m s^–1 and 3500 m s^–1. This comprehensive examination of the SARAS provides the opportunity to discuss, qualitatively, a possible generation mechanism for SARAS based on a proposed model for the production of a similar phenomenon referred to as sub-auroral ion drifts (SAIDs). The results of the comparison suggests that SARAS may result from a similar geophysical mechanism to that which produces SAID events, but probably occurs at a different time in the evolution of the event.