发射光谱法测定化探样品中的Cu、Pb、Zn、Co、Ag、Sn、Mo和B

以Al2O3、K2S2O7、NaF、C作为缓冲剂与样品混匀,装入石墨电极中,以平头石墨电极为上电极,样品电极为下电极进行摄谱,由光电译谱仪测定谱线的黑度值,以锗为内标用内标法测定样品中Cu、Pb、Zn、Co、Ag、Sn、Mo和B的质量分数。     

基于惯导/天文高精度定姿方法

研究了利用惯性导航系统与天文导航系统进行组合定姿的方法;构造了惯导/天文组合导航系统的状态方程和量测方程;采用卡尔曼滤波技术设计了惯导/天文组合定姿算法。设计飞行器的典型飞行轨迹,通过数学仿真对该算法的有效性进行了验证。结果表明,天文导航能够有效地补偿惯性导航因陀螺漂移带来的误差,非常适用于飞行器的高精度定姿。     

A constrained LAMBDA method for GPS attitude determination

An improved method to obtain fixed integer ambiguity in GPS attitude determination is presented. Known conditions are utilized as constraints to acquire attitude information when the float solution and its variance–covariance matrix are not accurate enough. The searching ellipsoidal region is first expanded to compensate for errors caused by the inaccurate float solution. Then the constraints are used to shrink the region to a proper size, which maintains the true integer ambiguity. Experimental results demonstrate that this scheme gives a fast search time and a higher success rate in determining the fixed integer ambiguity than the unconstrained method. The accuracy of attitude angles is also improved.

钴—5—Br—PADNm络合物的光度性质研究及其应用

本文研究了钴(Ⅱ)-5-Br-PADNm络合物的光度性质。在pH5.0缓冲溶液中,有TritonX-100存在时,Co~(2 )与5-Br-PADNm形成1:2红色络合物,λ_(max)为547nm,ε为1.35×10~5l·mol~(-1)·cm~(-1)。所提出的方法用于矿石及茶叶中Co的测定,得到满意结果。     

泡沫塑料吸附测金中无臭灰化技术的改进

根据泡沫塑料(简称泡塑)吸附测金的无臭灰化技术的机理,作者采用了3ml圆底瓷坩埚灰化,解决了大批量佯品的灰化问题和电极装样困难的问题,并节省了灰化用的滤纸。     

云南省潜在震源区综合统计判定之一

本文将云南省地震局多年来积累的关于中强震发生的地质构造、地貌、地球物理场、地形变等特征基础资料,用于Cora-3算法的模式识别,得出云南省潜在震源区的背景指标,结果是比较理想的。“投票”结果表明,80%的学习集D类对象仍被识别为D类,85%的学习集N类对象仍被识别为N类,控制试验的结果也表明识别结果是比较稳定和可靠的。     

The application of uranium series disequilibrium concepts to sediment yield determination

The determination of uranium series disequilibria in fluvial environments is proposed as a method of calculating catchment mass balances. The technique is based on two main principles. Firstly, ²³⁴U is more mobile than ²³⁸U, especially during the early stages of weathering. Secondly, uranium is far more mobile than either thorium or protactinium. Consequently, teaching during weathering results in the loss of the uranium found in the fresh rock, leaving the two immobile daughters behind. The ratio of uranium carried by sediment to that dissolved, U_S/U_W can, therefore, be determined from river water and sediment isotopic activity ratios. Fluxes of uranium can then be calculated from average concentrations in the water and the associated sediment, from which a sediment yield can be inferred. The Witham catchment in Lincolnshire has been used to test the proposed method. A U_S/U_W ratio of between 5 and 7 is determined and a sediment yield of 2.51 ± 2.12 tonnes yr^?1 km^?2 is proposed. Although some problems concerning environmental chemistry have arisen, the validity of the approach is confirmed by the close correspondence between the results obtained and those inferred by earlier workers using more conventional methods.     

均匀离散分布的平面应变过程和Fry法应变测量

本文运用 Apple Macitonsh 计算机对无应变的均匀离散点分布进行系列平面应变模拟,应变叠加模式分别采用具普遍意义的成岩压实+顺层缩短(LPS)+压溶作用和成岩压实+简单剪切+压溶作用。对各应变阶段的变形点分布进行相应的 Fry 法应变测量,并配合低变形砂岩样品的 Fry 法应变分析实例.证实 Fry 法应变测量方法为一非常有用的应变测量方法,其结果不仅能较好地揭示全岩总应变特征,而且能揭示出许多应变叠加的信息,Fry 法揭示的全岩有限应变椭球主面的方位也较为真实可靠。而 Fry 法运用于应变分布不均匀的劈理化岩石中时,能揭示不同变形域的应变特征,从而达到应变分解的目的。     

锂离子选择电极的研究 Ⅲ.：开链聚醚三（二环己酰胺）锂电极的制备和应用

以合成的开链聚醚三(二环己酰胺)等中性载体制成了PVC膜Li~+电极,研究了载体结构、膜成分与电极性能的关系,在聚醚三酰胺的胺基中,以环己基取代直链的烷基,显著地改善了Li~+—载体的性能,以邻苯二甲酸二癸酯或其和二苄醚混合增塑的1,1,1—三[1′—(2′—氧杂—3′—二环己胺基羰基)丙基]丙烷Li~+—电极的线性响应范围为2×10~(-5)～10~(-1)mol/L LiCl,K_(Li+Na)~(pot)～8×10~(-3),以Mg(Ac)_2为离子强度调节缓冲剂,用标准比较法或样品加入法测定了LiCl—HCl—H_2O或LiCl—MgCl_2—HCl—H_2O体系中的Li~+,LiCl含量≥2％的样品,测定误差≤5％。