新疆巴什布拉克铀矿床成矿地球化学环境分析

从地球化学角度,利用古气候条件和相关地球化学指标分析,指出研究区赋矿岩石形成于干旱的氧化环境;通过分析与铀矿化常见伴生元素组合结果,指出目的层曾遭受过不同程度还原性流体的改造,并在构造抬升期,地表氧化性流体顺层对目的层进行了再次改造,铀矿化则发生于两种不同性质流体混合改造部位。     

软基上沉入式大圆筒结构的水平承载力分析

大圆筒结构是一种适宜于软土地基上的新型港口水工建筑物,但目前对于软基上大圆筒结构的水平极限承载力尚缺乏合理的计算模式和分析方法.结合长江口深水航道治理二期工程,针对大圆筒结构设计方案提出了一种简便而实用的上限极限分析方法,采用有限元数值分析解验证了所提出计算方法的合理性,进而,据此进行了一系列变动参数比较计算,以此对大量的计算结果进行了系统的分析,所得到的数值计算结果与分析结论为工程设计提供参考依据.     

四川前陆盆地上三叠统须家河组物源区分析及其地质意义

为了深入认识四川前陆盆地须家河组沉积物源方向及物源区构造背景,对该盆地次级构造单元内须家河组砂岩碎屑组分、岩屑类型、重矿物组合特征、稀土元素和微量元素进行了分析。结果表明,盆地中的碎屑物源主要来自再旋回造山带,部分可能来自造山之前的混合区,不同的构造单元和层位存在不同物源区的特点：川西坳陷物源主要受龙门山逆冲推覆带控制;川东北坳陷物源主要受米仓山-大巴山逆冲推覆带控制;川东南坳陷物源受雪峰古陆控制,而川中古隆起物源则主要来自南部峨眉瓦山古陆。物源区具有大陆边缘向大陆岛弧转化的构造演化特点,须四期龙门山的逆冲推覆活动明显强于须二期。     

河北平原农田土壤重金属元素Pb、Hg地球化学行为的影响因素

土壤重金属元素地球化学行为是目前国内外研究的热点。研究显示重金属元素地球化学行为与土壤理化性质有密切关系。本文选择河北平原农田为研究区,采集了325个根系土样品,测定了Pb、Hg有效态含量,并探讨了影响其地球化学行为的主要因素。研究表明:(1)Pb、Hg水溶态和离子交换态与土壤p H值呈显著负相关关系,土壤酸化使Pb、Hg有效性增加,直接导致农作物中Pb、Hg含量增加,保持土壤p H值在弱酸性至弱碱性范围,防止土壤酸化,可以降低重金属危害。(2)土壤中有机质含量与Pb、Hg全量呈显著的正相关性,但与水溶态和离子交换态呈负相关。所以土壤中有机质的增加可以降低Pb、Hg元素水溶态和离子交换态含量。(3)随着土壤黏粒的增加,Pb、Hg水溶态和离子交换态含量降低,说明黏粒可以吸附一定量的重金属离子,与重金属元素Pb、Hg地球化学行为存在一定关系。土壤p H值、有机质、黏粒是控制重金属元素Pb、Hg地球化学行为的重要因素。     

贵州荔波董歌洞D3石笋碳氧稳定同位素及微量元素记录的环境变化

通过对贵州荔波董歌洞D3石笋一系列的TIMS U系法测年以及碳氧稳定同位素分析,取得了连续90.0~160,0 ka气候变化高分辨率的同位素记录.表明石笋氧同位素记录和海洋同位素记录一样,也可以明显地按峰、谷划分为MIS5c,MIS5d,MIS5e及MIS6多个气候阶段,界线年龄分别为:5c/5d为110.0 ka B P,5d/5e为120.0 ka B P,5e/6为129.2 ka B P.在由冰盛期的6阶段到间冰期的5e,δ18O值由偏重的谷底至偏轻的峰顶的跃变,代表冰期旋回之间由冷到暖的快速转变.此外,δ13C值也同样自谷底至峰顶的快速变化,说明生态环境也随气候环境的迅速变化而变化.系统的微量元素分析表明,S,Al,Sr,P,F等均表现出由冰盛期6阶段至间冰期5e阶段最大幅度的迅速变化,在间冰期,微量元素记录变化幅度较小,变化波形与δ13C记录更为相似,研究表明,这些微量元素与δ13C记录一样也可以作为岩溶区生态环境重建的代用指标.     

南沙海槽区表层沉积物的地球化学特征

对南沙海槽区73个表层沉积物的地球化学及沉积环境特征进行了研究。微量元素主要有Cu、Pb、Zn、Ni、Co、Cr、Sr、Ba和Zr，表现为亲陆性，常量组分为SiO2、AI2O3、TFe、CaO、MgO、K2O、Na2O、MnO、PO25、TiO2，表现为边缘海向深海过渡的沉积环境特点。沉积物质含有粘土组分、碳酸盐型生物碎屑组分、陆源碎屑非粘土组分以及火山碎屑、岛源物质，沉积环境与水深关系密切，在200m以浅，沉积物的供给复杂，沉积环境多变，在200m以深，沉积物的供给和沉积环境稳定。     

深基坑降水疏干过程中三维渗流场数值模拟研究

运用潜水、承压水渗流理论和有限差分法,以及干湿单元、预处理共扼梯度算法,以上海环球金融中心塔楼深基坑降水为依托工程,对深基坑降水的三维非稳定渗流场的计算建模和降水疏干过程进行了数值模拟研究.利用5口井和8口井的群井抽水试验资料,对模型主要参数进行了校正及后继检验计算.在上述基础上对中心基坑水位降至-22m时井的布置方案进行了优化设计,同时分析了深基坑内外渗流场的变化,为深基坑降水设计和施工提供了依据.     

锍镍试金-等离子体质谱法测定地球化学勘探样品中的铂族元素和金Ⅱ．分析流程空白的降低

对锍镍试金富集－等离子体质谱法测定贵金属流程中的试剂空白进行了检查，并对空白主要来源－捕集剂镍的各种纯化方法作了对比，提出了回收试金流程中溶扣后滤液中的镍循环使用。在有效降低空白的基础上，满足了化探样品所要求的0.0x ng/g级检出限，对超痕量贵金属标样分析结果与标准值符合。     

Geochemical evidences of dry climate in the Mid-Holocene in Gonghe Basin, northeastern Qinghai-Tibetan Plateau

Previous research on climatic change in the Mid-Holocene in China indicates that it was a warm and humid period, accompanied by stronger summer monsoons, and it is defined as the Megathermal in the Holocene, or the Holocene Optimum period. However, this conclusion is mainly directed at the monsoonal region in eastern China. In this research, we chose the Gonghe Basin in the northeastern Qinghai-Tibetan Plateau as the study area. Geochemical analysis of the profiles of paleosols and aeolian sand in the Santala area in the middle of the Gonghe Basin, along with OSL (optically stimulated luminescence) dating, indicates that the regional climate has experienced several warm-humid and cold-dry cycles since 11.8 ka. In particular, the Mid-Holocene (8.1–4.6 ka) was relatively cold and dry as evidenced by drastic fluctuations in chemical weathering degree and humidity, a higher aridity index, and sparse vegetation, accompanying increased winter monsoonal strength. In order to clarify whether this is an individual or local signal, we compared our geochemical analysis results with lake and peat records and aeolian deposits of the monsoonal boundary region. The results indicate that the climate deteriorated widely, with declines in temperature and moisture, in the Mid-Holocene in the modern monsoonal boundary zone. Furthermore, the duration of climate deterioration (relatively dry period) generally decreased from west to east in the aforementioned regions. Therefore, this dry phase in Gonghe Basin may be representative of dry events in Mid-Holocene in northern China. In addition, we discuss the reasons for this dry climate from several perspectives: (1) it probably can be attributed to a decline in summer monsoonal strength; (2) the regional evaporation loss (forced by high temperature) was not compensated by regional precipitation; (3) the thermal dynamic effect of the Qinghai-Tibetan Plateau.     

Concentrations of trace elements in marine fish and its risk assessment in Malaysia

Concentrations of trace elements (V, Cr, Mn, Co, Cu, Zn, Ga, Se, Rb, Sr, Mo, Ag, Cd, Sn, Sb, Cs, Ba, Hg, Tl, Pb and Bi) were determined in muscle and liver of 12 species of marine fish collected from coastal areas in Malaysia. Levels of V, Cr, Mn, Co, Cu, Zn, Ga, Sr, Mo, Ag, Cd, Sn, Ba and Pb in liver were higher than those in muscle, whereas Rb and Cs concentrations showed the opposite trend. Positive correlations between concentrations in liver and muscle were observed for all the trace elements except Cu and Sn. Copper, Zn, Se, Ag, Cd, Cs and Hg concentrations in bigeye scads from the east coast of the Peninsular Malaysia were higher than those from the west, whereas V showed the opposite trend. The high concentration of V in the west coast might indicate oil contamination in the Strait of Malacca. To evaluate the health risk to Malaysian population through consumption of fish, intake rates of trace elements were estimated on the basis of the concentrations of trace elements in muscle of fish and daily fish consumption. Some specimens of the marine fish had Hg levels higher than the guideline value by US Environmental Protection Agency (EPA), indicating that consumption of these fish at the present rate may be hazardous to Malaysian people. To our knowledge, this is the first study on multielemental accumulation in marine fish from the Malaysian coast.