岩体结构统计均质区的划分

本文介绍由Ｍｉｌｌｅｒ提出的基本概率统计理论的关联表分析，结合施密特投影图研究岩体统计均质区的划分方法。对该法进行了适当的修改，编写了相应的计算机程序。并对三峡永久船闸地区的岩体结构，进行了岩体结构统计均质区的划分，获得了良好的效果。     

香河地区光合有效辐射观测分析研究

利用中国科学院大气物理研究所香河大气综合观测实验站(39°47′N,116°57′E)2004年10月至2005年12月共15个月的太阳辐射观测资料,分析了该地区光合有效辐射与太阳总辐射比值的(PAR/Rs)日变化和季节变化特征,得出月平均PAR/Rs值变化范围在1.808~2.048μE.J-1之间,最大值出现在夏季,最小值出现在冬季,年平均值为1.948μE.J-1。提出了一个利用太阳总辐射观测值计算光合有效辐射瞬时值的参数化算式,用该算式计算得到的PAR与实际观测值的均方根误差为19.28μE.m-2.s-1,有96%的计算值与观测值偏差在±10%以内。比较了香河地区与太湖地区、额济纳地区光合有效辐射瞬时最大值、小时累积最大值及日累积最大值的差异。     

大气凝结水汽汇、凝结潜热作用与积云对流参数化

从引入包含质量(水汽)源、汇的连续方程出发,重新推导出大尺度凝结降水和积云对流凝结降水之水汽汇起作用的热力学方程,从而重新给出气压、气温预报方程及地面气压与高空位势高度预报方程。发现,在此基础上,才能实现凝结3个作用:气块水汽质量流失与气压降低;气块虚温降低;加热气块;和通过大气运动方程,实现大气凝结潜热“热机”作功。这时,对于预报气压、气温场,积云对流参数化方案中的参数在凝结3个作用中保持一致。否则,通过积云对流参数化方案,虽可以近似实现对于预报气压和气温场的凝结3个作用,但不可能调好参数的降水物理特性及其时空分布特征。且对于静力模式预报地面气压和高空位势高度场,不可能实现上述的第一凝结作用。最后表明,当模式分辨率提高到只用降水显式方案、不再用积云对流参数化方案后,则必须引入包含水汽源、汇的连续方程。因在热带海洋面上的水蒸发过程,水汽进入大气将改变地面气压场,且蒸发潜热可分为内潜热(水汽内能)和外潜热(水汽压力能),内潜热立即成为大气热能的一部分,而外潜热直接对大气层作功,使得大气位能增加。文中研究了大气中的大尺度凝结降水和积云对流凝结降水对气压场与位势高度场的影响。一般积云对流参数化方案都已考虑内潜热对大气的加热作用,但还须考虑因凝结与降水造成地面气压场及高空位势高度场的变化,后者应是外潜热作用的结果。在上述研究过程中,必须引入考虑凝结作用的连续方程,且最终可以改变有降水(包括大尺度凝结降水和积云对流凝结降水)发生时的数值预报模式动力框架。     

Vertical structures of PM10 and PM 2.5 and their dynamical character in low atmosphere in Beijing urban areas

The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.     

气团分类及其与贵州气候灾害的关系

通过对贵州3站点历年逐日地面气象要素进行统计分类，分析影响贵州的气团活动规律，并对贵州气候灾害与各类气团活动频数作相关分析。结果表明：贵州气候受多种气团活动的影响，各型气团对应特定的天气特征及一定的环流背景。另外，气候灾害与某些气团活动变化具有很好的相关性，这对进一步研究贵州气候变化及气候灾害成因具有一定的现实意义。     

利用MODIS卫星资料对比反演兰州地区气溶胶光学厚度

Kaufman的暗像元方法是目前利用MODIS卫星资料反演气溶胶光学厚度的方法之一,但在获取可见光通道地表反射率时存在局限性。我们用一种对比方法进行了反演试验,研究了反演粒径较大的气溶胶光学厚度的可行性。用6S辐射传输模式模拟了两天的表观反射率差异对气溶胶光学厚度的敏感性;利用两天(“清洁日”和“污染日”)MODIS的红、蓝和近红外通道表观反射率资料,通过查算表反演了水面上空的气溶胶光学厚度和几何平均质量粒径;在此基础上反演了兰州地区气溶胶光学厚度的分布情况。反演结果与地面光度计观测作了比较,两者比较接近,说明反演方法是可行的。     

韧性剪切带内流体作用及成分变化与体积变化

韧性剪切带中的大量流体活动,影响了变形机制和矿物成分的变化。由于流体的渗透,造成某些元素的迁移,形成剪切带的物质成分变化和体积变化。流体与岩石的相互作用则是剪切带发展过程中的重要作用。应用成分变化计算体积变化已成为研究的热点问题     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

基于GSI值量化和修正方法的岩体力学参数确定

为了准确确定岩体力学参数,通过综合分析多种地质强度指标(GSI)量化方法,提出了一种改进的GSI值量化和修正方法。首先,利用测线法估算结构面平均间距(d)和岩体块度指数(RBI)的改进型岩体块度率(RBR),根据岩体三维结构面网络,获得岩体体积节理数(Jv)和岩体结构等级(SR),然后采用上述参数和结构表面条件(SCR)及结构表面特性参数(Jc)进行了GSI值的定量化处理。为了克服GSI体系的缺点,考虑结构面产状和地下水对岩体力学性质的影响,提出了GSI值的修正方法和公式。以某铅锌矿体的矿岩体为例,根据改进的GSI值量化和修正方法及Hoek-Brown强度准则来确定矿岩体力学参数,通过与原位变形试验的对比分析,验证了该方法的精确性和可行性。该方法为从室内岩石力学试验合理地获取节理岩体力学参数提供了理论及实现的依据。     

黑龙江省东宁县洋灰洞子铜矿床成矿岩体特征

通过对洋灰洞子铜矿床的成矿岩体进行研究，进一步明确了其成矿地质背景，着重研究与铜钼矿床关系密切的花岗闪长岩体和花岗闪长斑岩体的岩性特征、岩石类型、岩石化学特点、成岩时代、物质来源及侵位方式等，确定了该区花岗闪长岩和花岗闪长斑岩为洋灰洞子斑岩型铜钼矿床的成矿母岩。