Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

马超营断裂带区域地球化学特征

该文探讨了马超营断裂带内各地层的成矿元素丰度特征,阐述了该带内成矿元素的分布特征及分布规律,总结了Ａｕ及有关元素Ａｇ、Ｐｂ、Ｚｎ、Ｍｏ、Ｃｏ、Ｎｉ、Ｍｎ、Ｂａ、Ｓｒ、Ａｓ、Ｓｂ、Ｂｉ等异常的特征及其分布规律。研究成果表明：马超营断裂带的韧性—韧脆性剪切带是本区Ａｕ及与其相关的Ａｇ、Ｐｂ、Ｚｎ等成矿元素异常规模、形态和空间分布的控制因素。     

基于PPT战略的广东省乐昌市生态旅游扶贫模式探讨

以贫困人口受益为出发点,基于有利于贫困人口发展的旅游(Pro-Poor Tourism,PPT)战略,以广东省乐昌市为例,开展适用于中国南方林区生态旅游扶贫开发的发展模式和旅游扶贫产业的发展路径研究.结果表明:1)政府部门、旅游企业、乡村社区和非营利社会组织都应在提升贫困人口参与度、减轻贫困和生态保护方面承担责任,具体...     

孔道结构化合物(H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]的钒氧化态与热稳定性关系研究

热处理脱除有机模板易导致VPO体系孔道结构化合物结构破坏,从而阻碍此类材料的实际应用。以孔道结构化合物(H3NCH2CH2NH3)3[(VO)4 (PO4 )2 (HPO4 )4 ](简称V2P3 en)为研究对象,利用热分析(DSC TG)、动态原位高温X 射线衍射(XRD)及多功能X 射线光电子能谱(XPS)等方法,研究了该化合物在不同气氛热处理过程中模板脱除及结构演化规律,重点探讨了钒氧化态的变化对结构稳定性的影响。结果表明,加热过程中随着有机模板的分解脱除,形成较强的还原环境,骨架中的部分钒被还原(V4+→V3+),使原有的配位环境([VⅣO5]三角双锥、[VⅣO6]畸变八面体)与钒的氧化态不符而导致结构重组。因此,钒氧化态的变化是影响热稳定性的重要因素之一。     

SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.     

瞬变电磁法在煤矿水害防治中的应用

煤层附近的富水区(带)严重威胁着煤矿的生产安全，探明地下煤层附近富水区的赋存和断层、裂隙的发育情况，可以有效地指导煤矿水害的防治工作。对于含水地层及富水区，瞬变电磁法在多测道剖面上具有典型响应特征，据此可以查明地下水分布情况。在山东某煤田和河南某矿，应用瞬变电磁勘探，准确地查明了煤层顶底板富水区。．     

地浸采铀浸出液氧化沉淀法除铁研究

在氧化沉淀法去除铁的过程中,氧化反应分别在自然曝气、充气和除钙的条件下进行,对照结果进行分析,得出最佳的除铁配方,同时还着重对氧化反应速率及其影响因素（pH,Eh等）进行了探索性研究,为以后试验提供了一定的依据。     

Integration of ASTER and landsat TM remote sensing data for chromite prospecting and lithological mapping in Neyriz ophiolite zone,south Iran

Chromite deposits in Iran are located in the ophiolite complexes, which have mostly podiform types and irregular in their settings. Exploration for podiform chromite deposits associated with ophiolite complexes has been a challenge for the prospectors due to tectonic disturbance and their distribution patterns. Most of Iranian ophiolitic zones are located in mountainous and inaccessible regions. Remote sensing approach could be applicable tool for choromite prospecting in Iranian ophiolitic zones with intensely rugged topography, where systematic sampling and conventional geological mapping are limited. In this study, Landsat Thematic Mapper (TM) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) satellite data were used for chromite prospecting and lithological mapping in the Neyriz ophiolitic zone in the south of Iran. Image transformation techniques, namely decorrelation stretch, band ratio and principal component analysis (PCA) were applied to Landsat TM and ASTER data sets for lithological mapping at regional scale. The RGB decorrelated image of Landsat TM spectral bands 7, 5, and 4, and the principal components PC1, PC2 and PC3 image of ASTER SWIR spectral bands efficiently showed the occurrence of major lithological units in the study area at regional scale. The band ratios of 5/3, 5/1, 7/5 applied on ASTER VNIR‐SWIR bands were very useful for discriminating most of rock units in the study area and delineation of the transition zone and mantle harzburgite in the Neyriz ophiolitic complex. Spectral Angle Mapper (SAM) technique was implemented to ASTER VNIR‐SWIR spectral bands for detecting minerals of rock units and especially delineation of the transition zone and mantle harzburgite as potential zones with high chromite mineralization in the Neyriz ophiolitic complex. The integration of information extracted from the image processing algorithms used in this study mapped most of lithological units of the Neyriz ophiolitic complex and identified potential areas of high chromite mineralization (transition zone and mantle harzburgite) for chromite prospecting targets in the future. Furthermore, image processing results were verified by comprehensive fieldwork and laboratory analysis in the study area. Accordingly, result of this investigation indicate that the integration of information extracted from the image processing algorithms using Landsat TM and ASTER data sets could be broadly applicable tool for chromite prospecting and lithological mapping in mountainous and inaccessible regions such Iranian ophiolitic zones.     

斜坡非饱和带低渗透岩石结构体风化前锋扩展过程

非饱和带低渗透岩石结构体风化前锋扩展是斜坡灾害孕育过程中的关键环节之一。到目前为止,化学风化领域的研究成果主要集中在高水-岩比的饱和环境下单矿物及矿物成分单一的碳酸盐岩的风化动力学方面,非饱和环境下的岩石风化研究还主要限于风化产物的特性描述方面。斜坡非饱和带低渗透岩石结构体风化前锋扩展是一种高度复杂的THMC过程。由于在溶解对象、溶解液及溶解过程的水动力-水化学环境等方面存在的显著差异,既有的地质材料风化动力学成果为探索这一复杂过程提供了理论储备,但还不能阐明其核心机理。斜坡非饱和带低渗透岩石结构体风化前锋的扩展过程研究不仅可以加深人们对斜坡灾害孕育的理解,为灾害预报-预警及其控制提供理论依据,同时可以促进岩石-岩体力学及浅表生水文地球化学等相关学科的交叉与发展。