温度变化对半刚性沥青路面裂缝的影响

半刚性基层沥青路面反射裂缝产生的原因之一是由半刚性基层温度变化引起的。根据路表代表性温度特征,运用有限元平面模型计算了裂缝尖端的应力强度因子,并对影响其大小的各因素进行了敏感性分析。结果表明,面层和基层的模量以及基层的温缩系数的增大会不同程度地导致裂缝尖端应力强度因子的增大,而面层的温缩系数对裂缝尖端应力 强度因子的影响并不明显。另外,增加面层厚度能有效地降低裂缝尖端应力强度因子,并提出碎石基层可有效地减缓路面反射裂缝的扩展的结论。     

厚层河道砂体储层非均质性研究——以葡萄花油层组PI1-PI4小层为例

储层非均质性对油气田的勘探和开发效果影响很大.结合测井资料二次解释的孔隙度(Φ)、泥质含量(Vsh)、粒度中值(Md)、束缚水饱和度(Swi)等资料,借助BP网络对渗透率进行预测.对萨尔图油田中部葡萄花油层组的非均质性进行了定量半定量的研究,认为萨尔图油田中部葡萄花油层组PI2小层层内非均质性最严重,与沉积微相密切相关.单砂层垂向上渗透率的变化以正韵律和复合式韵律为主,局部发育反韵律模式.葡萄花油层组PI1-PI4小层层内非均质性强弱依次为PI2a,PI3,PI2b,PI1,PI4;层间非均质性在PI3和PI4间表现得最强,其他相对要弱;各小层平面非均质性相差无几,整体表现为较强的非均质性.     

辽河油田D块中—厚层稠油油藏隔夹层的分类及识别

充分利用研究区Ng油层、XLT油层取芯井的岩芯资料和测井等资料,识别并划分出不同类型的隔夹层。研究区主要发育泥质隔夹层、物性隔夹层和砾岩隔夹层,以泥质隔夹层和物性隔夹层为主。从定性和定量两方面采用多学科、多信息对该区的隔夹层进行精细研究,建立隔夹层识别的定性、定量识别标准,为隔夹层的精细刻画奠定基础,为提高稠油热采开发效果提供地质依据     

个旧锡矿大马芦层间氧化矿床地质特征及找矿方向研究

个旧锡矿层间氧化矿床品位高、工业利用价值大，加强这类矿床地质特征的研究，对于矿山深部及外围的锡矿找矿具有重要的指导意义。通过对个旧锡矿层间氧化矿床产出的地质特征、控矿因素的分析与研究，探讨了其矿床成因，并总结出：“背-突式”、“向-断-凹式”、“断-互式”及“断裂式”四种成，矿模式。按这些模式的找矿实践表明，找矿效果极佳。     

山西阳泉矿区煤层气分层排采分析

煤层气开发过程中,由于各煤层及其顶底板之间物性特征等方面的差异,易导致层间干扰,影响煤层气产能。阳泉矿区煤层气资源储量丰富,主要可采煤层有3#、8#、9#、15#煤层,其中3#煤层为局部可采煤层。以该区YQ-191和YQ-359井为例,通过分析8#、9#、15#煤层在渗透率、储层压力、煤层厚度、含气量、埋藏深度、水文地质条件的差异,发现,YQ-191井8#、9#的各项参数较为接近,层间干扰小,适宜合层开采;YQ-359井8#、15#煤层渗透率与储层压力相差较大,层间干扰严重,合层开采严重影响15#煤层的产能,该井8#、15#煤层不适宜合层开采。     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Preparation of Mg/Al Layered Double Hydroxides by Buffer Solution Method and Cr（Ⅵ） Adsorption Characteristics

利用氨水-氯化铵体系在pH 9～10时具有缓冲能力的特点,以其作为沉淀剂成功合成了镁铝水滑石（Mg3Al-Cl-LDHs）,采用XRD、FT-IR、TG-DTA等手段对材料结构进行表征,并测试了合成Mg3Al-Cl-LDHs样品对溶液中Cr（Ⅵ）的吸附性能。研究结果表明,缓冲溶液法制备的Mg3Al-Cl-LDHs材料晶相单一,晶面生长的有序程度较高,结晶度较好。晶胞参数a=0.3106 nm,c=2.367 nm,粒子尺寸约为36.44 nm。其热分解过程包括水滑石层间结构水脱除和层板羟基脱水、氯离子分解两个步骤。Mg3Al-Cl-LDHs对Cr（Ⅵ）的吸附主要发生在0～1 h内,随着时间的增长吸附量先增加后趋于平缓;温度对Cr（Ⅵ）吸附量影响不大,在常温下即可进行;随着pH值的减小,饱和吸附量先增大后减小,在pH 6时吸附效果较好;2价与3价竞争阴离子比1价阴离子对吸附性能的影响更大。在最佳吸附条件下,Mg3Al-Cl-LDHs对Cr（Ⅵ）的饱和吸附量可达58.73 mg/g,有望应用于实际Cr（Ⅵ）废水处理。     

铝胁迫对海莲幼苗中某些金属元素累积的影响

对海莲(Brugiera sexangula)幼苗进行不同浓度的铝盐处理,采用微波消解和电感耦合等离子体质谱法(ICP-MS)测定了海莲幼苗叶片,茎和根组分的Na、Mg、K、Ca、Mn、Fe、Cu、Zn和Al金属元素含量。结果显示,随培养液Al浓度的增加,海莲叶片、茎和根部Al的积累增加,其中根组分增加尤为显著。Al胁迫下,海莲根部对Na的吸收增强,但在叶和茎中的变化不显著;10 mmol/L的Al处理促进了根对K的吸收;Al显著抑制了Mn和Fe在海莲中的积累;Cu、Zn含量在海莲各器官中的变化不一致。此外,25 mmol/L和50 mmol/L Al处理的海莲幼苗根部对Ca的积累显著增加,有利于Al毒害的缓解作用。     

鄂尔多斯盆地南部旬邑-宜君地区直罗组古层间氧化带地球化学特征及水-岩作用探讨

鄂尔多斯盆地南部旬邑-宜君地区直罗组古层间氧化带具有明显分带特征,通过对不同分带砂岩主量、微量、稀土元素及环境敏感参数特征对比研究,将旬邑-宜君地区古层间氧化带发育的水-岩作用过程划分成两个阶段：古层间氧化带形成和大规模成矿阶段、二次还原改造阶段。(1)古层间氧化带形成和大规模成矿阶段：含氧水进入目的层砂体,使砂体中Fe²⁺氧化成Fe³⁺(Fe²⁺含量最低,Fe³⁺最高);砂体中的U被氧化为U⁶⁺,形成铀酰腐殖酸盐络合物发生迁移(U、Corg、S含量最低、Th/U比值最高);长石高岭土化使Si发生流失(SiO₂含量降低);携带大量U的氧化流体运移至氧化还原过渡带(Corg、∑S含量最高、Fe²⁺含量仅低于灰绿色砂体),还原剂(有机质和黄铁矿等)将U⁶⁺还原成U⁴⁺,形成沥青铀矿;U⁴⁺与SiO₄^4-发生反应形成铀石(Th/U比...     

Ultrahigh-pressure garnet lherzolite from Chijiadian, Rongcheng County, in the Su-Lu region of eastern China

Abstract Petrological studies of a serpentinized garnet lherzolite body in Rongcheng of the Su-Lu region of eastern China revealed unusually high pressure. Spinel lherzolite probably in a subducting slab was transformed to garnet lherzolite at mantle depth. During exhumation, they were subsequently subjected to the granulite and then amphibolite overprinting and a phase of serpentinization. The peak P–T conditions of the garnet lherzolite estimated after detailed analysis of the metamorphic texture are 4–5 GPa and 820°C or 5–6 GPa and 780°C, depending on the chosen geothermobarometers. The lower dP/dT of the garnet lherzolite can be interpreted as the results of subduction of an old (say 100 Ma older than the time of collision) and cold, slab underneath the margin of the Sino–Korean craton.