Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

Age estimates of coastal terraces in the Andaman and Nicobar Islands and their tectonic implications

The great Indian Ocean earthquake of December 26, 2004 caused significant vertical changes in its rupture zone. About 800 km of the rupture is along the Andaman and Nicobar Islands, which forms the outer arc ridge of the subduction zone. Coseismic deformation along the exposed land could be observed as uplift/subsidence. Here we analyze the morphological features along the coast of the Andaman and Nicobar Islands, in an effort to reconstruct the past tectonics, taking cues from the coseismic effects. We obtained radiocarbon dates from coastal terraces of the island belt and used them to compute uplift rates, which vary from 1.33 mm yr^− 1 in the Little Andaman to 2.80 mm yr^− 1 in South Andaman and 2.45 mm yr^− 1 in the North Andaman. Our radiocarbon dates converge on  600 yr and  1000 yr old coastal uplifts, which we attribute to the level changes due to two major previous subduction earthquakes in the region.     

Crustal structure at the easternmost termination of the Variscan belt based on CELEBRATION 2000 and ALP 2002 data

The eastern margin of the Variscan belt in Europe comprises plate boundaries between continental blocks and terranes formed during different tectonic events. The crustal structure of that complicated area was studied using the data of the international refraction experiments CELEBRATION 2000 and ALP 2002. The seismic data were acquired along SW–NE oriented refraction and wide-angle reflection profiles CEL10 and ALP04 starting in the Eastern Alps, passing through the Moravo-Silesian zone of the Bohemian Massif and the Fore-Sudetic Monocline, and terminating in the TESZ in Poland. The data were interpreted by seismic tomographic inversion and by 2-D trial-and-error forward modelling of the P waves. Velocity models determine different types of the crust–mantle transition, reflecting variable crustal thickness and delimiting contacts of tectonic units in depth. In the Alpine area, few km thick LVZ with the Vp of 5.1 km s^− 1 dipping to the SW and outcropping at the surface represents the Molasse and Helvetic Flysch sediments overthrust by the Northern Calcareous Alps with higher velocities. In the Bohemian Massif, lower velocities in the range of 5.0–5.6 km s^− 1 down to a depth of 5 km might represent the SE termination of the Elbe Fault Zone. The Fore-Sudetic Monocline and the TESZ are covered by sediments with the velocities in the range of 3.6–5.5 km s^− 1 to the maximum depth of 15 km beneath the Mid-Polish Trough. The Moho in the Eastern Alps is dipping to the SW reaching the depth of 43–45 km. The lower crust at the eastern margin of the Bohemian Massif is characterized by elevated velocities and high Vp gradient, which seems to be a characteristic feature of the Moravo-Silesian. Slightly different properties in the Moravian and Silesian units might be attributed to varying distances of the profile from the Moldanubian Thrust front as well as a different type of contact of the Brunia with the Moldanubian and its northern root sector. The Moho beneath the Fore-Sudetic Monocline is the most pronounced and is interpreted as the first-order discontinuity at a depth of 30 km.     

Focal mechanism inversion in the Giudicarie–Lessini seismotectonic region (Southern Alps, Italy): Insights on tectonic stress and strain

A set of 41 focal mechanisms (1989–2006) from P-wave first polarities is computed from relocated seismic events in the Giudicarie–Lessini region (Southern Alps). Estimated hypocentral depths vary from 3.1 to 20.8 km, for duration magnitudes (M_D) in the range 2.7–5.1. Stress and strain inversions are performed for two seismotectonic zones, namely G (Giudicarie) and L (Lessini). This subdivision is supported by geological evidence, seismicity distribution, and focal mechanism types. The available number of data (16 in G, 22 in L) does not make possible any further subdivisions. Seismotectonic zones G and L are undergoing different kinematic regimes: thrust with strike-slip component in G, and strike-slip in L. Principal stress and strain axes in each sub-region show similar orientations. The direction of maximum horizontal compressive stress is roughly perpendicular to the thrust fronts along the Giudicarie Belt in zone G, and compatible with right-lateral strike-slip reactivation of the faults belonging to the Schio-Vicenza system in zone L. On the whole, kinematic regimes and horizontal stress orientations show a good fit with other stress data from focal mechanisms and breakouts and with geodetic strain rate axes.     

Morphological analysis of the drainage system in the Eastern Alps

We study the morphology of the major rivers draining the Eastern Alps to test whether the active tectonics of this part of the orogen is reflected in the shape of channel profiles of the river network. In our approach we compare channel profiles measured from digital elevation models with numerically modelled channel profiles using a stream power approach. It is shown that regions of high stream power coincide largely with regions of highest topography and largest uplift rates, while the forelands and the Pannonian Basin are characterised by a significantly lower stream power. From stream power modelling we conclude that there is young uplift at the very east of the Eastern Alps, in the Bohemian Massif and in the Pohorje Range. The impact of the Pleistocene glaciations is explored by comparing properties of rivers that drain in proximal and distal positions relative to the ice sheet during the last glacial maximum. Our analysis shows that most knick points, wind gaps and other non-equilibrium features of catchments covered by ice during the last glaciations (Salzach, Enns) can be correlated with glacial processes. In contrast the ice free catchments of the Mur and Drava are characterized by channels in morphological equilibrium at the first approximation and are showing only weak evidence of the strong tectonic activity within these catchments. Finally, the channel profiles of the Adige and the divide between the upper Rhine and Danube catchments differ significantly from the other catchments. We relate this to the fact that the Adige and the Rhine respond to different base levels from the remainder of the Eastern Alps: The Adige may preserve a record from the Messininan base level change and the Rhine is subject to the base level lowering in the Rhine Graben.     

Sensitivity analysis of support safety factor for predicting the effects of contributing parameters on roof falls in underground coal mines

Roof falls accounted for 18.18% of all fatal accidents in Indian coal mines, contributing about 35.29% of all fatal accidents in below-ground operations in 2005. The support safety factor, always preferred in support planning and design of underground coal mines, may be an important predictor for roof falls. In this paper, geotechnical data were collected from 14 roof fall incident places in an underground coal mine, located in the Eastern India, which has bord and pillar method of workings. The mean value of probabilistic support safety factor for the case study mine was found to be 1.24. However, the probability, of the estimated support safety factor of less than or equal to one, was found to be 0.246. Sensitivity analysis was conducted to analyze the effects of the contributing parameters on support safety factor and the likelihood of the roof fall. The multi-variate regression analysis was carried out for the data generated by Monte Carlo method to correlate the contributing factors to support safety factor. It ranked gallery width as the first parameter to control the support safety factor.     

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.     

Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.     

Belemnites from the lower middle Cenomanian of Hoppenstedt, northern Germany: significance and integrated correlation

The belemnite species Praeactinocamax primus (Arkhangelsky, 1912) and Belemnocamax boweri Crick, 1910 are described from the Cenomanian of the abandoned limestone quarry section of Hoppenstedt (Sachsen-Anhalt, northern Germany). They co-occur in the upper part of a prominent tripartite bioclastic limestone bed associated with the ammonite Acanthoceras rhotomagense, indicating the primus Event of the lower middle Cenomanian A. rhotomagense ammonite Zone. An integrated stratigraphical calibration including carbon stable isotope correlation to southern England suggests that the belemnite event horizon at Hoppenstedt occupies exactly the same chronostratigraphical position as elsewhere, highlighting the strictly isochronous character of the primus Event across northwestern Europe. Furthermore, stratigraphical gaps in the Hoppenstedt succession are evaluated.