热处理饱水致密砂岩的水相自吸与返排

致密砂岩气藏在开发过程中由于水相的侵入或滞留会在近井带或水力裂缝面造成水相圈闭损害,严重影响开发效益.储层高温热处理作为一种新型储层改造技术,已应用于解除近井地带水相圈闭损害.选取鄂尔多斯盆地典型致密砂岩岩样,分别采用干岩样、饱和蒸馏水、饱和3%KCl溶液以及饱和地层水的岩心开展了100～600℃的热处理实验;进行了超过阈值温度的高温热处理前后的岩心自吸、返排实验,并对热处理前后岩心的水相圈闭损害程度进行评价.研究表明,饱和蒸馏水和饱和3%KCl溶液的岩样在热处理后的增渗率明显大于干岩样和饱和地层水的岩样,且岩样热致裂的阈值温度明显降低,从干岩样时500℃降低到300℃;高温热处理增加致密砂岩孔隙度与渗透率,不仅使水相自吸量与自吸速率明显提高,而且岩心渗透率恢复率显著提升.致密岩石热致裂阈值温度可以降低,热增渗后不仅解除水相圈闭损害,而且可以预防后期作业储层水相圈闭损害.     

From back-arc rifting to arc accretion: the Late Jurassic–Early Cretaceous evolution of the Guerrero terrane recorded by a major provenance change in sandstones from the Sierra de los Cuarzos area,central Mexico

The Guerrero terrane is composed of Middle Jurassic–Lower Cretaceous arc assemblages that were rifted from the North American continental mainland during Late Jurassic–Early Cretaceous back-arc spreading within the Arperos Basin, and subsequently accreted back to the continental margin in the late Aptian. The Sierra de los Cuarzos area is located just 50 km east of the Guerrero terrane suture belt and, therefore, its stratigraphic record should be highly sensitive to first-order tectonic changes. Two Upper Jurassic–Lower Cretaceous clastic units were recognized in the Sierra de los Cuarzos area. The Sierra de los Cuarzos Formation is the lowermost exposed stratigraphic unit. Petrographic data and U-Pb zircon ages suggest that the Sierra de los Cuarzos Formation was derived from quartz-rich sedimentary and igneous sources within the North American continental mainland. The Sierra de los Cuarzos Formation is overlain by the Pelones Formation, which is composed of volcanoclastic sandstones derived from a mix of sources that include the mafic arc assemblages of the Guerrero terrane and quartz-rich sedimentary and volcanic rocks exposed in the continental mainland. The provenance change documented in the Sierra de los Cuarzos area suggests that the Pelones Formation was deposited when the Arperos Basin was closed and the Guerrero terrane was colliding with the North American continental mainland. Based on these data, we interpret the Pelones Formation as the syn-tectonic stratigraphic record associated with the accretion of the Guerrero terrane.     

丹霞山世界地质公园蜂窝状洞穴特征及成因分析

蜂窝状洞穴以其精致的形貌和众说纷纭的成因吸引着科研人员和普通大众的兴趣。丹霞山世界地质公园蜂窝状洞穴主要产于晚白垩世丹霞组二段(锦石岩段)风成砂岩的崖壁上。本文以园区长老峰锦石岩寺和睡美人禄意堂两处蜂窝状洞穴为研究对象,通过野外实地调查,了解洞穴生长环境,定量统计分析其形态特征,并采集砂岩样品进行显微镜下观察,探讨洞穴形成与盐风化作用的关系。研究表明:蜂窝状洞穴所在的岩性主要为中—细粒长石岩屑砂岩,发育大型高角度交错层理,渗透性较好;洞穴开口均向下朝向锦江,有利于来自锦江河流的湿润水汽较长时间地保持在小洞内部;洞穴开口基本服从泰森多边形分布。因此,碎屑颗粒相对比较均匀的风成砂岩为丹霞山蜂窝状洞穴的发育提供了重要的岩石基础,锦江河流为盐风化提供了必要的湿润水汽和盐分。在初始发育阶段,从岩壁上最适合盐风化作用的若干个点开始形成细小的坑洼,逐步向同层位扩张。单个小洞穴由于盐风化作用,洞穴内部风化速率大于洞穴开口边缘,导致蜂窝状洞穴内部空间扩大较快。然后,蜂窝状洞穴的发育突破纹层的限制,逐步加大、变深而呈泰森多边形规则分布。最终,随着洞穴加深,在重力、风力的影响下,蜂窝状洞穴隔壁减薄失稳,洞穴消亡。     

利用毛管模型研究泥质砂岩电化学测井响应机理

自然电位和激发极化电位测井响应所涉及的离子导体激发极化电位的微观机理解释,主要依据双电层形变假说和浓差极化假说,缺少定量描述的数学模型和理论体系.本文利用孔隙介质的微观毛管模型,给出了毛管模型中双电层理论和阳离子交换量与Zeta电位的关系,推导出毛管中离子流量和电流强度表达式.由电荷守恒定律和物质守恒定律,推导出毛管中离子浓度分布的解析表达式,建立了描述含水泥质砂岩激发极化电位和自然电位的数学模型.从而系统地严格证明了含水泥质砂岩激发极化现象是在电流场和浓度梯度场的共同作用下,由孔隙中离子浓度浓差极化电位和双电层形变电位形成的.并且证明了描述泥质砂岩自然电位的数学方程和描述激发极化电位的数学方程及形成机理是一致的.计算结果表明：激发极化极化率随孔隙度和渗透率的增大而减小;极化率随溶液浓度的增加而减小,随阳离子交换量的增加而增加;证明了地层水浓度、阳离子交换量是影响自然电位大小的主要因素.     

酸性环境干湿循环对泥质砂岩力学特性影响的试验研究

由于库水位升降及降雨等原因,岩体经常处于干湿交替状态,对岩体工程的长期稳定性不利。以三峡库区泥质砂岩为研究对象,进行了酸性环境干湿循环交替作用后的常规单轴与三轴压缩试验研究,获得了泥质砂岩在酸性溶液浸泡干湿循环后的相关力学参数。相对于没有经过干湿循环作用的干燥试件,经过不同次数的干湿循环作用后,泥质砂岩的弹性模量、单轴抗压强度、黏聚力与内摩擦角都有不同程度的降低。各个力学指标的总体变化趋势是在第一次饱水之后有大幅度的降低,此后随着干湿循环次数的增加其降低的幅度逐渐减小。同时,酸性溶液的pH值对力学指标的影响很大,存在对泥质砂岩力学性能影响较大的一个临界pH值,低于此值酸性溶液对泥质砂岩力学性能影响显著增大,高于此值酸性溶液对其力学性能影响较小。     

巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件及远景分析

本根据野外调查及室内系列编图成果，分析了巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件，认为下白里统巴彦花组是中新生代盆地的找矿目的层位，并存在古河道与潜水层间氧化带两种砂岩型铀矿类型。巴彦毛都、准巴彦塔拉、乌里雅斯太和伊勒门盆地是形成砂岩型铀矿的远景盆地。     

西湖凹陷西次凹古近系花港组—平湖组深层油气成藏过程

西湖凹陷西次凹古近系花港组和平湖组深层油气资源丰富,是东海陆架盆地勘探开发新领域,受储层差异致密化影响,油气成藏机理复杂。为了厘清西次凹深层油气成藏过程,本文通过流体包裹体岩相学特征、显微测温、激光拉曼光谱、包裹体所含油气地球化学等实验分析,结合构造演化、地层埋藏史、热史等,开展了系统的储层特征、油气成藏期次、成藏过程研究。结果表明,花港组深层（>4000 m）和平湖组储层均已致密化,溶蚀孔隙是主要的储集孔隙类型;花港组和平湖组均发育两期油气包裹体,早期含油包裹体较多,晚期以天然气包裹体为主,成藏时间分别为龙井运动期和冲绳运动期,以晚期天然气成藏最为关键。包裹体中油气地球化学特征类似,反映生烃母质以高等植物生源为主,低等生物为辅,与平湖组煤系烃源岩特征一致。冲绳运动叠加平湖组生气增压是晚期天然气成藏的主要动力,此时H10段及以上储层未致密化。根据储层致密化与成藏时序匹配关系可将西次凹M构造深层油气藏类型划分为常规型、先成藏后致密型、先致密后成藏型和边成藏边致密型4种。本文成果可为研究区下一步致密砂岩气的勘探开发部署提供重要的理论依据。     

化学腐蚀下砂岩三轴细观损伤机理及损伤变量分析

利用CT识别技术对化学腐蚀下的砂岩进行了三轴加载全过程的即时扫描试验，得到了在不同级荷载作用下砂岩的压密、微裂纹萌生、扩展和破裂的CT图像和CT数，分析了砂岩损伤演化的细观机理。同时，建立了一个基于化学腐蚀影响和CT数的损伤变量模型。     

障壁坝砂体储层特征与成岩孔隙定量演化模式 ——以鄂尔多斯盆地延长探区本溪组为例

为明确海陆变迁背景下障壁坝砂体成岩孔隙演化规律,运用岩石薄片、扫描电镜及配套能谱、阴极发光等资料,对延长探区石炭系本溪组障壁成因砂体储集特征与成岩作用进行综合分析,并结合砂岩初始孔隙度恢复模型与薄片孔隙定量分析技术,开展基于埋藏热演化历程的储层孔隙演化参数定量评价,建立该区本溪组障壁坝砂岩孔隙定量演化模式。结果表明:储层砂岩以石英砂岩、岩屑质石英砂岩及岩屑砂岩为主;孔隙度、渗透率平均值分别为4.72%和1.22×10^(-3 )μm^2;储集空间以溶蚀扩大孔、粒内孔、晶间孔为主;现今储层主体已达到晚成岩阶段;砂岩初始孔隙度平均值为38.1%,埋藏至今共经历了四个典型的成岩增/减孔阶段,即P_1～T_2(285～208 Ma)"低地温、快埋藏"的大幅减孔阶段(-30.7%)、T_2～J_3(208～153 Ma)"高地温、缓沉降"的溶蚀增孔阶段(+3.9%)、J_3～K_1(153～96 Ma)"高地温、稳埋深"的减孔定型阶段(-6.6%)、K_1至今(96 Ma～)"低地温、晚隆升"的弱改造阶段。     

Final Closure Time of the Paleo‐Asian Ocean: Implication from the Provenance Transformation from the Yangjiagou Formation to Lujiatun Formation in the Jiutai Area,NE China

The Jiutai area is tectonically situated at the eastern segment of the Central Asian Orogenic Belt(CAOB) and is close to the North China Craton(NCC) to the south, serving as an ideal place to investigations of the closure of the PaleoAsian Ocean(PAO). Sandstone samples collected from the Yangjiagou Formation and the Lujiatun Formation in this area have been studied in detail in terms of petrology, geochronology and geochemistry. The maximum depositional time of the Yangjiagou and Lujiatun formations has been constrained to early Middle Triassic(ca. 245 Ma) and middle Late Triassic(ca. 219 Ma), respectively. The Yangjiagou Formation, with a major provenance of dissected island arcs, is dominantly composed of Phanerozoic sediments from Northeastern China(NE China) massifs. The Lujiatun Formation, with major sediments from active continental margins, has a relatively larger proportion of Precambrian sediments, in which the ～1.85 Ga and ～2.5 Ga sediments are typical of the crystalline basements of the NCC and NE China massifs, which were uplifted and eroded during the closure of the PAO. Besides, both formations show the enrichment in LREEs and the depletion in HREEs, the common Eu negative anomalies, and trace element contents similar to that of the upper continental crust. Based on the provenance analysis of these two formations, the final closure time of the PAO in this area is constrained as from the early Middle Triassic(ca. 245 Ma) to the middle Late Triassic(ca. 219 Ma).