基于短波红外技术的蚀变矿物特征及勘查模型——以斯弄多银铅锌矿床为例

印度-亚洲大陆的碰撞成就了青藏高原的冈底斯成矿带,位于该成矿带的斯弄多银铅锌矿床赋存于林子宗群火山岩中,经过勘查确认该矿床属于低硫化浅成低温热液型矿床。通过对5个钻孔进行短波红外测量,发现钻孔中的蚀变矿物主要有绢(白)云母、钠云母(富Na云母)、伊利石和蒙脱石,并在垂向形成绢(白)云母→绢(白)云母+钠云母+蒙脱石+伊利石→绢(白)云母+伊利石→绢(白)云母的组合特征。通过总结归纳蚀变矿物分布、分带特征并与地质编录相结合,构建了基于短波红外技术的斯弄多找矿勘查模型。笔者在数据分析与模型构建中发现:(1)伊利石-蒙脱石混合矿物组成是寻找深部及外围矿体的重要线索;(2)绢(白)云母属于成矿前期的蚀变,与矿体之间的关系不明显;(3)矿床深部表现为两种不同的化学反应:SW方向深部反映了绢云母被交代形成伊利石的过程;NE方向深部表现为绢(白)云母二八面体结构的变化;(4)未被剥蚀的青磐岩化带是寻找浅成低温热液型金矿的主要依据。     

Application of Geochemistry and VNIR Spectroscopy in Mapping Heavy Metal Pollution of Stream Sediments in the Takab Mining Area, NW of Iran

This study considered the possibility of using visible and near infrared (VNIR) spectral absorption feature parameters (SAFPs) in predicting the concentration and mapping the distribution of heavy metals in sediments of the Takab area. In total, 60 sediment samples were collected along main streams draining from the mining districts and tailing sites, in order to measure the concentration of As, Co, V, Cu, Cr, Ni, Hg, Ti, Pb and Zn and the reflectance spectra (350–2500 nm). The quantitative relationship between SAFPs (Depth500nm, R610/500nm, R1344/778nm, Area500nm, Depth2200nm, Area2200nm, Asym2200nm) and geochemical data were assessed using stepwise multiple linear regression (SMLR) and enter multiple linear regression (EMLR) methods. The results showed a strong negative correlation between Ni and Cr with Area2200nm, a significant positive correlation between As and Asym2200nm, Ni and Co with Depth2200nm, as well as Co, V and total values with Depth500nm. The EMLR method eventuated in a significant prediction result for Ni, Cr, Co and As concentrations based on spectral parameters, whereas the prediction for Zn, V and total value was relatively weak. The spatial distribution pattern of geochemical data showed that mining activities, along with the natural weathering of base metal occurrences and rock units, has caused high concentrations of heavy metals in sediments of the Sarough River tributaries.     

长江中下游六省大气甲烷柱浓度时空分布

甲烷(CH4)是造成气候变暖的主要温室气体之一。为了了解长江中下游水稻种植区CH4浓度的分布情况,本次研究基于温室气体观测卫星(greenhouse gases observing satellite,GOSAT)和大气红外探测仪(atmospheric infrared sounder,AIRS)卫星反演的数据产品,对我国长江中下游六省大气CH4柱浓度的时空分布特征进行了研究。研究结果表明,由GOSAT反演的长江中下游六省大气CH4浓度呈逐年增长趋势,其年均浓度由2011年的1817×10^?9增长至2018年的1875×10^?9,高于东三省、华北平原和全国平均水平。区域平均年增长量为8.2×10^?9 a^?1。各省年际增长幅度略有差异,纬度偏低的江西、湖南和浙江三省大气CH4浓度高且增长量偏大,纬度偏高的湖北、安徽和江苏三省大气CH4浓度略低且增长量偏小。长江中下游六省大气CH4呈现较强的季节变化特征,湖北、湖南、江西和浙江峰值出现在9月,安徽、江苏峰值出现在8月。垂直方向上长江中下游六省CH4浓度随气压降低,浓度逐渐减小,呈现出明显的季节变化特征,近地面层GOSAT反演的最高值出现在夏季,最低值出现在春季;高层最高值出现在秋季,最低值出现在春季。AIRS反演的大气CH4浓度空间分布上北高南低,与GOSAT反演结果不一致,可能由于AIRS主要反映了对流层中层大气状况而GOSAT更多的反映了近地面层大气CH4的变化。其垂直方向上呈现高度越高,浓度越低,不同高度上秋季浓度均最高。     

Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.     

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。     

土壤中总有机碳环境标准样品研制

土壤环境标准样品是土壤生态环境监测质量控制的重要技术工具。目前,土壤中总有机碳环境标准样品仍为中国环境标准样品体系的空缺,特别是配套燃烧氧化-非分散红外法的土壤标准样品一直未曾问世。本文以有机碳含量较高的农用地土壤为原材料,经干燥、研磨、混匀、装瓶、灭菌等加工步骤,制备获得土壤中总有机碳环境标准样品。分层随机抽取10瓶样品进行均匀性检验,经评价统计量F小于临界值F_(0.05)(9,10),瓶间均匀性相对不确定度(u_(bb))为1.5%,样品均匀性良好。在室温避光保存条件下,对样品进行了18个月的稳定性检验,稳定性相对不确定度(u_(lts))为1.2%,样品具有良好稳定性。由中国11家实验室采用燃烧氧化-非分散红外法和重铬酸钾容量法进行协作定值,通过对检测结果的数理统计分析,样品量值评定结果为(25.2±1.4)mg/g。该标准样品为采用燃烧氧化-非分散红外法参与定值的土壤中总有机碳环境标准样品,可作为土壤中总有机碳测定标准方法配套的实物标准,满足土壤生态环境监测及相关研究需求,且与国外同类样品具有可比性。     

新疆奇台县黄羊山石墨矿床特征、物质来源及成因

黄羊山石墨矿床位于新疆东准噶尔造山带南部的卡拉麦里地区东南段,是近年来新发现的国内外首个产于花岗岩体中的超大型石墨矿床。成矿地质条件、矿床地质特征研究表明,该矿床与黄羊山碱性花岗岩体具有密切的时空及成因联系,矿石具独特的球状构造,球体中石墨与长英质矿物及磁黄铁矿、黄铜矿等金属硫化物密切共生。为确定黄羊山石墨矿床的成因和成矿物质来源,本文开展了球状矿石中的石墨拉曼光谱分析和C同位素测试,对与石墨密切共生的金属硫化物开展S-Pb同位素分析。结果表明,黄羊山矿床球状矿石不同部位石墨的拉曼谱峰相似,显示具有很高的结晶程度,估算结晶温度为750～800℃;7件石墨样品的δ~(13)C值在-19.27‰～-19.90‰,分布非常集中,介于岩浆碳值和有机碳值之间,表明具有两者的混合来源。4件磁黄铁矿样品的δ~(34)S值集中在-2.3‰～-2.9‰之间,接近原始地幔值;在Pb同位素构造环境判别图解上,Pb同位素比值(~(206)Pb/~(204) Pb=18.114～19.040,~(207)Pb/~(204) Pb=15.448 ～ 15.543,~(208) Pb/~(204)Pb=38.253～38.915)显示较好的线性关系,延伸方向与地幔演化曲线的延伸方向基本一致;S-Pb同位素测试结果表明,与石墨共生金属硫化物具有幔源特征。综合黄羊山矿床成矿地质条件、成矿特征、石墨及共生硫化物的物质来源等研究结果,本文初步认为,黄羊山石墨矿床形成于碱性花岗岩的岩浆作用阶段,矿石中的金属硫化物来自岩浆混合作用中的幔源基性端元,碳质由于岩浆同化混染作用达到饱和,在硫化物的催化下沉积形成石墨。     

热红外遥感技术在江西寻乌地区地热勘查中的应用

热红外遥感是地热资源勘查中的常用技术,对江西寻乌地区的Landsat 8热红外影像采用单窗算法,根据MODIS影像计算大气水汽含量,并逐步获取反演参数,得到地表温度反演结果;利用MOD11_L2地表温度产品对结果进行对比分析,验证反演有效性。通过对已有地热资料和地质构造背景的研究,总结地热形成的有利构造条件,分析地表反演温度与已有地热及断裂构造之间的空间关系,建立地热异常区圈定依据,并剔除假异常,最终在研究区圈定了11个潜在地热异常区,为该区地热勘查提供依据。     

短波红外光谱、X射线荧光光谱、黄铁矿热电性分析在胶东新城金矿田深部找矿中的应用

胶东半岛是我国最重要的金矿集区之一,其矿床是典型受北东向断裂构造(焦家断裂带、三山岛断裂带和招平断裂带),以及次生断裂构造(如望儿山断裂和灵北断裂等)控制的矿床类型。前人在该区域做了大量研究,但主要集中在地表和浅层成矿段,对于深部成矿规律与预测的研究相对较少。新城金矿田是胶东半岛的特大型金矿之一,由新城矿床、曲家矿床和招贤矿床三部分组成。由于受到焦家断裂带控制,在招贤矿区中的科研深钻达到2 500 m以下,为我们研究深部成矿规律提供了良好的样品。本文通过该地区蚀变矿物的短波红外光谱特征(short-wave infrared spectroscopy,SWIR),并结合X 射线荧光光谱(X-ray fluorescence spectrometry,XRF)法和黄铁矿热电性法,选取该地的不同成矿阶段的蚀变岩石和典型载金矿物黄铁矿,并在三维环境中,定量化分析了主要的蚀变矿物——白云母族的短波红外光谱的特征值,揭示其找矿规律与指示意义,进一步提取矿床中蚀变矿物的找矿标志。研究结果表明:(1)在靠近焦家主断裂构造蚀变岩型矿体的位置,伊利石结晶度(≥1.2)和绢云母Al—OH吸收位置(≥2 205 nm)偏高,而在远离焦家主断裂构造蚀变岩型矿体的位置伊利石结晶度和绢云母Al—OH吸收位置偏低,分别为0.2~1.2和2 198~2 205 nm。(2)X 射线荧光光谱结果提取了该地区20种元素含量,通过对元素的主成分分析和聚类分析, Al—OH吸收峰位置偏移与Al、K、Si含量变化有一定相关性。(3)黄铁矿热电性导型在近焦家主断裂构造蚀变岩主要为P型,远离主断裂的主要为N型。在新城矿区的Ⅰ号和Ⅴ号矿体的顶部到底部整体呈现N-P→P→P-N→N→N-P→P-N和P-N→N-P的规律;在招贤矿区中绝大部分是P型。剥蚀度整体处于在25%~50%,因此在新城矿区约-800 m以下和招贤矿区约-1 500 m以下,仍有较好的深部找矿前景。整体上P型黄铁矿成矿温度主要为180~250 ℃,N型成矿温度主要区间值在380~460 ℃;利用温度场进行三维插值建模,其与三维矿体品位模型空间展布趋势一致。本文综合研究方法为深部矿产资源评价提供新的研究思路,将光谱数据、地化数据等多维度信息集成整合,同时使用三维模型可视化功能,对于矿产模型定量化构建具有重要参考价值。     

An Operational Precipitable Water Vapor Retrieval Algorithm for Fengyun-2F/VISSR Using a Modified Three-Band Physical Split-Window Method

The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm.