Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

航空短波红外分光谱遥感技术直接寻找油气藏的有效性及应用实例

采用航空短波红外分光谱遥感技术，在新疆准噶尔盆地和塔里木盆地某些油气区，进行直接寻找油气资源的试验研究后发现，油气区含油岩系，油气藏上方盖层土壤的光谱在２３００和２３５０ｎｍ波段具有双吸收特征。     

RS和GIS结合的初步尝试

通过对航空遥感图像物体特征（色调、形状、大小、阴影、纹理及其相互关系）的提取，采用人机交互和自动识别的方法进行遥感航片的综合分析和利用，是合肥市规划与建设管理信息系统的一个重要内容。ＡＲＣ／ＧＲＩＤ模块的优势在于一对于栅格数据进行显示和查询；对于栅格数据进行算术、逻辑、关系、赋值等操作；对数据进行管理；其分析功能很强，可进行环境分析、社会分析、水文分析、经济分析；建立模型。通过图象分类处理，可将城市绿化、江河、城市主干道、建筑物分类，并对城市绿化进行区域统计，对江河、日照进行分析和对所分割的地块进行检索分析     

四川新康风化淋滤型海泡石的热相变研究

以四川新康风化淋滤型海泡石为研究对象，利用X射线衍射分析和红外光谱分析技术，对海泡石的热相变过程及特征进行了研究。结果发现，四川新康风化淋滤型海泡石的相变过程与沉积型、热液型海泡石相变过程明显不同，其相变过程可以划分为两个阶段：800℃以下保持海泡石相；800℃以上海泡石相转化为斜顽辉石相。     

利用AMTIS数据反演植被和土壤温度

遥感陆面温度 (LST)是目前遥感界面临的重要课题 ,组分温度反演则为LST反演的主攻目标。如果混合像元组分间的温度及发射率存在明显差别 ,就可以从多角度热辐射亮度变化中分离出组分温度的信息。在热辐射矩阵模型的基础上 ,讨论了确定可反演参数和反演组分温度的方法 ,并以AMTIS多角度热红外图像为数据源 ,在进行几何和大气纠正后 ,尝试利用矩阵反演方法分解混合像元中的植被和土壤温度。误差分析表明土壤温度反演结果较好 ,但植被温度的反演精度不高     

利用热红外温差识别沙尘

沙尘识别是沙尘灾害监测和沙尘气溶胶特性研究的首要工作。利用辐射传输方程进行了沙尘气溶胶的辐射计算 ,对不同沙尘气溶胶光学厚度下的热红外通道温差ΔT(T11μm-T12 μm)的变化进行了分析。理论分析表明 ,利用热红外通道的温度差ΔT进行陆地沙尘识别是可行的。并利用NOAA AVHRR热红外通道的温度差ΔT进行了陆地沙尘识别的实验 ,经与地面气象站实测的沙尘天气现象相比较 ,结果一致。     

Polymorphic phase transition in Superhydrous Phase B

We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction, Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures (down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering occurs not only at the Mg sites but also at the hydrogen sites.     

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.     

Quantitative estimation of submarine groundwater discharge using airborne thermal infrared data acquired at two different tidal heights

Submarine groundwater discharge (SGD) plays an important role in coastal biogeochemical processes and hydrological cycles, particularly off volcanic islands in oligotrophic oceans. However, the spatial and temporal variations of SGD are still poorly understood owing to difficulty in taking rapid SGD measurements over a large scale. In this study, we used four airborne thermal infrared surveys (twice each during high and low tides) to quantify the spatiotemporal variations of SGD over the entire coast of Jeju Island, Korea. On the basis of an analytical model, we found a linear positive correlation between the thermal anomaly and squares of the groundwater discharge velocity and a negative exponential correlation between the anomaly and water depth (including tide height and bathymetry). We then derived a new equation for quantitatively estimating the SGD flow rates from thermal anomalies acquired at two different tide heights. The proposed method was validated with the measured SGD flow rates using a current meter at Gongcheonpo Beach. We believe that the method can be effectively applied for rapid estimation of SGD over coastal areas, where fresh groundwater discharge is significant, using airborne thermal infrared surveys.