Solute concentrations in the lower niger river and the source rock contribution

Water quality analyses for the Niger River for the 1980/81 hydrological year are presented. The samples were collected from the main river at Lokoja, and from two main tributaries, the Kaduna and the Benue Rivers. Different water types were distinguished by the concentrations of major ions. The type Ca > Na > Mg > K - HCO₃ > SO₄ > Cl was represented at all stations during at least part of the year. Chloride was found to dominate the sulphate ion in the Kaduna and Niger, while the Benue maintained a higher concentration of sulphate relative to chloride all year round. Distinct patterns of seasonal variation in the ion concentrations were observed, particularly for the samples collected at Lokoja. Low ion concentrations were prominent during periods of high discharge, while low flow periods coincided with high dissolved ion concentrations. The contribution of rainwater to the total dissolved solids in the river waters was assessed indirectly using rainwater chemistry data from the Gulf of Guinea. The estimated rainwater contribution to the Lower Niger amounts to 5.15 mg 1^?1. Geochemical weathering calculations involving reactions of the four major minerals of granitic rocks - anorthite, biotite, albite, and K-feldspar - with carbon dioxide and water, can account for the average water composition of the Lower Niger. The proportion of the ionic components was also related to the occurrence of the respective element in the minerals.     

The origin and abundances of the chemical elements revisited

Summary The basic scheme of nucleosynthesis (building of heavy elements from light ones) has held up very well since it was first proposed more than 30 years ago by E.M. Burbidge, G.R. Burbidge, A.G.W. Cameron, W.A. Fowler, and F. Hoyle. Significant advances in the intervening years include (a) observations of elemental and a few isotopic ratios in many more extrasolar-system sites, including metal-poor dwarf irregular galaxies, where very little has happened, and supernovae and their remnants, where a great deal has happened, (b) recognition of the early universe as good for making all the elements up to helium, (c) resolution of heavy element burning in stars into separate carbon, neon, oxygen, and silicon burning, with fine tuning of the resulting abundances by explosive nucleosynthesis in outgoing supernova shock waves, (d) clarification of the role of Type I supernovae, (e) concordance between elements produced in short-lived and long-lived stars with those that increased quickly and slowly over the history of the galaxy, and (f) calibration of calculations of the evolution and explosion of massive stars against the detailed observations of SN 1987A. The discussion presupposes a reader (a) with some prior knowledge of astronomy at the level of recognizing what is meant by an A star and an AGB star and (b) with at least a mild interest in how we got to where we currently are.     

Perturbation of nuclear decay rates during the solar flare of 2006 December 13

Recently, correlations have been reported between fluctuations in nuclear decay rates and Earth–Sun distance, which suggest that nuclear decay rates may be affected by solar activity. In this paper, we report the detection of a significant decrease in the decay of ⁵⁴Mn during the solar flare of 2006 December 13, whose X-rays were first recorded at 02:37 UT (21:37 EST on 2006 December 12). Our detector was a 1 μCi sample of ⁵⁴Mn, whose decay rate exhibited a dip coincident in time with spikes in both the X-ray and subsequent charged particle fluxes recorded by the Geostationary Operational Environmental Satellites (GOES). A secondary peak in the X-ray and proton fluxes on December 17 at 12:40 EST was also accompanied by a coincident dip in the ⁵⁴Mn decay rate. These observations support the claim by Jenkins et al. that nuclear decay rates may vary with Earth–Sun distance.     

Supersoft X‐ray sources and the progenitors of Type Ia supernovae

Supersoft X‐ray sources have been proposed as one of the major channels to produce Type Ia supernovae (SNe Ia). However, the true nature of the progenitors has remained an unsolved problem. In this review I summarize the present status of our understanding of SN Ia progenitors, the main classes of progenitor models and recent observational constraints. At present, neither the single‐degenerate nor the double‐degenerate model can be ruled out, and indeed more than one channel may be required to explain the observed SN Ia diversity. Finally, I discuss the origin of the lightcurve peak – lightcurve width relation (the ‘Phillips relation’) and show that it is expected to depend on metallicity; this needs to be taken into account in high‐precision cosmological applications (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

白鹤滩水电站坝址区玄武岩水-岩作用模拟及应用研究

采用水-岩作用线型规划的模拟方法,以白鹤滩水电工程为实例,从水化学方面对坝区复杂水文地质条件作定量分析评价.建立由目标函数和约束条件方程组构成的数学模型,利用Excel规划求解的功能对其进行求解,为评价坝区水文地质条件提供了依据.     

Determining the direction of contact metamorphic fluid flow: an assessment of mineralogical and stable isotope criteria

ABSTRACT One-dimensional fluid advection-dispersion models predict differences in the patterns of mineralogical and oxygen isotope resetting during up- and down-temperature metamorphic fluid flow that may, in theory, be used to determine the fluid flow direction with respect to the palaeotemperature gradient. Under equilibrium conditions, down-temperature fluid flow is predicted to produce sharp reaction fronts that separate rocks with isobarically divariant mineral assemblages. In contrast, up-temperature fluid flow may produce extensive zones of isobarically univariant mineral assemblages without sharp reaction fronts. However, during contact metamorphism, mineral reaction rates are probably relatively slow compared with fluid velocities and distended reaction fronts may also form during down-temperature fluid flow. In addition, uncertainties in the timing of fluid flow with respect to the thermal peak of metamorphism and the increase in the variance of mineral assemblages due to solid solutions introduce uncertainties in determining fluid flow directions. Equilibrium down-temperature flow of magmatic fluids in contact aureoles is also predicted to produce sharp δ¹⁸O fronts, whereas up-temperature flow of fluids derived by metamorphic devolatilization may produce gradational δ¹⁸O vs. distance profiles. However, if fluids are channelled, significant kinematic dispersion occurs, or isotopic equilibrium is not maintained, the patterns of isotopic resetting may be difficult to interpret. The one-dimensional models provide a framework in which to study fluid-rock interaction; however, when some of the complexities inherent in fluid flow systems are taken into account, they may not uniquely distinguish between up- and down-temperature fluid flow. It is probably not possible to determine the fluid flow direction using any single criterion and a range of data is required.