White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

变形监测基准点的稳定性检验

基准点的稳定性评价，是变形观测数据处理时不可忽视的重要内容。该文对基准点构网和不构网2种情况时的数据处理方法进行了探讨。     

会泽超大型铅锌矿床成矿时代研究

云南会泽超大型铅锌矿床由麒麟厂和矿山厂两个独立的铅锌矿床组成。利用两组同源矿物组合Rb Sr等时线方法测定了麒麟厂6号矿体的成矿时代,测定结果分别为(225 1±2 9)Ma和(225 9±3 1)Ma,根据已知的分布于该矿床北部和西南部分布的峨眉山玄武岩成岩时代为250Ma左右,有多个火山喷发旋回,显示多期次的喷发活动,认为川—滇—黔成矿区内铅锌成矿作用与峨眉山玄武岩岩浆活动存在成因联系。     

东胜区污染状况分析

文章利用东胜区主要污染源排放情况以及2005年9月1日-2007年8月31日每日SO2、NO2、PM10浓度监测值和2005-2007年SO2、NO2、PM10平均值,分析了东胜区主要污染类型、污染物来源以及东胜区近3年SO2、NO2、PM10监测值日、月、季、年分布特征和变化规律;提出了消减大气污染物排放的对策。     

Performance of small-scale irrigation schemes in Lake Tana Basin of Ethiopia: technical and socio-political attributes

This study was conducted to investigate technical and socio-political attributes that lead to the underperformance of two selected irrigation schemes (Shina and Bebeks) in the Lake Tana floodplains, Ethiopia. Irrigation application efficiency (AE) at nine experimental fields showed a wide range, from 20 to 80%, but was mostly between 40 and 60%. Irrigation water-use efficiency (IWUE) varied from 1.9 to 7.2 kg m^?3 for onion and 0.9 to 1.2 kg m^?3 for maize. The lined and earthen canal conveyance losses in Bebeks were 0.037 and 0.047 l s^?1 m^?1, whereas in Shina they were 0.033 and 0.044 l s^?1 m^?1, respectively. The overall consumed ratio (OCR) of water was 0.58 for Bebeks and varied from 0.73 to 1.2 in Shina. Both schemes are performing below the standard based on technical performance indicators. Irrigation water user associations (WUAs) were not implemented, but irrigation committees (ICs), composed of local political leaders, are managing both schemes. Canal and reservoir sedimentation from erosion of upstream catchment areas during the rainy season was the major problem.     

银河系厚盘的本地空间密度

本文利用北银极天区的现代恒星计数资料，采用标准的银河系模型，通过恒星统计积分方程对参数值组合模型的亮度函数进行计数分析，证明了银河系厚盘恒星成份存在的必要性，并进一步得出太阳附近厚盘成份的空间密度的最佳期望值为薄盘密度的０．０４１．     

矿物热敏参数测试仪及其在地质找矿中的应用

介绍了国内外第一台矿物热敏参数测试仪研制的原理、应用范围和对一些金属矿物、半导体矿物的测试情况以及仪器在浙江、赣南等地区金矿找矿中的初步应用。     

海洋经济可持续发展评价指标体系探讨

在讨论比较相关研究成果的基础上,从海洋经济可持续发展的内涵出发,建立海洋经济可持续发展能力的概念模型,探讨海洋经济可持续发展评价指标体系的特征,构建海洋经济可持续发展评价指标体系的基本框架,并对辽宁省海洋经济可持续发展进行实例应用研究,提出今后需要继续深入研究的问题.应用结果表明:构建的海洋经济可持续发展评价指标体系能够有效地反映海洋经济可持续发展的特征与演变轨迹,具有一定的有效性和实用性.     

城市创意产业空间动态集聚演化的计算与可视优化方法

基于人文地理视角下的城市创意产业图像可视化分析对城市深层次空间综合和区域创新发展具有重大意义。但Swarm群智能动态时空建模难以满足创意产业空间集聚的可视化发展。本文研究目标是,从城市区域创意产业空间聚类影响因素指标出发,创新性地提出区域空间动态集聚轨迹算法（Density-Based Interest Spatial Clustering of Path,DBICP）,并与计算机浏览器共建聚类可视化图像,为城市管理提供决策依据。首先,根据影响因素指标体系,利用2014—2018年空间卡口流量数据和产业指标数据进行预处理,构建空间标准聚类算法DBSCAN。然后,对其进行聚类密度分级优化形成全新DBICP算法并得出初步轨迹图像。最后,通过源码转译实现了浏览器界面下空间动态集聚轨迹图像的输出。结果表明：以上海市为例,普陀区、浦东新区、徐汇地区的创意产业空间分布形成了3种不同的聚类模式,并相应提出了分摊、均布、虹吸的管控策略。此方法克服了传统图像的聚类分级和轨迹测量的缺失,可以有效地从指标数据中发现图像轨迹聚类信息,体现了地理信息科学和人文社会学科的交叉融合。也为大数据动态图像的集聚方法提供了全新视角和借鉴价值。     

山东省单县煤田张集井田3煤层煤质特征及工业利用方向

山东省单县煤田张集井田主采煤层为3煤,该煤层结构简单,煤质优良,为低灰、低硫、强黏结性、成焦率较高的焦煤（JM25）,次为肥煤（FM26）和1／3焦煤（1／3JM35）,是山东省稀缺的优质炼焦用煤。煤质的综合研究表明,为达到珍惜和合理利用资源,并使其效益最大化,该煤层应以冶金和铸造用焦为主要加工利用方向。