Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.     

白云石的微化反应与有序度

试验证实白云石的微化反应特征明显受有序度的影响，白云石粉末在稀盐酸中的起泡程度随有序度的降低而加剧，在茜素红溶液中的染色程度和速度随有序度的降低而增强。低有序度白云石或完全无序的原白云石，其微化反应与方解石极为相似，反之，高有序度白云石与菱镁矿相似。另外还讨论白云石微化反应的机理。     

Coincidence of cadmium and antibiotic resistance in New York Bight apex benthic microorganisms

Microorganisms resistant to 1–500 ppm cadmium were isolated over an 11 month period from sediments at the sewage sludge, dredge spoils and industrial acid waste disposal sites, as well as at an estuarine outflow to the New York Bight apex. Tests for antibiotic resistance in these isolates revealed that 94% of the isolates were resistant to one or more antibiotics and that 91% of the original isolates could be characterized by multiple drug resistance. Different selective pressures may account for the various genera and antimicrobial resistance patterns observed. The possibility of extrachromosomal linkage of cadmium and streptomycin resistance is discussed.     

Recurrence of major flank landslides during the last 2-Ma-history of Reunion Island

New detailed swath bathymetry and backscatter data corroborate the existence of four large bulges on the submarine flanks of Reunion Island. These fan-shaped promontories are 20–25 km wide at the coastline and 70–150 km across the seafloor 40–50 km offshore. Their surfaces are characterized by a speckle sonar pattern, indicating the presence of large blocks up to several hundred meters across. Each bulge results from the superposition of multiple landslide deposits whose older ones are dissected and delimited by erosive channels as much as 200 m deep and 20 km long. The submarine flanks of Reunion Island are thus mostly built by accumulation of debris avalanche fans. Morphologic and geologic evidence define large subaerial source areas for these mass-wasting events. In particular, inferred headwalls of most landslides having affected the Piton des Neiges massif generally coincide with the boundaries of its cirques (Mafate, Salazie, and Cilaos), whereas recurrent landslides have resulted in the formation of large concentric amphitheatre structures through the Piton de la Fournaise massif. Thus, about 15 slide events accompanied growth of the Reunion Island shield since 2 Ma.Editorial responsibility: J. Stix     

Analyse isotopique de l'air piégé dans la glace pour quantifier les variations de température

Isotopic measurements in polar ice core have shown a succession of rapid warming periods during the last glacial period over Greenland. However, this method underestimates the surface temperature variations. A new method based on gas thermal diffusion in the firn manages to quantify surface temperature variations through associated isotopic fractionations. We developed a method to extract air from the ice and to perform isotopic measurements to reduce analytical uncertainties to 0.006 and 0.020$\text{‰}$ for δ¹⁵N and δ⁴⁰Ar. It led to a 16±1.5 °C surface temperature variation during a rapid warming ($\text{?70}\text{000}$ yr). To cite this article: A. Landais et al., C. R. Geoscience 336 (2004).     

The crystalline complexes of Hamadan (Sanandaj–Sirjan zone, western Iran): metasedimentary Mesozoic sequences affected by Late Cretaceous tectono-metamorphic and plutonic events

The Hamadan area is characterised by various metamorphic rocks where the slates yielded Jurassic fossils. The entire column, representing the Mesozoic from at least the Jurassic to the Mid-Cretaceous, has been affected by tectono-metamorphic events and the emplacement of Late Cretaceous granitic rocks. A timing of these events is based on the ⁴⁰K–⁴⁰Ar ages carried mainly on separated amphiboles, biotites and muscovites, and interpreted as the ages of their isotopic closure. Results are ranging between 91 and 70 Ma. To cite this article: A. Baharifar et al., C. R. Geoscience 336 (2004).

Résumé

La région de Hamadan expose des roches métamorphiques dont les termes les moins transformés contiennent des fossiles jurassiques. Au cours du Crétacé supérieur, elle a été affectée par un événement tectono-métamorphique régional et elle a été le siège d'une activité plutonique. Les résultats des datations ⁴⁰K–⁴⁰Ar des amphiboles et des micas séparés des roches métamorphiques et plutoniques qui s'étagent entre 91 et 70 Ma montrent l'importance de ces événements et leur étalement au cours du Crétacé supérieur. Pour citer cet article : A. Baharifar et al., C. R. Geoscience 336 (2004).     

Discovery of the largest impact crater field on Earth in the Gilf Kebir region, Egypt

Using orbital imaging radar, we have detected a large number of circular structures in the southwestern Egyptian desert, covering more than 4500 km² close to the Gilf Kebir plateau in sandstones of Upper Cretaceous. Fieldwork confirmed that it is a new impact crater field: 13 craters from 20 m to 1 km in diameter were studied. The impact origin is confirmed by the observation of shock-related structures, such as shatter cones and planar fractures in quartz grains of breccia. Considering the extension of the crater field, it was possibly created by several meteorites that broke up when entering the atmosphere. To cite this article: P. Paillou et al., C. R. Geoscience 336 (2004).

Résumé

À partir d'images satellites issues de systèmes radar, nous avons détecté un grand nombre de structures circulaires dans le Sud-Ouest du désert égyptien, s'étendant sur plus de 4500 km² à l'est du plateau du Gilf Kebir, dans des grès du Crétacé supérieur. Une étude sur le terrain a permis de vérifier qu'il s'agit d'un champ d'impacts météoritiques jusque là inconnu : 13 structures, d'un diamètre compris entre 20 m et 1 km, ont été reconnues comme cratères d'impact. La présence d'un grand nombre de cônes de percussion et de brèches dans lesquelles des quartz choqués à structures planaires ont été observés confirment l'hypothèse de l'impact. Considérant l'extension du champ d'impact, il a probablement été créé par plusieurs météorites qui se sont fragmentées dans l'atmosphère terrestre. Pour citer cet article : P. Paillou et al., C. R. Geoscience 336 (2004).     

A numerical system to study the transport properties in the Ria de Aveiro lagoon

This work presents results from numerical modelling studies on the hydrodynamics and sediments and passive particles transport properties in Ria de Aveiro, a shallow lagoon located on the Portuguese Northwest Atlantic coast. The hydrodynamic of the lagoon was systematically studied, from both the Eulerian and Lagragian point of view, in order to understand the overall circulation in the lagoon, characterize the dynamics of its different channels and assess the transport of suspended cohesive sediments.Responsible Editor: Hans Burchard