甘肃厂坝-李家沟超大型铅锌矿床成矿金属来源 ——来自闪锌矿原位S-Pb和Zn同位素证据

甘肃厂坝-李家沟铅锌矿床位于西秦岭多金属成矿带内的西成矿集区,为矿集区内重要的超大型铅锌矿床。矿体赋存在中泥盆统安家岔组的白云石化大理岩及石英片岩中,其成因认识一直存在争议,主要分歧集中在是同生还是后生。文章对不同成矿阶段的闪锌矿,采用多接收电感耦合等离子体质谱(MC-ICP-MS)测定Zn同位素组成、采用激光剥蚀-多接收电感耦合等离子体质谱(LA-MC-ICP-MS)原位微区分析技术测定S、Pb同位素组成,示踪成矿物质来源,并分析矿物沉淀机制,为深入理解矿床成因提供新的精细证据。研究结果显示,Ⅰ、Ⅱ、Ⅲ三个成矿阶段闪锌矿的δ⁶⁶Zn分别为0.08‰~0.29‰,平均0.20‰;0.19‰~0.37‰,平均0.30‰;0.36‰~0.37‰,平均0.37‰。其中,Ⅰ阶段的闪锌矿δ³⁴S_Ⅰ值为20.9‰~26.1‰,平均24.4‰;Ⅱ阶段的闪锌矿δ³⁴S_Ⅱ值为12.2‰~21.9‰,平均19.1‰;Ⅲ阶段的闪锌矿δ³⁴S_Ⅲ值为18.2‰~24.7‰,平均21.5‰。3个阶段的矿石矿物Pb同位素组成变化不大,²⁰⁶Pb/²⁰⁴Pb为17.922~18.013,²⁰⁷Pb/²⁰⁴Pb为15.567~15.647,²⁰⁸Pb/²⁰⁴Pb为37.990~38.266。δ⁶⁶Zn同位素值显示,成矿金属早期来源于围岩海相碳酸盐岩,由于混合了岩浆热液或者是瑞利分馏作用,在成矿作用中后期δ⁶⁶Zn同位素逐渐上升。δ³⁴S同位素值显示,早期硫源主要为地层中的硫酸盐,中后期的δ³⁴S同位素值降低,可能是成矿流体中岩浆热液中的S^2-成分逐渐增多导致,闪锌矿为硫酸盐通过TSR反应沉淀成矿。Pb同位素指示成矿物质来源于上地壳,并混入了部分古老的变质基底的成分。笔者研究发现,厂坝-李家沟铅锌矿的成矿机制为不同来源的流体混合,随着pH值、成矿流体的温度发生变化而沉淀成矿。     

滇东南都龙Sn-Zn多金属矿床交生硫化物微区主量元素、硫同位素特征及成因研究

都龙Sn-Zn多金属矿床位于滇东南老君山锡锌钨多金属成矿区南部,是中国3大锡石硫化物矿床之一。该矿床发育闪锌矿-黄铜矿-磁黄铁矿密切共生结构,即硫化物交生结构。文章利用电子探针和LA-MC-ICP-MS对具有交生结构的闪锌矿-黄铜矿-磁黄铁矿和毒砂进行了微区主量元素和硫同位素测试,以期明确其成因及硫的来源。主量元素测试结果显示,闪锌矿中的w(Zn)为52.23%~57.22%,w(S)为33.06%~36.10%,w(Fe)为9.92%~12.24%,w(Cu)为0.11%~0.30%;黄铜矿中的w(Cu)为33.95%~35.08%,w(S)为33.49%~35.27%,w(Fe)为30.74%~31.41%,w(Zn)为0.04%~1.50%;磁黄铁矿中的w(Fe)为49.30%~51.94%,w(S)为38.36%~39.69%,w(Zn)为9.35%~11.01%,w(Cu)为0.05%~0.15%。磁黄铁矿和黄铜矿包裹体边部和核部成分均一,且投影点全部落在固溶体出溶区域,说明都龙矿床交生闪锌矿-黄铜矿-磁黄铁矿是固溶体分离成因。原位S同位素分析结果显示,闪锌矿的δ³⁴S为0.9‰~3.2‰,磁黄铁矿的δ³⁴S为0.6‰~2.1‰,毒砂的δ³⁴S为2.9‰~4.2‰,黄铜矿的δ³⁴S为0.6‰~2.8‰,均显示为岩浆来源特征。主量元素温度计估算的闪锌矿-黄铜矿的形成温度介于285~394℃,指示该矿床主要硫化物形成于中高温阶段。     

钻孔应变观测原位标定方法研究进展

钻孔应变观测的原位标定是制约钻孔应变定量观测理论与技术发展的基础性问题。为推进钻孔应变观测在地球动力学研究中的应用,从标定模型、参考应变信号等方面系统总结钻孔应变观测原位标定方法研究的最新进展,指出钻孔应变观测原位标定中存在的主要问题,并展望今后的发展方向。     

了墩隆起西缘地浸砂岩铀矿成矿水动力条件的遥感处理与分析

鉴于吐哈盆地地表植被覆盖稀少,故利用遥感技术提取亮度、绿度、湿度指数并加以合成,以反映盆地及其周边的反射蒸腾强度、植被覆盖程度和土壤湿度的信息,显示出盆地排泄构造的空间展布特征,进而分析成矿期间研究区的水动力环境,并划分出主要补给区(觉罗塔格山、天山山脉)和排泄区(鲁克沁附近及位于两者之间的径流区)。利用吐哈盆地现代三维地形图,结合盆地常规地质研究成果,反演成矿期间研究区及其周围地形高差特点,揭示出了墩隆起和西缘艾丁湖斜坡带的长期存在,以及它们影响了盆地的水动力系统,提供了南高北低长径流范围的成矿地形优势。     

返包式土工格栅加筋土高挡墙现场试验研究

为了研究返包式土工格栅加筋土高挡墙结构的受力、变形状态,分析其作用机理,进行了包括加筋土墙体基底应力、墙背侧向土压力、拉筋拉力和墙面水平变形等内容的现场试验,研究了加筋土墙体基底垂直应力、不同层位的拉筋拉力沿筋长的分布规律,加筋土挡墙潜在的破裂面位置,墙背侧向土压力沿墙高的分布规律以及墙面水平变形规律。测试结果表明,加筋土挡墙基底垂直土压力沿土工格栅拉筋长度方向呈非线性分布,最大值发生在拉筋中部附近,向拉筋两端方向逐渐减少;实测墙背侧向土压力沿墙高呈非线性形式分布,其值小于主动土压力;上部墙体拉筋应变沿筋长呈单峰值分布,下部墙体拉筋应变沿筋长呈双峰值分布;上部墙体潜在破裂面形状与“0.3H法”接近,而下部墙体潜在的破裂面形状与朗肯主动土压力理论接近;施工期墙面最大水平变形位置在墙高的下部,竣工后墙面最大水平变形发生在墙顶处等结论。     

随机镇定与反镇定概述

本文概述了随机镇定与反镇定理论的研究现状.主要回顾了一个微分方程的随机镇定与反镇定普遍理论及其发展,并围绕该理论的应用和扩展从四个方面阐述连续时间系统噪声镇定理论的当前发展概况.此外,本文还概述了离散时间系统随机镇定方面的最新进展.     

随机非完整系统控制问题综述和展望

随着随机非线性控制的发展,随机非完整系统的控制引起了学者们的注意.本文首先探讨了随机非完整控制系统的镇定问题,涉及严反馈链式系统的反馈镇定和不满足严反馈的移动机器人镇定等;其次,介绍了该系统跟踪控制及现状;最后,在总结现有结果的基础上,分析了随机非完整系统发展的趋势,给出了6个可能的研究方向.     

Characteristics of thawed interlayer and its effect on settlement beneath embankment in permafrost regions—A case study for the Qinghai-Tibet Highway

Based on ground temperatures and deformations monitored at the Xieshuihe site along the Qinghai-Tibet Highway(QTH)in permafrost regions from 2004 to 2015,variation of artificial permafrost table(APT),maximum frozen depth(MFD),thawed interlayer thickness(TIT)and ground temperature beneath embankment is analyzed,respectively.The results indicate that under the embankment,the change of APT occurred from October to December of that year and presented a deepening trend.The change of MFD occurred from April to June of that year with no obvious change trend,and TIT had an increasing trend year by year,which mainly resulted from the deepening artificial permafrost table.Mean annual ground temperature at 0.5 m depth was 3.91°C higher beneath the embankment center than that under the natural field.The rising ground temperature at shallow layer of embankment resulted in the development of thawed interlayer beneath the embankment and warming of underlying permafrost.Embankment settlement is closely associated with TIT.Greater settlement easily occurs when permafrost with higher ice content exists under the thawed interlayer,and in turn the settlement is smaller when permafrost with lower ice content exists under the thawed interlayer.     

Changes in Surface Morphology of Calcite Exposed to the Oceanic Water Column

Reactions occurring on the surfaces of biogenic carbonate minerals can have important consequences for the biogeochemical cycle of carbon. In this study, carbonate mineral surface reactions with ambient seawater were investigated by atomic force microscopy (AFM). A sampling method was developed in which calcite surfaces were hung at discrete depths on a sediment trap array line for a three-day deployment period in subtropical North Pacific waters. Changes in surface morphologies were examined at nanometer resolution and evaluated using as a constraint the depth profile of calcite saturation in these waters. Evidence suggests that: (1) organic films which develop on carbonate surfaces exposed to shallow seawater may be responsible for the oversaturated state of the upper oceanic water column, (2) dissolution of carbonate minerals within the shallow warm layer of the ocean could be responsible for part of the alkalinity anomaly observed in the North Pacific.     

Stabilization Mechanism and Effect Evaluation of Stabilized Silt with Lignin Based on Laboratory Data

The potential of a lignin-based by-product to stabilize silt was evaluated. The physical and mechanical properties of silt in its natural state, as well as when treated with varying proportions of lignin, were analyzed. The parameters tested include the particle size distribution, Atterberg limits, compaction characteristics, unconfined compressed strength, pH value, and electrical resistivity. To understand the stabilization mechanism of lignin-treated silt at a microscopic level, scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis, and Fourier transform infrared resonance (FTIR) spectroscopy were also carried out on lignin and representative samples after 28 days of curing. The results indicate that the engineering properties of silt are improved by the addition of lignin. Particle size distribution is changed and plastic index is reduced from 8.8 to 7.7. After improvement, the maximum dry density increases and the optimum moisture content decreases, while the change of dry density with moisture content is enhanced. The treated silt has greater strength performance than the natural silt in terms of unconfined compressed strength and all of the samples have a pH value lower than 10. Curing time and moisture content have a significant impact on unconfined compressed strength but almost no effect on pH. Micro-chemical analysis reveals that the improvement of performance exhibited by lignin-treated silt may be mainly attributed to the cation exchange and the formation of more stable soil structure by lignin cementing. The stabilization mechanism of lignin-treated silt was proposed according to the results of chemical analysis. It is shown that lignin-based stabilizers have potential to improve the engineering properties of silt.