Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

The Global Distribution of Diapycnal Mixing and Mixing Coefficient Tensor in the Upper 2000m Ocean from Argo Observations

Diapycnal Mixing (DM) within the upper 2000m of the global ocean is calculated by a fine-scale parameterization using the multiyear-mean density gridded product that created by employing all the Argo float observations to date through the recently published equation of seawater TEOS-10. The geographic distribution of Argo-derived DM derived in this study is spatial-dependent and varies with latitude and depth. The magnitude and pattern of DM is favorably validated by comparisons with previous studies. Furthermore, the mixing coefficient tensor K is calculated and analyzed. Components of the tensor fitting for the geopotential coordinate models are also presented. It is found that the tensor components in horizontal direction, K_xx and K_yy, have similar magnitude and distribution pattern. In the vertical, K_zz is enhanced over regions with rough topography and strong wind (e.g., Westerly region), suggesting agreement with previous estimates. This work presents a scheme to estimate the DM and mixing coefficient tensor using Argo observations, and offers a useful Argo-based mixing product for the purpose of promoting the study and modeling of ocean circulation and other processes.     

Interpretation of a two-point flux stencil for skew parallelogram grids

Control-volume formulations for elliptic equations often use two-point flux stencils, even for skew grids. Any two-point flux stencil may be interpreted as a multipoint flux stencil. This yields a definition of the permeability (or conductivity) tensor. Formulas for calculating the permeability tensor, based on the user-specified quantities in the two-point flux stencil, are given. Numerical test examples demonstrate the validity of the derivation.      

2019-12-26湖北应城MS4.9地震序列及发震构造讨论

从地震学和地质学的角度探讨2019-12-26应城MS4.9地震的发震构造。采用HYPO2000方法对地震序列进行重新定位,结果表明,余震主要分布在皂市断裂与长江埠断裂之间,总体呈NW向展布,与野外调查Ⅵ度烈度等震线长轴方向基本一致。采用kiwi波形拟合反演方法求解震源机制解,结果显示,主震破裂表现为走滑兼逆冲特征。节面Ⅰ走向NE,与震中以西的潜北断裂走向一致,但距离较远,且与该断裂的产状和受力方式不一致。节面Ⅱ走向NW,与皂市断裂和长江埠断裂相近。分析2条断裂的受力方式认为,在江汉盆地现今NWW向主挤压应力的控制下,皂市断裂与长江埠断裂均具有左旋走滑特征。由于2条断裂走向存在差异,在两者之间产生逆时针错转滑动,使得主震发震面走向处于2条断裂夹角中间方向;同时倾向也与实际断面存在差异,余震分布偏向主震东侧。综合分析认为,皂市断裂与长江埠断裂的构造活动共同引发本次应城地震序列。     

Understanding of hydraulic properties from configurations of stochastically distributed fracture networks

A systematic investigation of the effect of configurations of stochastically distributed fracture networks on hydraulic behaviour for fractured rock masses could provide either quantitative or qualitative correlation between the structural configuration of the fracture network and its corresponding hydraulic behaviour, and enhance our understanding of appropriate application of groundwater flow and contaminant transport modelling in fractured rock masses. In this study, the effect of block sizes, intersection angles of fracture sets, standard deviations of fracture orientation, and fracture densities on directional block hydraulic conductivity and representative elementary volume is systematically investigated in two dimensions by implementing a numerical discrete fracture fluid flow model and incorporating stochastically distributed fracture configurations. It is shown from this investigation that the configuration of a stochastically distributed fracture network has a significant quantitative or qualitative effect on the hydraulic behaviour of fractured rock masses. Compared with the deterministic fracture configurations that have been extensively dealt with in a previous study, this investigation is expected to be more practical and adequate, since fracture geometry parameters are inherently stochastically distributed in the field. Moreover, the methodology and approach presented in this study may be generally applied to any fracture system in investigating the hydraulic behaviours from configurations of the fracture system while establishing a ‘bridge’ from the discrete fracture network flow modelling to equivalent continuum modelling in fractured rock masses. Copyright © 2007 John Wiley & Sons, Ltd.     

Wall effect of underwater explosion load based on wave motion theories

Owing to the existence of the flow field boundary, the shock wave load near the boundary is different from the freefield shock wave load. In the present paper, the hull plate load subjected to underwater shock wave is investigated based onwave motion theories; in addition, the experimental study of the hull plate load is carried out. According to the theoreticalanalysis of the hull plate pressure, we find that the hull plate pressure oscillates repeatedly and decays rapidly with timepassing, the maximum hull plate pressure is 2/（1＋n） times the maximum free field pressure, where n is the ratio ofimpedance, and the impulse is much smaller than the free field impulse. Compared with the experimental study, thetheoretical results agree well with the experimental data.