In situ nitrite measurements using a compact spectrophotometric analysis system

Application of a portable spectrophotometric analysis system for measurement of nitrite in seawater is described in this work. The spectral analysis system (SEAS) used for observations of the primary nitrite maximum (PNM) has an operational depth of 500 m and is capable of fully autonomous data acquisition and analysis. The liquid core waveguides (LCWs) used as optical cells in SEAS allow for optical pathlengths as long as 5 m and provide subnanomolar detection limits for a variety of analytes. The 1-m waveguide used in the present study had an internal volume of 0.52 cm³ and provided NO₂⁻ measurement precisions and detection limits on the order of 1.2 and 2.5 nM. The time required for a complete in situ analysis, approximately 3–5 min, allows acquisition of detailed profiles on time scales commensurate with the duration of typical hydrocast operations. NO₂⁻ profiles in the Gulf of Mexico showed very sharp gradients over a 5–10-m depth range and a primary nitrite maximum between 100 and 130 m. A shoulder was often observed approximately 10 m below the primary maximum, with relatively slowly decreasing NO₂⁻ concentrations at increasing depth.     

Numerical Modeling of Suspended Sediment Transport in the Gulf of Kachchh Including Kandla Creek, West Coast of India

A depth-averaged numerical model has been developed to study tidal circulation and suspended sediment transport in the Gulf of Kachchh including Kandla creek, west coast of India. The resolution of the model is taken as 750 m × 750 m, which is found to be adequate for the gulf region. However, this resolution could not produce the realistic circulation pattern and suspended sediment concentration in the Kandla creek region. There is a major seaport at Kandla which serves as the sea gate to northwest India. Therefore, a 2-D fine resolution (75 m × 75 m) model for Kandla creek has been developed and coupled with the coarser gulf model to compute the flow features in the creek region. The model dynamics and basic formulation remain the same for both the gulf model and the creek model. The models are barotropic, based on shallow water equations, and neglect horizontal diffusion and wind stress terms in the momentum equations. The models are fully nonlinear and use a semiexplicit finite difference scheme to solve mass, momentum, and advection-diffusion equations in a horizontal plane. The tide in the gulf is represented in the model by the semidiurnal M₂ constituent mainly. In this study, no fresh water discharge conditions have been considered so the results are appropriate for the dry season. Numerical experiments are carried out to study the circulation and suspended sediment concentrations in the gulf and the creek regions. The computed results are validated with the available observations.     

Nutrient Concentrations are High in the Turbid Waters of the Colorado River Delta

We studied the seasonal change of the spatial distribution of nitrite (NO^-₂), nitrate (NO^-₃), reactive phosphate (PO^3-₄), and silicate (SiO₂) in the Colorado River Delta. We also generated 24-h time series at one location to study their short-period variability. The delta is a negative estuary. During summer, salinity may be as high as 40. Amplitude of spring tides is as large as 9 m, and this causes great water turbidity by sediment resuspension. Nutrient concentrations were high throughout the whole year, with lower values towards the oceanic region. Maximum nutrient values in the river delta were 15, 53, 11·5 and 92 μM, for NO^-₂, NO^-₃, PO^3-₄, and SiO₂, respectively. Most values were under 2, 40, 5, and 60 μM, for NO^-₂, NO^-₃, PO^3-₄, and SiO₂, respectively. Our nutrient data show no clear seasonal pattern. Possibly, high NO^-₃ values in the delta are due to groundwater input, mostly at the internal extreme, and high NO^-₂, PO^3-₄, and SiO₂ values are due to resuspension of sediments and mixing of porewaters with the water column, caused mainly during spring tides. In the case of NO^-₂, oxidation of NH⁺₄ in the water column would be part of the mechanism. This would explain the high negative correlation between NO^-₃ and sea-level, and the relatively low correlation between the other nutrients and sea-level, for the time series generated at a single location.     

The Ecology of Benthos in the Gulf of ThermaTkos, Greece

Abstract. Benthic samples were taken at 26 stations during a two year period (1975–1977) in the Gulf of Thermaïkos, Greece. The topography and relevant physicochemical characteristics of the area are presented and discussed. Both density and biomass increase towards the northern limits in the Bay of Thessaloniki and in the Gulf of Thermaïkos, the difference between them being the degree of change in a north-south direction. Analyses of the degree of concurrence of the dominant species show the existence of a number of groups of concurrent dominant species with characteristic distributional patterns and differing areal coverage in the study area. The observed quantitative and qualitative differences in the benthos are causally related to the differing environmental conditions prevailing in the two subareas.     

The Diets in Four Pacific Tube Blennies (Acanthemblemaria: Chaenopsidae): Lack of Ecological Divergence in Syntopic Species

Abstract. The diets of three syntopic Gulf of California Acanthemblemaria (A. balanorum, A. crock-eri and A. macrospilus) and A. castroi from the Galapagos Island are nearly uniformly composed of harpacticoid copepods and other small benthic-vagile or planktonic crustaceans. On occasion, large prey items such as crabs or other small fishes are taken. HORN'S index of niche overlap indicates that the three syntopic Acanthemblemaria are not separated along the food resource utilization axis. Slight variations in diets among the syntopic species seem to be related to differences in degree of microhabitat specialization.     

北部湾冬季强风的主分量神经网络预报方法研究

本文首先分析造成北部湾冬季强风的天气动力学机理，在此基础上以相关分析法确定强风的预报因子(气压梯度、气温梯度、高层风速等因子)与预报量之间存在着较好的相关性；进而采用人工神经网络与主分量分析(PCA)相结合的方法建立了北部湾冬季强风的预报模型．该预报方法所构造的预报模型对历史样本风速拟合平均绝对误差为1．80m/s，对独立样本风速试报的平均绝对误差为1．46m/s．计算结果表明，该方法的拟合效果及预报稳定性较好，可在预报业务中应用．     

Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids of superficial sediments from three contrasted areas

Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids (THAA and EHHA) and EHAA/THAA ratios of superficial sediments were assessed during 1997-1999 in three areas (i.e., the Gulf of Lions, the Bay of Biscay, and Central Chile) differing in their primary productivity. In all three areas, and even off Central Chile where a strong El Niño event took place during 1997-1998, spatial changes were always much greater than temporal ones. The factors affecting the spatial distributions of amino acid concentrations differed among areas. In the Gulf of Lions, sediment granulometry was apparently the most important driving force of THAA, EHAA, and EHAA/THAA, and there was no marked difference between stations located on the open slope and those in submarine canyons. Conversely, in the Bay of Biscay, there were clear differences between the stations located off Cap-Breton, on the open slope, and those in the Cap-Ferret canyon; the latter two featuring lower EHAA and THAA but higher EHAA/THAA. This pattern is likely to result from the predominance of different sources of organic matter and especially from the importance of continental inputs to the Cap-Breton canyon. Off Central Chile, amino acid concentrations and ratios were both maximal around 100 m depth, probably reflecting the interaction between the primary productivity gradient and the presence of an oxygen minimum zone (OMZ) reducing the degradation of sedimentary organics. When comparing the average values collected in the three areas studied, THAA and EHAA were highest in Central Chile, intermediate in the Bay of Biscay and lowest in the Gulf of Lions. EHAA/THAA ratios were also highest in Central Chile but were lowest in the Bay of Biscay. Differences between the Gulf of Lions and the Bay of Biscay could have been affected by sampling design. In Central Chile, the use of labile organic carbon to total organic carbon (C-LOM/TOC) and EHAA/THAA as indices of organic matter lability led to very similar results. This was not the case in the Bay of Biscay. It is therefore argued that the use of C-LOM/TOC should be restricted to highly productive areas.