Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

Bound and mobile soil water isotope ratios are affected by soil texture and mineralogy,whereas extraction method influences their measurement

Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ²H and δ¹⁸O of soil water isotope ratios.     

Enhancement of backtracking search algorithm for identifying soil parameters

In this paper, an enhanced backtracking search algorithm (so-called MBSA-LS) for parameter identification is proposed with two modifications: (a) modifying the mutation of original backtracking search algorithm (BSA) considering the contribution of current best individual for accelerating convergence speed and (b) novelly incorporating an efficient differential evolution (DE) as local search for improving the quality of population. The proposed MBSA-LS is first validated with better performance than the original BSA and some other typical state-of-the-art optimization algorithms on a benchmark of soil parameter identification in terms of effectiveness, efficiency, and robustness. Then, the efficiency of the MBSA-LS is further illustrated by two representative cases: identifying soil parameters from both laboratory tests and field measurements. All comparisons demonstrate that the proposed MBSA-LS algorithm can give accurate results in a short time. Finally, to conveniently solve the problems of parameter identification, a practical tool ErosOpt for parameter identification is developed by integrating the proposed MBSA-LS and some other efficient algorithms for readers to conduct the parameter identification using optimisation algorithms.     

基于ArcMap的地图制作研究

随着计算机技术的飞速发展,计算机软件为地图设计和制作提供了更加便捷的操作模式,电子地图的出现摆脱了传统纸张对地图的限制,使其可以更好地为用户服务。ArcMap是一个统一的地理信息平台,在数据库制作、符号制作和地图装饰等方面具有独特的优势,适用范围广泛,在林业、牧业、电力等多行业具有非常好的数据展现效果,方便用户浏览、搜索和定位。本文从ArcMap制图流程入手,研究不同流程中制图方法。     

X射线衍射技术应用于宝石鉴定-合成及晶体结构研究进展

因宝石检测常附带无损要求、宝石评价具科学性和不确定性等特点,X射线衍射(XRD)在宝石学这门矿物学的分支学科中的应用具有特殊性,其应用领域主要集中在三个方面。①宝石鉴定领域:对单晶宝石和多晶宝石进行物相鉴定、宝石产地特征研究以及宝石矿物多型的种类划分等。例如根据XRD图谱,可将品种繁多的微晶石英隐晶质变种玉髓中不同的SiO₂质矿物相精确区分;通过黏土矿物成分及其含量可将鸡血石中"地"的种类进行划分。②宝石矿物的晶体结构研究:对成分复杂的单晶宝石进行晶体化学分析、获取矿物类质同象替代情况、利用结晶度划分宝石品质。例如晶格参数中的c/a比值可将绿柱石的Al八面体类质同象替代和Be四面体类质同象替代进行区分;软玉中通过XRD数据计算出的结晶度与软玉的品质关系密切。③宝石学研究技术的开发:对宝石的优化处理过程进行监测,在宝石合成过程中检验矿物晶形大小、结晶质量及内应力等,以有机宝石的晶体结构为基础的人工养殖技术研究。例如尖晶石在热处理过程中,Mg离子由四面体中的T位迁移至八面体中的M位,导致M-O和T-O键长随温度变化,并反映在尖晶石的色调中;在托帕石合成过程中,XRD数据显示770~800℃时形成含氟托帕石(与天然托帕石结构相同),而在950℃和1000℃出现含氟托帕石离解成刚玉和莫来石。目前,我国在宝石学的XRD应用方面起步较晚,国外在宝石鉴定、优化与合成方面的应用相对成熟。本文认为,该技术与扫描电镜、质子探针等分析技术的联用仍有很大发展空间。     

风暴分类识别技术在人工防雹中的应用

利用新一代多普勒天气雷达资料,在风暴跟踪识别算法的基础上,发展了风暴分类技术,以提高人工防雹作业指挥的效率。首先以SCIT算法为基础,结合风暴的结构特征,综合利用雷达、探空资料,自动提取风暴结构特征指数;其次采用基于决策树模型的风暴自动分类技术,将风暴按强度分为雷雨云、单体风暴、多单体风暴和强风暴;最后根据风暴强度、高度和位置等属性,对有可能产生冰雹的单体,结合GIS,自动对下游方向或附近作业点进行预警或输出作业参数。通过对2006—2014年期间重庆、辽宁大连和河南三门峡三地发生的较为典型的31次冰雹天气过程、182站次冰雹样本的检验来看:该方法通过对风暴按强度、垂直结构等综合属性进行分类,能有效提高冰雹识别的命中率、降低空报率,其中强风暴的命中率能达到100%,空报率仅为11.4%。能有效提高人工防雹作业的自动化程度,对防雹作业的科学决策有着重要参考作用。     

利用双线偏振雷达分析人工防雹作业效果

以北京市平谷区2011年6月11日防雹作业为例,利用双线偏振雷达资料,选取与作业区条件十分接近的云块为对比区,根据回波移动方向和速度,跟踪分析在不同高度上防雹作业前后云体宏观结构特征和粒子相态等微物理变化过程。作业后云体所呈现特征为:1作业区的云顶高度、强回波中心高度迅速下降,对比区变化不明显;2作业区水平反射率Zh减小,差分反射率Zdr、零相关系数ρhv增大,单位差分传播相移Kdp小范围内波动,对比区Zh、Zdr、Kdp变化不明显;ρhv增大;3作业区对流减弱,高层较大冰雹粒子、大雨滴下沉明显,最终以霰粒子为主;而对比区域则对流仍然旺盛,冰雹粒子有增多趋势。以上特征表明防雹作业可有效抑制冰雹胚胎成长为冰雹的过程,通过偏振雷达观测参量可对防雹作业效果进行较好的验证。     

海-塔盆地中部断陷带南屯组沉积体系配置及有利相带分析

本文充分利用岩芯、测井、地震及分析化验等资料,对海-塔盆地中部断陷带4个主力凹陷的南屯组砂体类型及分布特征进行了详细研究。结果表明,南屯组主要发育扇三角洲、近岸水下扇、辫状河三角洲和湖底扇等4种典型类型砂体,并从沉积背景、发育部位、沉积特征、搬运机制以及地震反射特征等5个方面,分不同角度、不同层次详细阐述了扇三角洲、近岸水下扇、辫状河三角洲和湖底扇的识别标志;其中扇三角洲主要分布在乌尔逊凹陷和贝尔凹陷的陡坡带,近岸水下扇主要分布在南贝尔凹陷和塔南凹陷的陡坡带,而辫状河三角洲主要分布乌尔逊凹陷、贝尔凹陷和南贝尔凹陷的缓坡带。从盆地边部向盆地中心方向,沉积相由扇三角洲、近岸水下扇和辫状河三角洲沉积逐渐过渡为半深湖-深湖相沉积,局部半深湖-深湖相中发育湖底扇沉积体系,整体具有“南北分块、东西分带”的沉积格局。综合研究表明,扇三角洲前缘、近岸水下扇中扇和辫状河三角洲前缘砂体是油气富集的有利沉积相带,而洼槽边缘的湖底扇砂体为岩性油气藏勘探的重点对象。     

吉林地区地电阻率震兆异常对比分析

对采用形态法、归一化变化速率法和各向异性度法提取到的吉林省内深源地震以及浅源地震前的地电阻率异常变化进行对比分析,结果表明:(1)震前地电阻率出现1~2年尺度中期异常,甚至短期异常,异常以负异常为主;(2)震前地电阻率原始月均值异常变化幅度1%,表明数字地电仪捕捉电信号灵敏度的提高,更与台址构造密不可分;(3)震前地电阻率出现异常变化,震后恢复到正常变化形态,反映出震前震中区地下应力的变化,震后区域构造应力场重新调整并逐渐恢复的过程。     

层状边坡滑动边界强度参数取值方法研究

滑坡滑带土强度参数取值的准确性,决定了滑坡稳定性计算的可靠程度。因此获得准确、可靠的滑动边界强度参数至关重要。然而在实际情况中,由于取样位置试样的代表性,以及试样转运过程中保存条件的限制,现场所取得的滑带土在室内试验得到的强度参数已经不能完全反映真实环境下的抗剪强度。因此考虑软弱夹层、滑带土各种物理和力学指标间存在必然联系,并表现出特定的规律性,尝试通过试验,揭示指标间的关联规律,并建立了相关性好的关系式,据此评价滑动边界的抗剪强度参数。