Postcollisional flow of aqueous fluid within ultrahigh-pressure eclogite in the Dabie orogen

A combined study of chronometric dating and oxygen isotope analysis for minerals from vein and host eclogite as well as regional country-rock gneiss in the Dabie orogen provides a direct constraint on timing of fluid flow in this orogen formed by continental collision. Oxygen isotope ratios of vein minerals are significantly lower than those of the host eclogite, but comparable with those of the regional gneiss. This suggests the veining fluid came from the regional gneiss (i.e. exhumed slab itself) rather than the host eclogite. While zircon U–Pb and phengite Ar–Ar dating yields ages of 214 to 222 Ma for the eclogite and gneiss, the vein gives a quartz–muscovite Rb–Sr isochron age of 181 Ma and a muscovite K–Ar age of 179 Ma. Thus the veining postdates the Triassic ultrahigh pressure metamorphic event, witnessing postcollisional fluid flow after the orogenic cycle of continental collision.     

Geochemistry and Origin of Ananai Stratiform Manganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Major and trace element contents are reported for Permian manganese ore and associated greenstone from the Ananai manganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The manganese deposit occurs between greenstone and red chert, or among red chert beds. Chemical compositions of manganese ore are characterized by enrichments in Mn, Ca, P, Co, Ni, Zn, Sr and Ba, and negative Ce and positive Eu anomalies relative to post-Archean average Australian Shale (PAAS). Geochemical features of the manganese ore are similar to those of modern submarine hydrother-mal manganese deposits from volcanic arc or hotspot setting. In addition, geochemical characteristics of the greenstone closely associated with the Ananai manganese deposit are analogous to those of with-in plate alkaline basalt (WPA). Consequently, the Ananai manganese deposit was most likely formed by hydrothermal activity related to hotspot volcanism in the Panthalassa Ocean during the Middle Permian. This is the first report documenting the terrestrially-exposed manganese deposit that was a submarine precipitate at hotspot.     

湖南船岭脚锡矿区矿化特征及成因探讨

船岭脚锡矿为南岭锡多金属成矿带的一大型锡矿床。矿化类型较多,以构造蚀变带-矽卡岩复合型、接触带矽卡岩型锡矿为主,分布于中侏罗世姑婆山岩体接触带,且具分带性,自岩体内接触带往外依次为构造蚀变带-矽卡岩复合型、接触带矽卡岩型。矿化与成矿岩体及构造复合等因素密切相关,成矿物质主要来源于岩浆,为一与花岗岩有关的中高温矽卡岩型矿床。     

伊宁吐拉苏火山盆地热液活动与金成矿关系

吐拉苏火山盆地中与金成矿有关的热液富含K^＋、Na^＋、F、SO4^2-和N2、O2等，是一种主要来源于岩浆．火山的热液，有大气水参于的次生热液．平均均一温度96～158℃，平均盐度0．26％～1．08％，热液活动深度0．26～0．67km，具有低温、低盐度、在地壳浅部活动的基本特征．热液活动生成围绕金矿体由内向外环状展布的黄英岩化、高级泥化、泥化和绿泥石碳酸盐化4个围岩蚀变带．与其有关的金成矿期分为原生沉积富集和次生热液交代蚀变2期，后者包括毒砂黄铁矿化、面状硅化、脉状硅化和绿泥石碳酸盐化4个成矿阶段．金富集成矿主要与黄英岩化蚀变带和面状硅化、脉状硅化2个成矿阶段密切相关．     

环境样品中痕量元素的化学形态分析Ⅱ．砷汞镉锡铅硒铬的形态分析

环境中元素的生物有效性和毒性依赖于其存在的化学形态。文章依据文献的有关报道介绍砷、汞、镉、锡、铅、硒和铬在环境中的分布、毒性及它们在环境样品如水、土壤、沉积物和生物体中的形态分析方法,包括分析物的保存、提取、分离和检测。引用文献120篇。     

新密煤田地热资源成因探讨

通过对新密煤田地质条件、构造条件、煤系岩石的放射性特征、下热水的水文地球化学、气体成分等特征的研究,认为形成新密煤田地热资源的热源是来自硫化矿物生热、岩浆余热以及煤系地层岩石放射性物质产热的学说证据不足;而新密煤田的水文地质条件,地质构造条件为该区地下水的深循环提供了条件,故而在该区形成了水热型的中低温地热资源.     

新疆西天山高硫化型京希-伊尔曼德金矿床的识别标志及其找矿意义

经过详细的野外地质勘查、热液蚀变及蚀变矿物学研究，流体包裹体和同位素研究，首次将西天山京希－伊尔曼德金矿床确定为高硫化型浅成低温热液金矿床。该矿床的主要识别标志为：发育以多孔状石英为特征的硅化蚀变带和高级泥化蚀变带；成矿流体性质为低盐度[W(NaCl)为0.3-4.2%]、低pH值（3－4）和高氧化态；氧同位素δ（^18O)为1.7 ‰-4.3‰,δ(D)为－60‰--80‰。金主要富集在高级泥化带和中心硅化蚀变带内。系统研究和总结了成矿地质－地球化学制约因素以及区域、靶区和勘探区尺度的找矿标志。     

热液矿床成矿元素地球化学异常探讨

为什么有些热液矿床矿体周围蚀变岩中出现明显的成矿元素负异常，而有些热液矿床矿体周围蚀变岩中出现明显的成矿元素正异常？以湘中地区锑（金）矿床为例，探讨了热液矿床成矿元素异常的形成机理，研究表明，热液矿床成矿物质来源的差异是导致成矿元素正异常或负异常的根本原因。     

云南墨江金矿热水喷流沉积成岩成矿的地质地球化学证据

在墨江金矿区发现了两个热水喷流沉积旋回，赋矿地层烂山段出露的硅质岩和（黄铁矿）硫化物岩具有低TiO2,Al2O3和富含As,Sb,Au,Ag,Hg含量特征，稀土元素具有总量低，轻稀土总量高于重稀土特征，其球粒陨石标准化模式为向右倾曲线，大多数样品具有负Eu异常；而其北美页岩标准化曲线向左倾，在SiO2-Al2O3,Al-Fe-Mn和Al2O3-TFeO-CaO等地球化学图解上，大多数样品位于热水沉积区，当样品中含有火山角砾成分时偏离热水沉积区，研究表明硅质岩和（黄铁矿）硫化物岩主要由热水喷流沉积形成的，再结合矿床地质特征，认为墨江金矿存在早期热水喷流沉积成岩成矿作用，形成了矿化或低品位矿石，并可能与下伏火山喷发有关，这为墨江金矿的成因研究和进一步找矿开辟新的思路。