Ocean-floor hydrothermal metamorphism in the Limousin ophiolites (western French Massif Central): evidence of a rare preserved Variscan oceanic marker

The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany).     

Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.     

南秦岭十里坪锑矿床成矿时代及成因的初步研究

十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%～11.3%,均一温度为109～232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。     

腾冲热海火山地热区近期水热爆炸的阶段性演化特征

水热爆炸是活动性地热田的典型显示。腾冲热海火山地热区历史上曾发生过强烈的水热爆炸活动，但前期一度沉寂。1993年以来水热爆炸活动再度活跃。在过去十年间，研究区内发生过较大的爆炸喷发事件20余次，且规模越来越大。本文根据对爆炸形成泉点的选出气体化学和氦同位素组成的测试结果，研究了区内近期水热爆炸活动的演化特征。逸出气体化学和氦同位素组成特征指示，区内近期引发水热爆炸活动的气体源区有从浅层、中层向深层发展的趋势；作者认为，区内未来可能发生更大规模的爆炸活动，其危险性应引起高度关注。     

高坪-吉心段公路喀斯特工程地质综合勘察

以沪蓉国道主干线湖北省高坪-吉心段的喀斯特地质勘察工作为例，探讨喀斯特地区公路工程地质综合勘察的基本方法。在喀斯特地区运用遥感和地理信息技术技术、地质测绘、综合物探以及地质钻探等勘察手段，通过综合分析各种勘探成果，能够较准确地查明可溶岩的分布、喀斯特形态类型、分布规律、控制因素以及喀斯特水的赋存、分布和运移规律等，并根据不同的喀斯特地貌提出了有针对性的处理对策。通过不断的实践和经验总结。针对喀斯特工程地质问题合理运用综合工程勘察方法，能做出科学的分析评价，可以适应喀斯特区公路建设的需要，并且供今后在喀斯特地区修建公路时参考和借鉴。     

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。     

个旧锡矿区域地壳演化与成矿探讨

个旧锡多金属矿床是驰名中外的特大型矿床，过去认为是燕山晚期“花岗岩岩浆期后气液矿床”。但通过探讨区域上前震旦纪地壳演化、震旦纪-早古生代地壳演化、泥盆纪-三叠纪地壳演化以及侏罗纪-第四纪地壳演化，以及与成矿之间的关系，发现个旧矿区至少经历了印支中晚期海底基性火山-沉积成矿、印支中晚期海底喷流热水沉积成矿、燕山晚期花岗岩叠加改造成矿以及喜山期陆相表生沉积成矿作用，厘定了个旧锡矿区的印支中晚期海底基性火山．沉积Sn-Cu-Zn(Au)矿床系列、印支中晚期海底喷流-沉积Sn-Cu-Pb-Zn矿床系列、燕山晚期花岗岩叠加改造Sn-Cu-W-Be-Bi-Pb-Zn-Ag矿床系列、喜山期陆相表生沉积砂矿矿床系列等4大矿床系列及12种矿床类型。     

热液中铅、锌、银共生分异的热力学探讨

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。     

内蒙古东乌珠穆沁旗舒哈迪铅锌多金属矿成矿特征

舒哈迪铅锌多金属矿床赋存在发育于奥陶系中统多宝山组细碧岩、石英角斑岩岩系中的断裂构造蚀变带内,矿体呈脉状、透镜状,受舒哈迪背斜构造及其伴生的断裂构造控制,铅锌矿石成分简单,伴生有银和铜.围岩蚀变主要为黄铁矿化、硅化、绿泥石化、绿帘石化、绢云母化和碳酸盐化,具有不明显的分带性.成矿物质来源于奥陶系中统多宝山组变质岩系,成矿热液来源于隐伏的岩浆侵入体,矿床成因属于岩浆热液充填（脉）型铅锌多金属矿床,矿床形成时代为燕山早-中期.