贵州泥堡金矿床构造蚀变体岩相学及地球化学特征

贵州泥堡金矿构造蚀变体(SBT)为产出于茅口组(P_2m)和龙潭组(P_3l)或峨眉山玄武岩(P_3β)之间沉积间断面-不整合界面附近的一套硅质蚀变岩石组合。采用光学显微镜及ICP-MS研究SBT样品岩相学及元素地球化学特征,结果显示,SBT矿石样品中主要矿物有石英、黄铁矿、褐铁矿、萤石、白云石和辉锑矿等,蚀变类型主要为黄铁矿化、白云石化和硅化,微观结构主要为砂状、岩屑-凝灰碎屑结构、交代结构等,构造主要有浸染状、块状、角砾状、条带状和脉状构造。SBT微量元素标准化曲线以Au、As、Sb、Hg、Te的强烈富集,Li、Sc、Cr的亏损和Cd、Ta的富集为特征。稀土元素CI球粒陨石标准化配分模式图表现为轻稀土富集的右倾型,LREE/HREE为6. 98～19. 91,"四分组"效应明显,重稀土分馏不明显,解释为受热液作用强烈; SBT微量元素标准化图及稀土元素配分曲线均表现出与围岩相似,表明继承了原岩的元素组成;δEu为0. 80～1. 84,显示Eu从明显负异常到明显的正异常;δCe为0. 72～1. 25,显示Ce从明显负异常到弱正异常,认为流体来源于深部或至少经历过对富含斜长石源区的水-岩反应,而不是含矿地层的改造热液。     

额济纳旗灰石山东北铌多金属矿床成矿规律及成因浅析

通过对灰石山东北铌多金属矿床地质特征综合分析表明,矿床的产出受地层和构造的双重制约。矿区的二叠系双堡塘组是矿源层,矿体具有明显的层位控制性;北东东向断裂构造提供了热液通道并进行了叠加改造;矿床成因类型属于沉积变质-热液叠加型。     

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.     

Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.     

Dissolution characteristics of deep?buried dolostone in the Member 5 of Ordovician Majiagou Formation in southern Ordos Basin

The different types of deep-buried dissolution process in the Member 5 of Ordovician Majiagou Formation in the southern Ordos Basin and its influence on the reservoir properties are studied in this paper. It shows that three types of mechanisms include organic acid fluid, hydrothermal fluid and TSR are identified through studies of core observation, thin section analysis, inclusion temperature, trace elements and rare earth elements. It is found that the dissolution of organic acid fluid causes the stratified dissolution pores, film-like asphaltene and ring-like asphaltene, while hydrothermal fluid causes the non-selective dissolution pores without petrofabric, veins of pyrites, massive pyrites and the association of hypothermal minerals. Four occurrence models of dissolution include, (1) the deep-buried dissolution of low-temperature hydrothermal fluid occurs in Zhiluo Period of Middle Jurassic; (2) the deep-buried dissolution of organic acid fluid started from the late Middle Jurassic followed by the first hydrocarbon injection; (3) the deep-buried dissolution of middle-high temperature hydrothermal fluid occurred in the Dongsheng Period of Early Cretaceous; (4) TSR occurred at the end of Early Cretaceous with the second larger hydrocarbon injection. Both organic acid fluid and hydrothermal fluid can improve the porosity and permeability of reservoir, but the hydrothermal fluid is more effective than that of organic acid fluid.     

四川盆地东部中二叠统茅口组热液活动特征

四川盆地中二叠统茅口组存在丰富的热液流体活动。在野外剖面和岩心观察的基础上,利用多种分析测试方法,对四川盆地东部茅口组碳酸盐岩中的热液活动特征进行了探讨。研究区茅口组热液活动包括2类,一类为硅质热液,表现为薄层硅质岩或硅质团块;另一类为碳酸盐型热液,表现为粗晶方解石和白云石充填在张性构造裂缝中或呈"雪片状"集合体,偶见少量黄铁矿、闪锌矿等金属硫化物伴生。硅质岩主量元素之间的关系表明硅质来源具有多样性,是热液硅与壳源硅的混合;黄铁矿、闪锌矿原位S同位素δ34S介于-3.91‰~-6.87‰之间,推测可能受到了微生物和基性岩浆岩的双重影响;方解石脉和具鞍状双晶的白云石脉普遍具有Ca O高于标准计量、相对富Sr和U、贫REE和Ti、Ce/Ce*明显负异常、Eu/Eu*主体正异常、Y正异常等特征,表明碳酸盐脉为热液活动的产物,流体来源也呈现出火山活动相关流体与富钙地下水混合的特点。闪锌矿富集Ge和Cd,Zn/Cd及Zn/Fe值反映了中等成矿温度。硅质岩和碳酸盐流体包裹体均一温度变化范围较大,介于54.7~294.3℃之间,与稀土元素和微量元素比值所揭示的特征吻合。研究结果表明,穿层状硅质结核和团块的首次出现往往标志着茅口组热液活动的开始,而张性构造裂缝和碳酸盐型热液活动带来的围岩白云化作用则有效地改善了白云岩储集层的物性。     

南秦岭柞山地区铅银锌矿成矿规律及找矿模型

南秦岭柞水银洞子—山阳桐木沟铅银锌矿带地处陕西柞山地区中部,位于中秦岭晚古生代弧前盆地的柞水—山阳矿集区内。该带东西长约71 km,南北宽1～7 km。对带内银洞子（铜）铅银菱铁矿床、黑沟铅锌菱铁矿床、桐木沟锌矿床、南沟（银）铅矿床和松林沟铅矿点的地质、矿体、蚀变、矿化规律进行总结,发现矿体均严格产于中-上泥盆统青石垭组,具有明显的时控、层控、岩控及后期热液改造成矿特征,属典型的海底热水喷流沉积-热液改造层控矿床,构成与晚古生代海底热水喷流沉积-热液改造作用有关的铅锌银成矿系列。建立以层控+热液改造为主控矿条件,以青石垭组热水沉积岩+断裂+化探异常+硫化物、重晶石、菱铁矿蚀变分带为组合的找矿模型,对柞山地区金属矿的找矿突破具有重要的指导意义。     

黔西南水银洞爆破角砾岩筒与金元素超常富集

水银洞金矿床曾被认为是滇黔桂地区最有代表性的微细浸染型金矿(卡林型金矿),然而矿床的金品位明显高于一般意义上的卡林型金矿床,且金矿体与气液爆破角砾岩关系密切.气液爆破角砾岩呈垂直筒状产状,两侧断裂矿化带呈向上扩张的"喇叭口"状成矿空间,富金矿体紧密围绕角砾岩筒分布.根据野外和显微镜观察,角砾岩块成分复杂与显著磨圆.气液角砾岩筒的角砾岩显著富集金、稀土、亲地幔过渡元素Ti、Cr、Ni、Co、V等,以及Zr、Hf等,明显地区别于围岩,反映出深源流体快速上升的气液爆破角砾岩的特征,角砾岩筒实际上具备含金成矿流体的上涌通道的功能.岩筒中早期角砾岩的角砾含Au达18×10–6,属于深部金矿体的爆破碎块,显示出水银洞金矿床可观的深部找矿勘探前景.     

巴音戈壁盆地塔木素铀矿床含矿砂岩成岩作用类型、演化序列及其对铀成矿的约束

勘查和研究发现部分砂岩型铀矿床中不仅有表生氧化流体作用还存在深部流体的参与,这类砂岩型铀矿床蚀变类型多样且成因复杂.塔木素砂岩型铀矿表生流体和深部流体活动都很明显,砂岩普遍固结且后生蚀变类型独特,因此,恢复成岩成矿事件及其演化过程,对揭示铀沉淀富集机理至关重要.本文通过镜下鉴定、电子探针、扫描电镜分析等,系统研究了塔木素矿床含矿砂岩成岩作用特征与后生蚀变矿物生成序列,重塑了成岩成矿事件的演化过程.研究结果显示,塔木素矿床砂岩中压实作用较弱而胶结作用很强,重结晶作用普遍,是造成目的层致密的主要原因,赤铁矿、褐铁矿化、碳酸盐化、石膏化是该地区主要的胶结类型.将该地区的成岩演化划分为沉积-早成岩阶段、早期氧化流体作用阶段、热流体改造阶段和晚期氧化流体弱改造阶段.成岩环境由弱碱性向酸性环境转变的过程中的氧化还原过渡部位是造成铀沉淀的关键,大规模的氧化作用是矿床形成的基础,后期热流体活动对早期形成的低品位铀矿石进行叠加改造,是成矿的关键环节.     

Fluid fluxes during low-temperature alteration: implications of multi-style alteration assemblages from the Welsh Borderland,UK

Localized (domainal) low-temperature alteration may indicate variations in the chemistry of alteration fluids and/or discrete fluid flow paths during metamorphism. Occurrences of epidote- and pumpellyite-dominated domains are often used as evidence for large fluxes of Ca-rich fluids. However, comparative studies of two domainal alteration styles from basaltic to andesitic lavas and volcaniclastic rocks at Builth Wells, Wales, UK suggest that such interpretations cannot be applied universally. Here, only one set of domains can be attributed to large fluxes of Ca-rich fluids. In contrast, the second set of domains formed where the host rock supplied the necessary Ca, and fluid/rock ratios were relatively low. These domains are hosted by rocks which show a Caledonian regional metamorphic imprint, characterized by the alteration assemblage albite+chlorite+titanite±prehnite±pumpellyite±calcite±muscovite±quartz (considered to have formed at c. 200°C and ≤2.5 kbar). Type 1 domains lie along fluid channelways, such as veins. Pumpellyite is the dominant secondary mineral, but the alteration assemblage is variable with pumpellyite±prehnite±calcite±titanite±chlorite (±quartz). The domains formed at temperatures of 130–230°C during Ordovician hydrothermal activity, before the peak of regional metamorphism. In contrast, Type 2 domains are not associated with obvious fluid channelways. A central prehnite-dominated zone typically has a rim with the assemblage pumpellyite+calcite±prehnite±chlorite±titanite±K-rich phyllosilicate. These domains probably formed from pelitic xenoliths which contained a volcaniclastic component at temperatures of 130–230°C and at relatively low fluid/rock ratios. However, the timing of domain formation is uncertain. Pyrobitumen, in veins and disseminated throughout the rock, may have influenced the formation of both types of domain by stabilizing pumpellyite in preference to epidote and causing metamorphic calcite formation through the release of CO₂ to the alteration fluids. © 1996 John Wiley & Sons, Ltd.