塔什库尔干地区赞坎铁矿矿物学特征与成因

赞坎铁矿石西昆仑成矿带近年来新发现的一处超大型铁矿床,矿区内广泛出露古元古代布伦阔勒变质岩层,矿体主要赋存于布伦阔勒岩群角闪斜长片岩和黑云石英片岩内部,部分产于霏细岩与黑云石英片岩接触带内。矿床由Ⅰ~Ⅶ号矿体组成,其中Ⅰ号和Ⅲ号矿体为主要矿体。根据矿石组构、矿物共生关系等特征,成矿过程可划分为早期沉积期、中期变质期及晚期岩浆热液期3个成矿期,其中,岩浆热液期可进一步划分为矽卡岩阶段、热液改造阶段和硫化物阶段。早期沉积期磁铁矿呈微细粒他形晶结构,被变质期石英颗粒包裹,以较低含量的TFeO、MgO、MnO和较高含量的TiO2、Al2O3为特征;中期变质期磁铁矿分布于条带状矿石内,他形晶粒状结构,与早期相比,TFeO、MgO、MnO等含量相对升高而TiO2、Al2O3等含量相对降低;晚期岩浆热液期矽卡岩阶段磁铁矿分布于块状矿石内,自形晶粒状结构,以相对富TFeO、MgO、MnO而贫TiO2、Al2O3为特征;晚期热液改造阶段磁铁矿分布于浸染状矿石中,半自形-自形粒状结构、交代残余结构为主,TFeO、Al2O3、TiO2、MnO等含量变化较大。认为赞坎铁矿是沉积变质型铁矿床,遭受后期岩浆热液作用交代改造。     

多次干湿循环后土-水特征曲线的模拟

目前对于土体的干湿循环过程中变形、强度变化规律研究较多,而对经过多次干湿循环后土-水特征曲线的试验研究较少。由于吸力平衡需要时间太长,对干湿循环过程中土-水特征曲线的研究也多限于单次的干湿循环试验。但考虑到实际岩土工程中气候条件的多变性和自然环境的复杂性,一般土体均要经历多次干湿循环,因此,对多次干湿循环后的土-水特性曲线研究显得非常重要。结合已有的试验数据总结脱湿曲线与吸湿曲线随着干湿循环次数的变化规律,通过引入一个与干湿循环次数有关的函数,提出能预测多次干湿循环后土-水特征曲线的方法。本方法仅需土-水特征曲线的首次干湿循环脱湿与吸湿曲线和塑性指数,就可以预测多次干湿循环后的土-水特征曲线。     

对新型螺杆灌注桩的受力特征与破坏性状的探讨

螺杆灌注桩是一种承载力高、造价低、施工方便、无环境污染的新桩型。根据螺杆桩的静荷载试验资料,深入分析了螺杆桩竖向荷载的传递机理,探讨了螺杆桩的受力特征和破坏性状,为今后螺杆桩的设计和施工提供可靠的依据。     

贵州泥堡金矿床构造蚀变体岩相学及地球化学特征

贵州泥堡金矿构造蚀变体(SBT)为产出于茅口组(P_2m)和龙潭组(P_3l)或峨眉山玄武岩(P_3β)之间沉积间断面-不整合界面附近的一套硅质蚀变岩石组合。采用光学显微镜及ICP-MS研究SBT样品岩相学及元素地球化学特征,结果显示,SBT矿石样品中主要矿物有石英、黄铁矿、褐铁矿、萤石、白云石和辉锑矿等,蚀变类型主要为黄铁矿化、白云石化和硅化,微观结构主要为砂状、岩屑-凝灰碎屑结构、交代结构等,构造主要有浸染状、块状、角砾状、条带状和脉状构造。SBT微量元素标准化曲线以Au、As、Sb、Hg、Te的强烈富集,Li、Sc、Cr的亏损和Cd、Ta的富集为特征。稀土元素CI球粒陨石标准化配分模式图表现为轻稀土富集的右倾型,LREE/HREE为6. 98～19. 91,"四分组"效应明显,重稀土分馏不明显,解释为受热液作用强烈; SBT微量元素标准化图及稀土元素配分曲线均表现出与围岩相似,表明继承了原岩的元素组成;δEu为0. 80～1. 84,显示Eu从明显负异常到明显的正异常;δCe为0. 72～1. 25,显示Ce从明显负异常到弱正异常,认为流体来源于深部或至少经历过对富含斜长石源区的水-岩反应,而不是含矿地层的改造热液。     

湖南黄沙坪铅锌矿NNW向构造的识别及其找矿意义

湖南黄沙坪铅锌矿床属岩浆期后热液型矿床,近年来由于危机矿山深部找矿项目取得重大找矿进展而引起各方关注。矿床经历了多期构造活动,包括NNE向、近NE向和NNW向,但以往一直将NNE向作为控岩控矿构造。系统的地质调查及岩体对比发现,NNE向断裂为成矿前逆冲构造,控制区内的褶皱与石英斑岩的侵入,并在成矿期继续活动。NNW向构造控制了矿区内花岗斑岩(301#、304#)的侵入以及矽卡岩及其相关的钨钼矿、铅锌矿的成矿。铅锌矿体受NNW与NNE向断裂的联合控制,常呈S型、或两组断裂交汇处的不规则脉状。矿化以NNW向花岗斑岩为中心形成分带,矽卡岩型钨钼矿化分布于花岗斑岩体边部,铅锌矿体分布于外侧。NNW向控矿构造的认识揭示出黄沙坪矿床301#花岗斑岩体及其东南部深部地区将是重要的找矿方向;同时,301#-304#岩体构成的NW构造线两侧,具有进一步寻找小型铅锌矿体的条件,这些矿体主要位于NNE与NNW向断裂的交汇部位。     

山西省王村地区隐伏侵入岩体隆起区地热地质特征

祁县王村地区位于晋中盆地中部东缘,晋中盆地四周为活动断裂所控制,盆地内受不同方向的次级断层切割,形成隆凹起伏的次级构造单元。祁县王村隆起中心部位是一个岩浆岩侵入体。井深350~400m时水温28℃,多年来水温稳定,该区域存在地热异常。为了查明该区域深部地热地质条件,省地勘基金项目立项进行勘查,采用地球化学调查、地球物理勘查、地热钻探、水文测井等工作方法,推测隐伏岩体分布面积57km^2,地热勘探井深2905.65m时,井口水温仅39℃,含水层为岩体,上覆三叠、二叠系砂岩裂隙水,涌水量1064m^3/d,水化学类型为HCO3·Cl-Na型水。同时测温曲线反映,随着井深增加,井深2045.92m以下侵入岩浆岩体地层地温梯度未见明显增高,说明在长期的地壳构造活动中侵入岩浆岩体的大部分热量已散失,因此本区地热资源勘探开发前景有限。侵入岩体上覆砂岩热储层所含低温温水,对养殖业有一定的开发利用价值。     

Pathways and distances of fluid flow during low-grade metamorphism: evidence from pyrite deposits of the Cameros Basin, Spain

New geochemical and sulphur isotopic data are presented for a number of pyrite deposits from the Late Jurassic–Early Cretaceous Cameros Basin, Spain. The deposits were formed at, or close to, the peak of metamorphism and are always related to sandstone units in the mainly metapelite sequence. Iron remained immobile and conservative, pyrite iron being derived by sulphidation of chlorite in the host metapelites. Reduced sulphur, however, was supplied from two external sources: thermochemical reduction of sulphate and release of S during metamorphism of sedimentary sulphides. These sources provided isotopically heavy and light S, respectively, with variation in pyrite isotopic composition between different deposits resulting from differences in their relative importance at each site. During metamorphism, the sandstone units acted as aquifers, carrying the sulphidic pore waters to locations where permeability provided by syn-depositional fractures on a scale of 0.5–5  m allowed its interaction with the metapelites. Transport distances for sulphide during metamorphism were of the order of hundreds of metres.     

Water,restite and granite mineralisation

Dehydration (vapour absent) partial melting reactions in the Earth's crust produce a hydrous granitic melt phase, new anhydrous minerals that are mostly pyroxenes, and new plagioclase more calcic than the initial plagioclase. These solid phases of the melt reaction are restite. If the restite is carried to high levels in the crust as a component of the magma, cooling and crystallisation to granite will result in back reactions in which the H₂O in the melt phase is consumed and is not then available to form a hydrothermal solution. Even in magmas in which some restite has been removed there will be some back reaction and again less H₂O. Only fractional crystallisation will enrich the H₂O in the magma in sufficient amounts to form a substantial quantity of hydrothermal solution and possible mineralisation.     

Evaluating new fault-controlled hydrothermal dolomitization models: Insights from the Cambrian Dolomite,Western Canadian Sedimentary Basin

Fault-controlled hydrothermal dolomitization in tectonically complex basins can occur at any depth and from different fluid compositions, including ‘deep-seated’, ‘crustal’ or ‘basinal’ brines. Nevertheless, many studies have failed to identify the actual source of these fluids, resulting in a gap in our knowledge on the likely source of magnesium of hydrothermal dolomitization. With development of new concepts in hydrothermal dolomitization, the study aims in particular to test the hypothesis that dolomitizing fluids were sourced from either seawater, ultramafic carbonation or a mixture between the two by utilizing the Cambrian Mount Whyte Formation as an example. Here, the large-scale dolostone bodies are fabric-destructive with a range of crystal fabrics, including euhedral replacement (RD1) and anhedral replacement (RD2). Since dolomite is cross-cut by low amplitude stylolites, dolomitization is interpreted to have occurred shortly after deposition, at a very shallow depth (<1 km). At this time, there would have been sufficient porosity in the mudstones for extensive dolomitization to occur, and the necessary high heat flows and faulting associated with Cambrian rifting to transfer hot brines into the near surface. While the δ¹⁸O_water and ⁸⁷Sr/⁸⁶Sr ratios values of RD1 are comparable with Cambrian seawater, RD2 shows higher values in both parameters. Therefore, although aspects of the fluid geochemistry are consistent with dolomitization from seawater, very high fluid temperature and salinity could be suggestive of mixing with another, hydrothermal fluid. The very hot temperature, positive Eu anomaly, enriched metal concentrations, and cogenetic relation with quartz could indicate that hot brines were at least partially sourced from ultramafic rocks, potentially as a result of interaction between the underlying Proterozoic serpentinites and CO₂-rich fluids. This study highlights that large-scale hydrothermal dolostone bodies can form at shallow burial depths via mixing during fluid pulses, providing a potential explanation for the mass balance problem often associated with their genesis.     

西南印度洋中脊热液区烃类有机质组成及其成因意义

利用气相色谱(GC)、气相色谱-质谱联用仪(GC-MS)测定了西南印度洋中脊49.6°E热液区热液产物中的可溶有机质,结合生物标志物和单体同位素分析,对烃类有机质的组成、来源及成因意义进行了探讨。硫化物烟囱体以正构烷烃(3.437~3.962μg/g)为主要烃类,L/H1,C22以上烷烃具有轻微奇碳数优势(CPI=1.140~1.209),NAR接近0;生物标志物类型丰富(Sq、IS40、烷基环己烷),C31藿烷22S/(R+S)高达0.77,且缺少17β(H),21β(H)构型藿烷;低碳数饱和脂肪酸为主要脂肪酸类型,异构/反异构脂肪酸含量显著,缺少单不饱和脂肪酸。热液蚀变岩以异构烷烃(2.094μg/g)为主要烃类,正构烷烃以低碳数(L/H=1.33)、偶碳优势(CPI=0.377)为特征;脂肪酸以单不饱和脂肪酸为主。结果表明,海洋原生生物体是49.6°E热液区主要的烃类有机质输入源,热液流体温度及化学条件是控制热液喷口区原生生物群落分布及热液产物中烃类有机质组成的主要因素。生物标志物类型显示硫化物烟囱体中具有产甲烷古菌与硫酸盐还原菌共存的现象,反映出热液流体中富含H2,表明49.6°E热液区具有非生物合成烃类的可能。