阿塔卡马海沟表层水颗粒有机碳与微生物群落呼吸作用的时空变化研究

海沟是全球大洋体系的重要组成部分。研究这一极端环境的生物地球化学循环过程有助于我们进一步理解海洋的物质循环。前期研究发现,海沟表层水体的初级生产力(NPP)对海沟沉积物埋藏的有机碳性质具有重要影响,但是,颗粒有机碳(POC)在沉降过程中被微生物呼吸和降解的过程尚不清楚。因此,本研究利用2018年春"太阳号"阿塔卡马海沟(Atacama Trench)国际联合航次SO261所采集的表层水样品,测试其中POC浓度、C/N、δ¹³C、δ¹⁵N等参数,并结合0.2—0.8、0.8—3.0、>3.0μm三种粒径微生物群落呼吸(microbial community respiration,MCR)速率测试,探究其日变化模式及不同站位的空间变化模式,进而衡量微生物对POC的呼吸降解作用。结果表明,该海域表层水中对POC降解占主导作用的微生物类群粒径为0.8—3.0μm;24 h时间序列实验表明MCR随时间呈现"M"型曲线的双峰变化模式,且和C/N、δ¹³C、δ¹⁵N等参数变化趋势吻合,表明同一站位的呼吸速...     

针铁矿对湖泊草、藻来源可溶有机质的非均质吸附

为探究富营养化湖泊中自生源可溶有机质(DOM)在泥水界面的吸附行为,以马来眼子菜(Potamogeton malaianus)和铜绿微囊藻(Microcystis aeruginosa)释放的DOM为代表,考察针铁矿对草、藻源DOM中不同组分的吸附特征.三维荧光平行因子分析表明类富里酸组分C1和类胡敏酸组分C4的含量很低,而类蛋白物质(类酪氨酸组分C2和类色氨酸组分C3)分别占草、藻源DOM荧光组成的70%和93%. 2种DOM均可被针铁矿吸附,吸附过程符合伪一级动力学.通过等温线拟合发现针铁矿吸附藻源DOM的非线性更强,饱和吸附量(23.77 mg/g)高于草源DOM(19.10 mg/g).特别地,类蛋白组分呈现非线性吸附,而类腐殖物质的吸附近似线性,且针铁矿对于DOM各荧光组分的吸附量顺序为:C3>C2> C4> C1,此非均质吸附特征与DOM组分的初始含量、分子大小、芳香性及有效吸附位点有关.红外光谱证实氨基、羧基和羟基是吸附过程中的重要官能团.因此,草、藻源DOM显著改变了针铁矿表面的有机物质组成,影响湖泊沉积物的生物地球化学行为.     

台湾海峡中北部上升流区各种形态磷的化学特性

根据１９８８年７月调查资料讨论了台湾海峡中北部海域夏季上升流区各种形态磷的分布特征。结果表明，上升流中心区（即海坛岛东侧一带水域）具有低温、高盐、低溶解氧；ＤＩｐ，ＴＤＰ，ＰＰ，ＴＰ较高；ＤＯＰ较低（０．２７）；及ＤＩＰ／ＤＯＰ比值（约为１）较高的特性。ＤＯＰ是该海域磷的主要形态（占ＴＰ的４９．２％），其含量分布及其形态转化与生物活动直接相关，是该海域生物生产力高的体现。     

Distribution of dissolved organic carbon in and near the Prydz Bay, Antarctica

INTRODUCTIONDissolvedorganiccarbon (DOC)makesupthesecondlargestofthebioactivepoolsofcar bonintheocean ,secondtothelargestpoolofdissolvedinorganiccarbon .Theglobaldissolvedorganiccarbonpoolisestimatedtobe 6 85Gt,avaluecomparabletothemassofCO2 intheat mosphere (Hedges,1 992 ) .Thesizeofthereservoir,aswellasitsdynamics ,indicatesthatDOCplaysacentralroleintheoceancarboncycle .AsitrelatestogreenhousegasessuchasCO2 andassociatesclimatecycle ,oceanicDOCbiogeochemicalcycleshavebeenoneoftheh…     

Deposition Rates of Terrestrial and Marine Organic Carbon in the Osaka Bay, Seto Inland Sea, Japan, Determined Using Carbon and Nitrogen Stable Isotope Ratios in the Sediment

Carbon and nitrogen stable isotope ratios (¹³C and ¹⁵N) of surface sediments were measured within Osaka Bay, in the Seto Inland Sea in Japan, in order to better understand the sedimentation processes operating on both terrestrial and marine organic matter in the Bay. The ¹³C and ¹⁵N of surface sediments in the estuary of the Yodo River were less than –23 and 5 respectively, but increased in the area up to about 10 km from the river mouth. At greater distances they became constant (giving ¹³C of about –20 and ¹⁵N about 6). It can be concluded that large amounts of terrestrial organic matter exist near the mouth of the Yodo River. Stable isotope ratios in the estuary of the Yodo River within 10 km of the river mouth were useful indicators allowing study of the movement of terrestrial organic matter. Deposition rates for total organic carbon (TOC) and total nitrogen (TN) over the whole of the Bay were estimated to be 63,100 ton C/year and 7,590 ton N/year, respectively. The deposition rate of terrestrial organic carbon was estimated to be 13,200 (range 2,000–21,500) ton C/year for the whole of Osaka Bay, and terrestrial organic carbon was estimated to be about 21% (range 3–34) of the TOC deposition rate. The ratio of the deposition rate of terrestrial organic carbon to the rate inflow of riverine TOC and particulate organic carbon (POC) were estimated to be 19% (range 3–31) and 76% (range 12–100), respectively.     

Impact of dynamic feedbacks between sedimentation,sea-level rise,and biomass production on near-surface marsh stratigraphy and carbon accumulation

Salt marshes accrete both organic and inorganic sediments. Here we present analytical and numerical models of salt marsh sedimentation that, in addition to capturing inorganic processes, explicitly account for above- and belowground organic processes including root growth and decay of organic carbon. The analytical model is used to examine the bias introduced by organic processes into proxy records of sedimentation, namely ¹³⁷Cs and ²¹⁰Pb. We find that accretion rates estimated using ²¹⁰Pb will be less than accretion rates estimated using the ¹³⁷Cs peak in steadily accreting marshes if (1) carbon decay is significant and (2) data for ²¹⁰Pb extend below the ¹³⁷Cs peak. The numerical model expands upon the analytical model by including belowground processes such as compaction and root growth, and by explicitly tracking the evolution of aboveground biomass and its effect on sedimentation rates. Using the numerical model we explore how marsh stratigraphy responds to sediment supply and the rate of sea-level rise. It is calibrated and tested using an extensive data set of both marsh stratigraphy and measurements of vegetation dynamics in a Spartina alterniflora marsh in South Carolina, USA. We find that carbon accumulation in marshes is nonlinearly related to both the supply of inorganic sediment and the rate of sea-level rise; carbon accumulation increases with sea-level rise until sea-level rise reaches a critical rate that drowns the marsh vegetation and halts carbon accumulation. The model predicts that changes in carbon storage resulting from changing sediment supply or sea-level rise are strongly dependent on the background sediment supply: if inorganic sediment supply is reduced in an already sediment poor marsh the storage of organic carbon will increase to a far greater extent than in a sediment-rich marsh, provided that the rate of sea-level rise does not exceed a threshold. These results imply that altering sediment supply to estuaries (e.g., by damming upstream rivers or altering littoral sediment transport) could lead to significant changes in the carbon budgets of coastal salt marshes.     

旧供水井化学处理方法介绍--以加德满都市旧供水井修复为例

本文以加德满都市旧供水井修复项目为例,针对因滤水管缝隙被化学物质堵塞,导致井出水量逐年减少的旧供水井。通过井下电视摄像系统检查,采用六偏磷酸钠、氨基黄酸等有机酸,结合刷洗、高压喷射等机械方法进行处理,使旧供水井出水量得到明显提高。     

不同温度、羧酸溶液中长石溶解模拟实验

报道了在100℃、140℃下微斜长石在不同羧酸溶液中的溶解实验数据。通过实验表明1)反应温度增高,可增强溶液中阳离子的活性和迁移性,加快长石溶解的反应速率,促进长石的溶解。2)在强酸性条件下,pH值的变化可影响长石的溶解。但在中等酸性条件下,pH值对长石的溶解影响很小。3)羧酸(乙二酸)可不同程度地促进长石溶解,可通过形成乙二酸络合物的形式,增加离子在溶液中的溶解度。但乙酸络合物的作用不明显。长石溶蚀导致岩石孔隙度变大,并且改善孔喉性质。同时,由于乙二酸络合物的存在,增加了Si在溶液中的溶解度,阻止了石英加大和其它成因SiO₂的生成,有利于次生孔隙和原生孔隙的保存。4)长石溶解使溶液中Al的浓度较高,但由于铝-羧酸络合物的亲油性比亲水性强,故有一部分Al被分配到油相中,这也是目前大多数油田水中Al浓度偏低的主要原因。     

现场海水中有机污染物光学测量方法研究

介绍了一种用光学方法对海水中的有机污染物（主要包括：叶绿素-a、黄色物质、石油）进行测量的光学系统，该系统可同时测量海水中多种有机污染物的种类和浓度。     

莱州湾沉积物有机质来源

应用C/N、δ13C、δ15N解析了莱州湾沉积物有机质来源,发现湾内有机质主要存在海洋、河口浮游植物以及陆地有机质3种来源。通过C/N、δ13C定量示踪,发现海洋浮游植物是湾内沉积物有机质的最主要来源,相对含量在41.6%—58.5%之间。河口浮游植物有机质、陆源有机质相对含量波动较大,分别在3.8%—43.8%、0—53.5%之间。海洋浮游植物有机质在整个海湾都表现出较高含量。近岸河口附近海域往往表现出高含量的河口浮游植物有机质特征,陆源有机质含量较高区域大都集中在黄河口周围海域,高河口浮游植物有机质以及高陆源有机质特征在黄河口周围海域均有出现。