黑河中游临泽绿洲农田土壤有机质时空变化特征

土壤有机质是表征土壤质量的一个重要指标,持续稳定的有机质含量是土壤维持生产能力的基础。土壤有机质的动态演变可以表征土地利用和管理水平。结合地理信息系统,运用地统计方法研究了黑河中游的临泽县绿洲农田20多年来土壤有机质含量的时空变化特征。结果表明:(1)1982年0~20 cm耕层土壤有机质含量平均为12.78±4.38 g/kg,2008年平均为13.76±4.02g/kg;从1982-2008年,有机质含量总体有所上升。(2)两个时期的土壤有机质的实验变异函数值与理论变异函数拟合均较好;克立格插值和不同时期的有机质空间分布图叠加运算表明,由于人为活动的影响,土壤有机质的结构性空间变化程度有所减弱。(3)临泽县土壤有机质含量和变化具有一定的区域性特点:南部的山前平原地区土壤有机质含量较高,呈现上升趋势;中部地势低下的区域土壤有机质相对较高,由于农田面积扩大,有机肥供应不足而下降显著;北部绿洲与戈壁交错带土壤有机质偏低。总体来看,临泽县土壤有机质含量有所上升,但局部地区的有机质发生了下降。为了防止局部区域土壤有机质下降引起土壤退化,应该采取加大有机肥投入和实施秸秆还田等措施。     

星地多源数据的区域土壤有机质数字制图

土壤有机质(SOM)是全球碳循环、土壤养分的重要组成部分,精确估算土壤有机质含量具有重要意义。本文以中国东北—华北平原为研究区,收集了1078个土壤样本,以遥感数据(MODIS,TRMM和STRM数据)与土壤地面光谱数据为预测因子,运用基于树形结构的数据挖掘技术构建土壤有机质-环境预测因子模型进行数字土壤制图。通过不同建模样本数建模精度比较,选择300个样本数时的模型为最优模型。建模结果表明土壤光谱和气候因子是研究区SOM变异的主控因子,生物因子次之,而地形因子影响最小。预测结果经检验,RMSE为7.25,R2为0.69,RPD为1.53制图结果与基于第二次全国土壤普查数据的土壤有机质地图具有相似的分布规律,呈现SOM自东北向西南递减的趋势。通过比较分析发现,经过20年左右的土地开发与利用,研究区低SOM和高SOM含量土壤面积减少,而中等SOM含量土壤面积增加。     

土壤有机物质对土壤介电常数的影响

土壤介电常数是开展微波土壤水分和冻融状态的监测的基础,也是植被和积雪的下垫面边界条件,然而目前已有的介电常数研究都没有对高有机质含量的土壤开展系统观测。本文将土壤中的自然有机物质分为腐殖质和植物性残留物两类。采用控制变量实验方法,通过测量5种不同有机质含量的东北黑土和加入不同比例毛白杨碎屑的扁都口草甸土,研究了腐殖质和植物性残留物的对土壤介电常数的影响。结果表明,腐殖质会降低干燥土壤的容重,从而发挥间接作用,使介电常数降低;而对于相同容重下观测的潮湿土壤,腐殖质含量较多的土壤介电常数更大。与Dobson模型的比较显示,在29℃室温下,腐殖质对25%重量含水量潮湿土壤实部的影响在±2左右,虚部能达到1。与腐殖质相比,植物性残留物对风干土壤和潮湿土壤的影响都十分明显。植物性残留物能有效地疏松土壤并代入植物组分的介电特征。当重量含水量为30%时,含毛白杨含量为20%的混合土壤比纯扁都口土壤在实部平均减小3—7左右,虚部减小 1—3左右。因此,根据实验观测以及和模型的比较,土壤中的有机物质会改变土壤介电性质,对微波遥感造成影响。     

运用地统计学的土壤有机碳含量空间分布研究

运用GIS地统计、缓冲区分析、叠置分析等方法,初步研究了西昌市邛海盆地土壤有机碳空间变异特征及主要影响因素。分析结果表明,研究区土壤样本,呈正态分布,属中等变异强度,高值区位于主城区东南部和邛海海域东南部,低值区位于邛海海域东北部,并向西北方向递增。不同土壤质地其含量显著不同,中性条件下,其含量较高;不同缓冲区范围内,其含量表现出相应的相关性。     

Re-parameterization of a quasi-analytical algorithm for colored dissolved organic matter dominant inland waters

Quasi-Analytical Algorithms (QAAs) are based on radiative transfer equations and have been used to derive inherent optical properties (IOPs) from the above surface remote sensing reflectance (R_rs) in aquatic systems in which phytoplankton is the dominant optically active constituents (OACs). However, Colored Dissolved Organic Matter (CDOM) and Non Algal Particles (NAP) can also be dominant OACs in water bodies and till now a QAA has not been parametrized for these aquatic systems. In this study, we compared the performance of three widely used QAAs in two CDOM dominated aquatic systems which were unsuccessful in retrieving the spectral shape of IOPS and produced minimum errors of 350% for the total absorption coefficient (a), 39% for colored dissolved matter absorption coefficient (a_CDM) and 7566.33% for phytoplankton absorption coefficient (a_phy). We re-parameterized a QAA for CDOM dominated (hereafter QAA_CDOM) waters which was able to not only achieve the spectral shape of the OACs absorption coefficients but also brought the error magnitude to a reasonable level. The average errors found for the 400–750 nm range were 30.71 and 14.51 for a, 14.89 and 8.95 for a_CDM and 25.90 and 29.76 for a_phy in Funil and Itumbiara Reservoirs, Brazil respectively. Although QAA_CDOM showed significant promise for retrieving IOPs in CDOM dominated waters, results indicated further tuning is needed in the estimation of a(λ) and a_phy(λ). Successful retrieval of the absorption coefficients by QAA_CDOM would be very useful in monitoring the spatio-temporal variability of IOPS in CDOM dominated waters.     

施肥对新垦绿洲风沙土肥力及碳积累的影响

利用2005年安排在临泽边缘绿洲沙地农田的长期施肥定位试验,研究不同用量有机肥、化肥、有机肥和化肥配施对绿洲沙地土壤肥力及有机碳积累的影响。试验包括高量有机肥单施(M3),氮磷化肥单施(NP3),低、中、高量氮磷钾化肥单施(NPK1,NPK2,NPK3),及低、中、高量氮磷钾化肥配施高、中、低量有机肥9个处理(NPK1M3,NPK2M2,NPK3M1),测定分析10年后不同施肥处理耕层(0~20 cm)土壤物理化学性状特征及有机碳动态。结果表明:施有机肥及有机无机配施处理较单施化肥处理容重下降0.13 g·cm^-3,田间持水量提高6.7%,单施有机肥、有机无机配施较单施化肥,土壤有机碳(SOC)和全氮含量分别提高64.8%、36.3%和64.9%、49.5%。高量施用氮磷化肥和氮磷钾化肥处理全磷含量最高,有机肥及有机无机配施较单施化肥有效氮含量显著增加,有机无机配施及高量施用磷肥土壤有效磷积累明显,高量施用有机肥能显著提升有效钾含量。连续施肥处理10年后,SOC含量提高了1.68~2.84倍,土壤全氮、全磷、碱解氮及有效磷均有一定程度的提高,但单施化肥及有机肥与氮磷化肥配施有效钾含量下降。SOC的积累速率单施化肥、有机无机配施、单施有机肥处理分别为0.27、0.59,0.87 g·kg^-1·a^-1。增施有机肥、适量减少化肥投入、氮磷钾化肥的平衡施用是绿洲沙地农田土壤肥力持续提升的施肥管理对策。     

Regional soil organic carbon prediction model based on a discrete wavelet analysis of hyperspectral satellite data

Most studies have the achieved rapid and accurate determination of soil organic carbon (SOC) using laboratory spectroscopy; however, it remains difficult to map the spatial distribution of SOC. To predict and map SOC at a regional scale, we obtained fourteen hyperspectral images from the Gaofen-5 (GF-5) satellite and decomposed and reconstructed the original reflectance (OR) and the first derivative reflectance (FDR) using discrete wavelet transform (DWT) at different scales. At these different scales, as inputs, we selected the 3 optimal bands with the highest weight coefficient using principal component analysis and chose the normalized difference index (NDI), ratio index (RI) and difference index (DI) with the strongest correlation with the SOC content using a contour map method. These inputs were then used to build regional-scale SOC prediction models using random forest (RF), support vector machine (SVM) and back-propagation neural network (BPNN) algorithms. The results indicated that: 1) at a low decomposition scale, DWT can effectively eliminate the noise in satellite hyperspectral data, and the FDR combined with DWT can improve the SOC prediction accuracy significantly; 2) the method of selecting inputs using principal component analysis and a contour map can eliminate the redundancy of hyperspectral data while retaining the physical meaning of the inputs. For the model with the highest prediction accuracy, the inputs were all derived from the wavelength range of SOC variations; 3) the differences in prediction accuracy among the different prediction models are small; and 4) the SOC prediction accuracy using hyperspectral satellite data is greatly improved compared with that of previous SOC prediction studies using multispectral satellite data. This study provides a highly robust and accurate method for predicting and mapping regional SOC contents.     

云南金顶铅锌矿床的有机成矿作用——来自围岩、矿石中有机质生物标志化合物的证据

云南金顶铅锌矿床是世界上成矿时代最新且唯一的陆相沉积岩容矿的超大型铅锌矿床。矿区存在2类有机质——原生型和迁移型,与矿石共生。生物标志化合物研究结果表明：正构烷烃碳数分布范围较宽,有2种峰型;萜烷化合物的相对丰度五环三萜烷＞三环萜烷＞四环萜烷;规则甾烷C27～C28～C29呈不对称V字型分布;有机质的母质来源以低等水生生源的海藻类为主,伴随有一定量的陆源高等植物组分;有机质沉积于弱氧化—弱还原环境;成矿热液的热力作用使样品遭受了一定程度的热解,部分样品还遭受了生物降解作用;生物标志物多参数对比表明有机质来源于三叠纪三合洞组碳酸盐岩地层。原生型有机质的成矿作用主要体现在对成矿金属元素的预富集上,而迁移型有机质的成矿作用主要是对成矿金属元素的活化运移。     

Relationship between statistical thermal alteration index and vitrinite reflectance for sedimentary rocks in northern Japan with reference to effects for unconformity,faulting, and contact metamorphism

Two organic maturity indices, the statistical thermal alteration index (stTAI) and vitrinite reflectance (R_O), are used to gain insight into the geological histories of sequences of Tertiary and Upper Cretaceous sediments in northern Japan that contain an unconformity and which are affected by faulting and contact metamorphism. The stTAI is based on the brightness, or gray level, of fossil pollen of Pinus, Podocarpus, Abies, and Picea species. Pollen brightness is measured using a transmitted‐light microscope equipped with a computer‐driven digital image processor. The stTAI represents the mean value of the modes for the complete array of indigenous pollen in rock samples. The stTAI indicates the level of organic maturation for Neogene sedimentary rocks of Japan, from incipient diagenesis to early catagenesis (R_O ≤1.0%). With the progressive diagenesis and catagenesis of sedimentary rocks, stTAI values generally show a progressive decrease, whereas R_O values increase. The effects of an unconformity and faulting are more clearly recorded in stTAI trends than in R_O trends. During early stages of organic maturation (R_O ≤0.7%), stTAI shows a rapid decrease, while R_O shows a rapid increase during the mature and post‐mature stages (R_O ≥0.8%). The occurrence of a range in R_O values for a given level of organic maturity makes it difficult to determine the influence of the unconformity on the increasing R_O trend. R_O values show a progressive increase toward an igneous dyke, but this trend is not apparent in stTAI values. Measurements of Tertiary and Upper Cretaceous rocks in Japan reveal that stTAI is more sensitive to heating duration than R_O, although R_O is more sensitive to heating temperature.     

西南喀斯特石漠化过程中土壤有机质组分及其影响因素

通过采集我国西南喀斯特地区不同石漠化阶段典型土壤样品,研究了土壤有机质组分及其影响因素.结果表明:(1)喀斯特地区土壤有机质各组分含量中胡敏素>富里酸>胡敏酸,HA/FA一般<0.4,为富里酸土壤,与同水平地带土壤一致.(2)石漠化过程对喀斯特地区土壤中有机质组成有明显的影响,土壤中胡敏素、富里酸与胡敏酸表现出未石漠化＞潜在石漠化＞轻度石漠化＞中度石漠化的趋势.(3)喀斯特地区土壤有机质组分空间分布有较大差异,剖面层次上各有机质组分胡敏素、富里酸与胡敏酸均表现出表土层>底土层,山区不同部位上表现以山坡中下部有机质含量最高,而以山顶最低,且FA/HA表现出从山顶到山脚有明显增加的趋势.(4)喀斯特地区土壤土壤有机碳、酸碱度、碳酸钙、容重、非晶形氧化铝、颗粒组成、有效磷与土壤有机碳组分间表现出显著或极显著的相关性,土壤有机碳和质地是影响土壤有机碳组分含量的主要因素.