河嘉203H含硫水平气井测试工艺实践

河嘉203H井是川东北河坝构造嘉二高压含硫气藏部署的第一口水平井,具有埋藏深、储层压力高、腐蚀分压高、地层易漏失、水平井压井堵漏难度大的特点,通过开展工具优选、管柱结构优化设计、流程优选,并对替浆、放喷油嘴控制及压井等主要工序的施工工艺参数进行研究,形成了河坝嘉二含硫气藏水平井测试工艺技术体系,并在河嘉203H井获得成功应用。     

闽西南地区块状硫化物矿床的喷流-沉积成矿作用

通过对闽西南地区石炭纪—早二叠世主要块状硫化物矿床的区域成矿背景、贮矿层位特征以及矿石矿物成分、结构构造,硫同位素地球化学特征、成矿温度等分析研究,指出该地区石炭纪—早二叠世块状硫化物矿床的形成多与海底火山活动有关,贮矿层中伴有典型的喷流沉积岩—硅质岩,并提出闽西南地区块状硫化物矿床存在海底喷流-沉积成矿作用的新认识。     

华南型块状硫化物矿床中的胶黄铁矿及其退火作用

华南型块状硫化物矿床中胶黄铁矿的退火过程从早到晚可分成三个阶段:原始晶化变胶体阶段、不等粒变晶生长阶段和颗粒界面调整阶段。不同阶段的矿石各具特征性的结构,反映了燕山期侵入活动对于先存胶黄铁矿的不同程度热效应。     

Interaction of glucose and cellulose with hydrogen sulphide and polysulphides

This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor.     

Responses of the tropospheric ozone and odd hydrogen radicals to column ozone change

The response of tropospheric ozone to a change in solar UV penetration due to perturbation on column ozone depends critically on the tropospheric NO _x (NO+NO₂) concentration. At high NO _x or a polluted area where there is net ozone production, a decrease in column ozone will increase the solar UV penetration to the troposphere and thus increase the tropospheric ozone concentration. However, the opposite will occur, for example, at a remote oceanic area where NO _x is so low that there is net ozone destruction. This finding may have important implication on the interpretation of the long term trend of tropospheric ozone. A change in column ozone will also induce change in tropospheric OH, HO₂, and H₂O₂ concentrations which are major oxidants in the troposphere. Thus, the oxidation capacity and, in turn, the abundances of many reduced gases will be perturbed. Our model calculations show that the change in OH, HO₂, and H₂O₂ concentrations are essentially independent of the NO _x concentration.     

块状硫化物矿床的地球化学找矿标志

近年来国外发现了许多大型块状硫化物矿床，而我国进展还不大。原因之一是我们对这类矿床的地质特征，成矿条件尤其是找矿标志研究还不够。这是一类成矿物质通过热液作用在海底沉积而成的特殊矿床，故在找矿勘探讨既要研究沉积矿时形成的原生晕，又要研究热液经过围岩时蚀变而产生的次生晕?Ｍｎ晕，Ｔｌ，Ｈｇ，Ｂａ，Ａｓ和Ｚｎ等元素的异常，络合剂元素的富集，微量元素的分布，铅同位素，岩石化学异指数尤其是块状硫化物Ｃｕ矿中     

北祁连块状硫化物矿床中矿石和主要矿石矿物地球化学特征

对北祁连山白银矿田和郭密寺矿田中主要矿床的矿石和矿石矿物组分特征研究表明，由于各矿田的成矿条件和地球化学背景存在差异，造成不同矿床的矿石和矿石矿物元素组合各具特色。但作为同一类型矿床，它们之间又有很多共性，特别是同一矿田内各矿床的地球化学特征具有相似性和过渡性，反映了成矿条件变化的趋势。     

电气石和水之间的氢同位素分馏

作者对电气-水体系氢同位素平衡分馏和动力学分馏和动力学分馏开展了实验研究，丰富了羟基矿物氢同位素分馏资料。本文对该研究的实验技术、分析方法作了介绍，并对实验结果进行讨论与国外已有的该方面的资料作了对比。在800-650℃时电气石和水之间氢同位素平衡分馏系数与温度间线性关系为103lna电气石-水=-28.24（106/T2）+2.60；交换速率常数与温度间关系为lnk2=-0.19-6.70（103/T）     

Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.     

绿砷钡铁石在广西的发现

本文研究了在广西德保铜锡矿床氧带化中发现的绿砷钡铁石,给出了它的物理性质、化学成分和晶胞参数等矿物学数据。