Isolation,purification and characterization of the hydrogen evolution promoting factor of hydrogenase ofSpirulina platensis

A component (s-factor) with obvious promoting effect on hydrogen evolution of hydrogenase has been isolated and extracted from a cell-free preparation ofSpirulina platensis. The effect of the s-factor in the reaction system is similar to that of Na₂S₂O₄, but is coupled with light. The s-factor has the maximum absorption peak at 620 nm in the oxidized state, at 590 nm in the reduced state. The partially purified s-factor showed two bands by SDS-PAGE and is distinctly different from phycocyanin, which has no change of oxidized state and reduced state absorption spectra, and also has no promoting effect on hydrogenase ofSpirulina platensis under the light. The research supported by the NSFC.     

四川彭州大宝山铜矿矿石与三星堆青铜器关联性研究

四川省广汉三星堆遗址出土了大量青铜器,目前关于三星堆青铜器铜料来源的研究尚无定论,通过对大宝山铜矿遗留矿洞进行实际调查,并在不同采矿点采集矿石以及冶炼弃渣样品进行铅同位素测定以及Cu、Pb、Zn等主要金属元素,Au、Ag、Se、As、Sb等亲铜元素和Ni、Co等亲铁元素的含量测定。采用铅同位素比值法和微量元素示踪法,与前人对三星堆青铜器化学成分的研究结果进行比对,综合分析大宝山铜矿与三星堆青铜器铜料来源的关联性,结果揭示：（1）大宝山铜矿石为普通铅,用铅同位素比值法对三星堆这类含特殊铅青铜器的铜料进行溯源研究不能准确的得到其铜矿石来源。（2）微量元素含量特征表明三星堆青铜器中大部分青铜器的微量元素组合特征与大宝山铜矿的微量元素特征接近。（3）通过微量元素的进一步因子分析和聚类分析,表明三星堆部分青铜器的微量元素组合特征与大宝山铜矿大部分样品相似,该部分青铜器铜料很可能来自大宝山铜矿。     

河北省北部晶质石墨矿层岩(矿)石地球化学特征与成因分析

晶质石墨是一种新兴战略矿产。近年在河北省北部发现了多处大中型晶质石墨矿床,主要赋矿层位于新太古代崇礼上岩群、古元古代红旗营子岩群等,具有良好的成矿潜力。通过系统的野外地质调查与采样、分析测试工作,详细研究了赋矿层位的岩相学、地球化学特征,并对碳质来源进行了分析。结果表明:赋矿岩石主要为含石墨黑云斜长变粒岩、片麻岩与透辉岩,原岩恢复以砂泥质碎屑岩、钙质沉积岩为主。主量元素含量变化较大, SiO₂含量为38.90%～80.42%, CaO+MgO为2.05%～31.93%, Al₂O₃为1.50%～15.34%;稀土元素含量为79.1～321.4μg/g, PAAS标准化分布模式一般具有右倾或较平坦分布特征, δCe略具负异常,部分具有δEu异常。微量元素特征指示沉积环境为滨浅海环境,部分地区存在富氧条件,局部为还原环境或存在热液加入。石墨中碳同位素值为–26.0‰～–20.7‰,主要来源于生物成因有机碳;大理岩碳同位素值为–3.8‰～1.1‰,主要来源于碳酸盐岩成因无机碳。区内晶质石墨矿层分布受到地层、岩性、岩相控制,含矿...     

塔中地区奥陶系喜马拉雅山期S干气充注的证据

塔中地区奥陶系天然气成因多样;Ⅰ号坡折带中东部奥陶系天然气以高干燥系数、 甲烷同位素值重为特征;与塔深1井寒武系原油裂解气接近;应主要来自寒武系原油裂解气成因。寒武系贫H2S、 高成熟原油裂解气在喜马拉雅山期时;气侵奥陶系油气藏;得到了以下主要证据的支持: 1）天然气甲烷δ13C值大多比Chung et al.（1988）天然气模式甲烷δ13C值计算值高3‰以上;2）干燥系数与甲烷δ13C值大体上具有正相关关系;3）天然气干燥系数与H2S含量大体上具有负相关关系。这些特征表明;存在贫H2S、 相对富13C甲烷为主的干气与富H2S、 相对贫13C甲烷的湿气混合作用。奥陶系中H2S-δ34S 值为14‰～20‰;远低于中深1井寒武系原地热化学硫酸盐还原作用（TSR）成因的H2S（33‰）;支持了奥陶系中H2S并不是来源于寒武系古油气藏。于是提出;来自寒武系贫H2S的干气在喜马拉雅山期对良里塔格组和鹰山组油气藏发生了气洗;油气藏的气/油比值增大、 导致了原油蜡含量增高、 甲烷δ13C值发生正偏移。     

从化石群及壳体同位素看古近纪东营湖湖水化学

从"海源陆生化石"、壳体O、C和S同位素等几个新的角度和方法对山东东营凹陷古近纪古湖泊湖水化学性质进行讨论.通过与现生"海源陆生生物"的比较,得出原先认为是"海相"标志的有孔虫、钙质超微化石、沟鞭藻和疑源类、多毛类和鱼类等实际上是"海源陆生化石",它们生活在以Cl-和Na+为主的咸水湖泊环境.超微化石S同位素分析表明,渐新世与始新世钙质超微化石的87Sr/86Sr 比值都明显高于同时期海水的87Sr/86Sr比值,而与现代河、湖水的87Sr/86Sr比值相近,进一步揭示它们生活的环境不是海,而是与海无关的湖.介形虫壳体O、C同位素分析则表明,古东营湖是一封闭型咸水湖泊,从另一角度也否定了与海连通的可能性.根据不同层段同位素特征讨论了湖水矿化度的相对变化.     

秦岭——大别造山带区域地壳Sm-Nd同位素组成及其意义

对秦岭—大别造山带大量Nd同位素资料进行统计,获得了该地区陆壳基底和区域花岗岩类的147Sm/144Nd平均值,分别为0.136和0.108。基于区域资料获得的二阶段亏损地幔模式年龄(T2DM)比用147Sm/144Nd=0.118做参数的计算结果要普遍偏老,两种结果的差异随着模式年龄的偏老明显偏大。本研究获得的该区域地壳147Sm/144Nd组成特征与元素丰度资料之间存在较大差异,结合稀土元素综合对比,表明前人获得的该区域元素丰度资料偏酸性。     

Sr isotope evolution during chemical weathering of granites -- impact of relative weathering rates of minerals

The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in 87Sr/86Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made 87Sr/86Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the prefer-ential release of Sr from dissolving solid phase and the fluctuation of 87Sr/86Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.     

Stable Isotope and Element Geochemistry of Saline Springs in Evaporite-bearing Mengla Basin,South Yunnan,China

正1 Introduction Mengla Basin is a sub-basin in southern evaporitebearing Lanping-Simao Basin.There are many salt springs in the basin.In 2012,11 spring samples were collected for analyses of chemistry and boron,hydrogen and oxygen     

中天山天湖东铁钼矿含矿片麻状花岗岩年代学、地球化学和锆石Hf同位素-对于中天山早古生代构造演化的启示

以中天山东段的天湖东铁钼矿含矿花岗岩为例,在LA-ICP-MS锆石U-Pb年代学测定其为早古生代花岗岩（（445.3±4.6） Ma）基础上,通过岩相学、地球化学及锆石原位Hf同位素组成等多方面研究,探讨该岩体的成岩作用及其构造背景。天湖东含矿片麻状花岗岩的主要矿物为斜长石、石英、钾长石,并含少量黑云母和角闪石等。全岩地球化学分析结果表明,该片麻状花岗岩高硅、弱富铝、富钙、富钠而贫钾,ASI值为0.68~0.82,属于准铝质钙碱性花岗岩,总体上富集大离子亲石元素（LILE）Rb、Ba等和轻稀土元素La、Ce、Nd等,而亏损高场强元素Nb、Ta、Ti、Yb等,轻重稀土分异明显,轻稀土分异较为明显,而重稀土分异不明显,表现出典型岛弧岩浆岩的地球化学特征。锆石的ε_Hf(445 Ma)值为-6.31~-1.77,二阶段Hf模式年龄（T_DM2）为1.538~1.825 Ga,表明该花岗岩的源区主要为壳源物质。综合分析上述资料,认为天湖东铁钼矿片麻状花岗岩是由俯冲过程中地壳物质重熔的产物。结合前人的研究和本课题组的新近研究成果认为,在早古生代时,中天山为岩浆弧构造环境,形成一系列的钙碱性岩浆岩,而该岩浆弧的形成可能是受到介于吐哈陆块和塔里木板块之间的古天山大洋在早古生代时期向南俯冲而形成的。     

GEOCHEMISTRY

正20141357 Guo Tao(School of Mathematics and Science,Shijiazhuang University of Economics,Shijiazhuang 050031,China);Hu Jiawen Assessment on the New Pressure-Volume-Temperature(PVT) Data of Supercritical Water(Geological Journal of China Universities,ISSN1006-7493,CN32-1440/P,19(3),2013,p.447-455,9 illus.,3 tables,32 refs.)Key words:supercritical fluids