褐藻酸降解菌的产酶条件研究

以海带病烂处分离到的别单胞菌属（Alkteromonas)的褐藻酸降解菌菌株A1为研究对象，在该菌的产酶条件进行了研究。结果表明，产酶的最适温度20℃，褐藻酸钠浓度（质量分数）0．5％－0．6％，pH7.5，盐度15，氮源为（NH4)2SO4，培养时间72h。     

松辽盆地葡萄花油田北部鞍部地区成藏控制因素分析

在系统描述葡萄花油田北部鞍部地区构造特征和断裂体系的基础上,分析了烃源岩大量排烃期与构造形成时期的匹配关系、砂体分布、地层压力和断层封闭性对研究区成藏的控制作用。研究结果表明:烃源岩大量排烃期和构造形成时期良好匹配,地层压力低势区和在成藏时期断块边界断层侧向开启是成藏的有利条件,构造和砂体分布则是成藏的主要控制因素。研究区成藏条件较好,可作为有利扩边潜力区。     

基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

Research Advances and Exploration Significance of Large-area Accumulation of Low and Medium Abundance Lithologic Reservoirs

In recent years, a series of large low and medium abundance oil and gas fields are discovered through exploration activities onshore China, which are commonly characterized by low porosity-permeability reservoirs, low oil/gas column height, multiple thin hydrocarbon layers, and distribution in overlapping and connection, and so on. The advantageous conditions for large-area accumulation of low-medium abundance hydrocarbon reservoirs include： （1） large （fan） delta sandbodies are developed in the hinterland of large flow-uncontrolled lake basins and they are alternated with source rocks extensively in a structure like ＂sandwiches＂; （2） effective hydrocarbon source kitchens are extensively distributed, offering maximum contact chances with various sandbodies and hydrocarbon source rocks; （3） oil and gas columns are low in height, hydrocarbon layers are mainly of normal-low pressure, and requirements for seal rock are low; （4） reservoirs have strong inheterogeneity and gas reservoirs are badly connected; （5） the hydrocarbon desorption and expulsion under uplifting and unloading environments cause widely distributed hydrocarbon source rocks of coal measures to form large-area reservoirs; （6） deep basin areas and synclinal areas possess reservoir-forming dynamics. The areas with great exploration potential include the Paleozoic and Mesozoic in the Ordos Basin, the Xujiahe Formation in Dachuanzhong in the Sichuan basin, deep basin areas in the Songliao basin etc. The core techniques of improving exploration efficiency consist of the sweetspot prediction technique that focuses on fine characterization of reservoirs, the hydrocarbon layer protecting and high-speed drilling technique, and the rework technique for enhancing productivity.     

The distribution and geological significance of carbazole compounds in Silurian paleo-pools of the Tarim Basin,Northwest China

The results presented in this paper indicated that the carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and （or） bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin （at the end of the Silurian period） and at the second stage in the Awati area （in Permian）, the hydrocarbons experienced a long-distance migration.     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag

Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas： the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion： free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps.     

应用生烃动力学法研究川东上二叠统烃源岩生烃史

现今川东上二叠统烃源岩生烃史研究具有局限性.首先,没有对上二叠统Ⅰ-Ⅱ1型灰岩生油、Ⅲ型泥岩的生气史分开评价;其次,海相镜质组反射率通过拟合公式换算成镜质体反射率评价烃源岩成熟度具有局限性.针对上述不足,笔者通过热模拟实验,利用化学动力学方法,标定出两类源岩生油、生气的动力学参数,并结合川东地区的埋藏史及热史,模拟出源岩有机质的成烃转化率曲线.研究表明:上二叠统灰岩、泥岩有机质在距今200 Ma和190 Ma分别进入了生油、生气门限,而在距今170 Ma和140 Ma生烃结束.     

The paleoclimatic records and the relevance with the formation of hydrocarbon source rocks:A case study of Huanghekou depression,Bohaiwan basin

Bohaiwan basin, covering an area of 200 000 km², is one of the most important oil-bearing basins in Eastern China. Rifting processes formed the basin, and two evolution phases can be recognized. The rifting phase developed in Paleogene, and post-rifting phase occurred in Neogene. More than 200 oil fields have been found in the onshore and offshore area in Bohaiwan basin in recent years. The distribution of the oil fields is closely related to the rich hydrocarbon depressions, and the Huanghekou depression is one of these rich hydrocarbon depressions. A number of large and medium-sized oil and gas fields have been found in this area, such as BZ25-1, BZ34 etc., and the hydrocarbon was mainly from the Huanghekou depression. The formation of rich hydrocarbon source rocks depended on the tectonic setting of rapid subsidence, favorable paleoclimatic conditions and paleolimnology environments. The effects of paleoclimatic condition on hydrocarbon source rocks are the focus of this paper. __________ Translated from Geological Bulletin of China, 2007, 26(7): 830–840 [译自: 地质通报]     

Fossil carotenoids and paleolimnology of meromictic Mahoney Lake,British Columbia,Canada

Vertical distribution of fossil carotenoids in a sediment core from meromictic Mahoney Lake was studied. Besides okenone and demethylated okenone, lutein and zeaxanthin and-carotene isomers were identified. No carotenoids typical for purple nonsulfur or green sulfur bacteria were detected. The ratio of zeaxanthin to lutein (above 1:1 in all samples) indicates a dominance of cyanobacteria over green algae in the phytoplankton assemblages of the past. Okenone, which is found exclusively in Chromatiaceae, was the dominating carotenoid in all sediment zones.The oldest sediment layers containing okenone were deposited 11 000 years ago. Between 9000 and 7000 and since 3000 years b.p., Chromatiaceae reached a considerable biomass in the lake. Vertical changes in okenone concentration were not related to changes of paleotemperatures. In contrast, okenone concentrations decreased during periods of volcanic ash input. During most of the lake history, however, mean okenone concentrations were positively correlated with sedimentation rates. This indicates that vertical changes of okenone concentration in the sediment reflect past changes of purple sulfur bacterial biomass in the lake.According to these results, the past limnology of Mahoney Lake resembled that of the present with a sulfide-containing monimolimnion and a well-developed population of okenone-bearing purple sulfur bacteria.