鄂尔多斯盆地南部马莲河流域地下水中锶富集特征及成因分析

马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr²⁺)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr²⁺的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr²⁺的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr²⁺的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。     

Geochronology and geochemistry of Cretaceous Nanshanping alkaline rocks from the Zijinshan district in Fujian Province,South China: Implications for crust–mantle interaction and lithospheric extension

In situ zircon U–Pb ages and Hf isotopic data, major and trace elements, and Sr–Nd–Pb isotopic compositions are reported for Nanshanping alkaline rocks from the Zijingshan district in southwestern Fujian Province (the Interior or Western Cathaysia Block) of South China. The Nanshanping alkaline rocks, which consist of porphyritic quartz monzonite, porphyritic syenite, and syenite, revealed a Late Cretaceous age of 100–93 Ma. All of the rocks show high SiO₂, K₂O + Na₂O, and LREE but low CaO, Fe₂O₃^T, MgO, and HFSE (Nb, Ta, P, and Ti) concentrations. These rocks also exhibit uniform initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7078 to 0.7087 and ε_Nd(t) values of −4.1 to −7.2, thus falling within the compositional field of Cretaceous basalts and mafic dikes occurring in the Cathaysia Block. Additionally, these rocks display initial Pb isotopic compositions with a ²⁰⁶Pb/²⁰⁴Pb_i ratio of 18.25 to 18.45, a ²⁰⁷Pb/²⁰⁴Pb_i ratio of 15.63 to 15.67, and a ²⁰⁸Pb/²⁰⁴Pb_i ratio of 38.45 to 38.88. Combined with the zircon Hf isotopic compositions (ε_Hf(t) = −11.7 to −3.2), which are different from those of the basement rocks, we suggest that Nanshanping alkaline rocks were primarily derived from a subduction-related enriched mantle source. High Rb/Sr (0.29–0.65) and Zr/Hf (37.5–49.2) but relatively low Ba/Rb (4.4–8.1) ratios suggest that the parental magmas of these rocks were most likely formed via partial melting of a phlogopite-bearing mantle source with carbonate metasomatism. The relatively high SiO₂ (62.35–70.79 wt.%) and low Nb/Ta (10.0–15.3) ratios, positive correlation between SiO₂ and (⁸⁷Sr/⁸⁶Sr)_I, and negative correlation between SiO₂ and ε_Nd(t) of these rocks suggest that the crustal materials were also involved in formation of the Nanshanping alkaline rocks. Combined with geochemical and isotopic features, we infer magmatic processes similar to AFC (assimilation and fractional crystallization) involving early fractionation of clinopyroxene and olivine and subsequent fractionation of biotite-dominated assemblages coupled with a lesser amount of crustal contamination, thereby forming the Nanshanping alkaline rocks. The Nanshanping alkaline rocks appear to be associated with an extensional environment in the Cathaysia Block. This extensional regime could have resulted in the slab break-off and rollback of the subducting paleo-Pacific plate and the upwelling of the asthenospheric mantle, which induced partial melting of the enriched lithospheric mantle in the Cretaceous.     

Stable isotope study of the Archaean rocks of the Vredefort impact structure,central Kaapvaal Craton,South Africa

The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ ¹⁸O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ ¹⁸O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ ¹⁸O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ ¹⁸O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ ¹⁸O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

淮南顾北矿F104断层两侧岩溶水化学形成机制及导隔水性评价

利用断层两盘岩溶水化学特征判断其导隔水性对于我国华北型煤田水害防治具有十分重要的实践意义。以顾北矿F₁₀₄断层两侧太原组岩溶地下水为研究对象,在分析断层两盘水文地质条件基础上,采用Piper三线图、离子组合比和主成分法,分析了主要组分来源及水-岩作用差异性,并采用PHREEQC软件对岩溶地下水进行反向水化学模拟。结果表明:南北区岩溶水均存在方解石和白云石的溶解和沉淀现象,南区阳离子交换吸附和脱硫酸作用程度强于北区,而北区黄铁矿氧化和岩盐溶解作用较南区明显,南北两区水化学环境及水-岩作用存在显著差异,进而推断F₁₀₄断层具有较好的阻水性,且影响了其两侧的氧化-还原环境及温度差异,控制着地下水径流方向和水-岩作用程度。      

水平和竖向地震作用下液化场地群桩基础动力响应试验研究

为研究水平和竖向(双向)耦合地震作用下液化场地群桩基础的动力响应,设计了可液化地基-群桩基础-框筒结构动力相互作用体系振动台模型试验。选取不同类型模拟地震波作为振动台试验激励,通过对比水平地震作用和双向耦合地震作用下土体加速度、超孔隙水压力和群桩应变等试验结果,进而分析双向耦合地震作用对可液化地基和群桩基础动力响应的影响。研究结果表明:双向耦合地震作用下,液化场地土体竖向加速度峰值随土体埋深高度的减小而逐渐增大;饱和砂土的液化效应与双向耦合地震作用和输入地震波的类型有关;相比水平地震作用,不同种类波双向耦合地震作用下群桩基础桩身中部和底部的应变峰值增大,桩顶应变峰值变化略有不同;双向耦合地震作用加剧了建筑结构群桩体系的摇摆和倾斜。研究结果对可液化地基上群桩基础的抗震设计和防灾减灾具有十分重要的研究意义。     

采用复合单元法模拟裂隙多孔介质变饱和流动

采用复合单元法建立了模拟裂隙多孔介质变饱和流动的数值模型。该模型具有以下特点:裂隙不需要离散成特定单元,而是根据几何位置插入到孔隙基质单元中形成复合单元;在复合单元中,分别建立裂隙流和孔隙基质流的计算方程,二者通过裂隙-基质界面产生联系并整合成复合单元方程;复合单元方程具有和常规有限单元方程相同的格式,因此,可以使用常规有限单元方程的求解技术。采用欠松弛迭代、集中质量矩阵以及自适应时步调节等技术,开发了裂隙多孔介质变饱和流动计算程序。通过模拟一维干土入渗和复杂裂隙含水层内的流动问题,验证了该模型的合理性和适用性。模拟结果为进一步认识非饱和裂隙含水层地下水流动特性提供了理论依据。     

基于GIS的三维水文地质建模及应用——以咸阳市为例

为了提升城市地质调查工作的总体服务水平,通过搭建城市地质综合GIS平台,采用人机交互式单元分割-拼接建模方法,以水文地质剖面为基础数据,加入水文地质钻孔、水文地质图、地表高程等多源数据作为约束,首次在咸阳地区构建了建模深度300 m、建模面积3714 km2的水文地质三维结构模型.本次建模的工作顺利完成为研究咸阳地区地下水文地质结构、地下水资源赋存特征提供了三维可视化的数据支撑,也为其他城市开展类似建模工作提供借鉴.     

桩-土相互作用影响的模型试验研究

通过将模型试验、现场实测的结果与弹性理论解进行对比,指出弹性理论解夸大了桩-桩、桩-土、土-土相互作用影响,造成沉降计算值偏大和过高估计桩顶反力的不均匀性（或筏底地基土反力的不均匀性）,并提出对弹性理论解进行修正的途径和方法。     

Makran ophiolitic basalts (SE Iran) record Late Cretaceous Neotethys plume-ridge interaction

ABSTRACT

The Makran complex in southeast Iran provides a spectacular subduction-related accretionary complex to understand the mechanism of oceanic accretion and the evolution of subduction zones. In this paper, we present new major and trace element data as well as isotopic compositions of mafic volcanic blocks from the Makran ophiolitic mélange complex (OMC). Our aim is to assess the genesis of these rocks and discuss their implications on the evolution of Neotethys Ocean. These volcanic blocks are composed mainly of basalts with minor trachytes. The Makran lavas are occasionally interlayered with tuff layers. Zircons from these tuffs give U-Pb ages of 95 Ma, which is well in accordance with the reposted microfossil data for the interlayered pelagic limestones with pillow lavas. Makran basalts can be geochemically subdivided into four groups; normal to transitional MORB, enriched-MORB, Plume-type MORB and alkaline (-OIB-like) basalts. The OIB-like pillow lavas are represented by high values of Th/Tb (6.3–7.4) which are higher than other basalts (group 1 = 0.3–0.8; groups 2 = 0.7–1.6; group 3 = 1.58–1.36).¹⁴³Nd/¹⁴⁴Nd_(t) ratios for basalts ranges from 0.51247 to 0.51292, whereas ⁸⁷Sr/⁸⁶Sr_(t) isotopic composition of the OMC lavas varies from 0.704433 to 0.709466. The Pb isotopic composition of the lavas are quite high, ranging from 15.49–15.66 for ²⁰⁷Pb/²⁰⁴Pb_(t), 18.09–19.12 for ²⁰⁶Pb/²⁰⁴Pb_(t) and 37.80–39.23 for ²⁰⁸Pb/²⁰⁴Pb_(t). The chemistry of these rocks suggests that they were formed most likely in an oceanic setting with clear plume-ridge interaction. These rocks can form from partial melting of a highly heterogeneous mantle source, which is extensively metasomatized with deep mantle OIB-type components. We suggest these rocks have been generated in an oceanic ridge with plume-ridge interaction, similar to the Iceland-Reykjanes Ridge, before being fragmented and accreted into the Makran accretionary complex.     

100MPa、800℃下Mo和W在流体／花岗质熔体相间分配的实验研究

利用“RQV-快速内冷淬火”（外加热冷封式）高温高压实验装置,在100MPa、800℃条件下,以东秦岭地区出露的高钾钙碱性岩浆岩（合峪花岗岩）为实验初始物,实验研究了Mo和W在花岗岩-H2O、花岗岩-NaCl（KCl）-H2O及花岗岩-NaF-H2O体系流体／熔体相间的分配行为。实验结果表明,Mo比W更倾向于分配进入流体相（DMo^流体/溶体〉〉DW^流体/溶体）,相对于纯水体系而言,流体介质中Cl和F的存在均有利于Mo和W向流体相迁移富集,随体系内Cl含量的不断增高,Mo和W的分配系数呈线性增大趋势,而在天然花岗岩可能含有的F含量范围之内,F含量的增高将阻碍Mo、W向流体相迁移,流体介质中Na／K（摩尔比）的变化对Mo和W的分配系数没有明显影响,表明体系碱质（Na或K）类型不是Mo和W在流体／熔体相间分配的主要影响因素。