河北某氧化石英脉型金矿石全泥氰化浸出试验研究

河北省某金矿为氧化石英脉型金矿石,矿石中的金粒微细,平均粒径为0.011 3mm,包裹于黄铁矿、褐铁矿、石英中的金占64.68%,有一部分呈微细粒包裹在土状褐铁矿中,对这种细粒分散的含金氧化矿石采用全泥氰化浸金工艺。将原矿磨矿细度确定为-200目含量占85%,加入石灰对金矿石进行碱预处理,再加入氰化钠浸金,取得了浸出率为96.89%,吸附率为99.55%的试验结果。     

Evaluation of various relationships of reaeration rate coefficient for modeling dissolved oxygen in a river with extreme flow variations in Pakistan

Mathematical relationships have been developed for reaeration rate coefficient (K_a) by various researchers. These relationships have a number of variables such as depth, velocity, width, slope, Froud number, molecular diffusion coefficient, kinematic viscosity and the gas‐transfer Reynolds number. From these variables, 29 relations have been developed and divided into four groups. To evaluate their predictive capability for highly variable flow rivers receiving high pollution loads form large cities, these relationships have been used to model dissolved oxygen (DO) in the River Ravi. Such rivers are either saturated with DO during high flows or anaerobic during critical low‐flow conditions. The evaluation is based on the agreement between model DO values calculated using K_a obtained from the available equations and the measured DO concentrations in the river samples in terms of sum of square of residuals (SSR) and coefficient of determination (R²). It has been found that in general, the group of equations containing depth and velocity as the only two variables affecting K_a performed better than the equations in other groups as reflected by lower SSR and higher R² values. The study results also reveal that the turbulence‐based reaeration rate coefficient equation containing additional variables also resulted in close agreement between DO model results and the measured values. The study results identify the most important parameters affecting the reaeration rate coefficient and the suitability of various K_a relationships as well for rivers with highly variable flows. Copyright © 2012 John Wiley & Sons, Ltd.     

高粘土质氧化矿石制粒实验研究

通过对黔西南贞丰某一典型的高粘土质低晶位金氧化矿石浸出、粘结剂配比实验和催熟剂Ｎｏ．１浸金实验研究,表明少量复合粘结剂的加入,极大改善矿石的性质,提高浸取液的溶液渗稼性。４％复合粘结剂的掺入量,不仅使成球粒在２４ｈ内的抗坟强度达到４．０ｋｇｆ／ｃｍ＾２,而且在２４ｈ内氰化反应近乎完全,金溶出率高达９６％。     

柴达木盆地冷湖地区古近——新近系可地浸砂岩型铀矿成矿前景

从地质、水文地质两个方面入手,分析了柴达木盆地冷湖地区古近—新近系有利于可地浸砂岩型铀矿成矿的铀源,泥—砂—泥结构,补—径—排条件,及不利于可地浸砂岩型铀矿成矿与开发的构造因素。     

回注井与矿井水处理

为解决矿井水排放对周边环境和地下水水质的污染,对矿区水文地质资料进行了认真分析,认为梧桐庄矿井位于鼓山东南端的停滞区,属基本封闭的地垒块段,含水层基本处于停滞状态,具备回注储存高矿化度矿井水的地质构造条件。在选定区内建凿大口径回注井组,将经地面水处理厂多级处理后达标的矿井水,通过管网系统分级配送利用、回注储存,用于矿井生产、生活及农田灌溉。该工艺技术解放煤炭资源3 900万t,实现了水资源循环利用,达到了节能减排,保护生态环境的目的。     

Differential Fractionation of Rare Earth Elements in Oxidized and Reduced Granitic Rocks: Implication for Heavy Rare Earth Enriched Ion Adsorption Mineralization

Ion adsorption rare earth element (REE) deposits in southern China are the exclusive source of heavy REEs (HREEs) in the world, and this HREE‐enriched character of the deposits is inherited from the REE compositions of the underlying granitic rocks. Such HREE‐enriched rocks form from heavy fractionation of reduced granitic magmas. We explore why reduced granitic magmas are enriched in HREEs during the fractionation, based on the REE geochemistry of granitic rocks and abundance of REEs in their constituent minerals in the southwestern Japan arc of Cretaceous to Paleogene age. The compilation of the whole rock geochemistry and REE compositions of the granitic rocks of the Sanin (oxidized), Sanyo (reduced) and Ryoke (reduced) belts in the southwestern Japan arc indicates that: (i) light REEs (LREEs) decease with fractionation of the granitoids in the Sanin belt but this trend is not clear in the granitoids in the Sanyo belt and LREEs rather increase in the Ryoke granitoids; (ii) Eu decreases with fractionation in all the belts; and (iii) HREEs slightly, but steadily decrease in the Sanin belt but enrich significantly in the Sanyo and Ryoke belts with fractionation. Analytical results of REE concentrations by scanning electron microscope with energy dispersive X‐ray spectroscope and laser ablation‐inductively coupled plasma mass spectrometer in the constituent minerals in a granodiorite sample from the Sanin belt show a moderate concentration of REEs in hornblende (577 ppm) in addition to high concentrations in allanite (~20 %), britholite (~30 %), primary titanite (8922 ppm), apatite (4062 ppm), and zircon (1693 ppm). Because primary titanite and allanite are commonly present in the oxidized granitoids but not in the reduced ones, the REE depletion in the fractionated, oxidized granites is attributed to the crystallization of these minerals. In contrast, scarcity of these minerals in the reduced granitoids enriches REEs, in particular HREEs in the fractionated magmas, which finally precipitate REEs in the granites and pegmatites. Both positive, but different correlation ratios between the Nb and Dy concentrations in the granitoids of the Sanin and Sanyo‐Ryoke belts suggest that columbite–pyrochlore‐group and fergusonite‐group minerals are the major HREE host in the oxidized and reduced granites, respectively.     

冰藻对南大洋大西洋扇区南极磷虾越冬期间碳源的贡献

南极磷虾是南大洋生态系统的关键物种, 种群聚集在南大洋的大西洋扇区。海冰在南极磷虾生活史中起着重要作用, 海冰及其冰下环境为磷虾越冬提供了避难场所, 但海冰是否为磷虾越冬提供了重要的饵料存在一定的争议, 对此问题的解决需要量化源于海冰的冰藻对南极磷虾越冬期间饵料及碳源的贡献。基于2020年冬季(3~8月)于南大洋大西洋扇区48.1亚区(布兰斯菲尔德海峡周边区域)和48.3亚区(南乔治亚岛周边海域)采集的磷虾样品, 通过两种高支链类异戊二烯化合物(IPSO₂₅和HBI III)分别作为源于海冰的冰藻和源于水体浮游植物的生物标志物, 对两个区域冬季磷虾对冰藻和浮游植物的依赖进行研究。结果显示, 处于较高纬度、海冰密集度较高的48.1亚区的南极磷虾体内含有更高的IPSO₂₅, 而处于开阔水域48.3亚区的磷虾体内有更高比例的HBI III, 另外48.3亚区磷虾的δ¹³C和δ¹⁵N稳定同位素显著高于48.1亚区的磷虾。48.1亚区南极磷虾越冬期间对浮游植物和冰藻的依赖与体长相关, 其中体长相对较短的早期成体呈现更高的依赖性, 同时该区域磷虾对冰藻的摄食提高了其营养级地位。48.3区南极磷虾越冬期间两种类异戊二烯含量与δ¹⁵N稳定同位素数值呈负相关关系, 表明该区域南极磷虾在初级生产匮乏时会摄食动物性饵料。若未来南大洋大西洋扇区海冰持续减少, 这将对整个磷虾种群、磷虾渔业的可持续发展和区域生态系统的稳定性产生威胁。     

An evaluation method of hydrocarbon generating potential of highly mature and over-mature marine carbonate

How to restore the residual organic carbon and residual hydrocarbon-generating potential is discussed based on the hydrocarbon degradability of source rock. The results indicate there is linear function relationship between the restoring coefficient of residual organic carbon (K_c) and the vitrinite reflectance (R _o%) of various kinds of source rock, but the relationship is secondary functional between the restoring coefficient of residual hydrocarbon-generating potential (K_s) and the vitrinite reflectance (R _o%). It is pointed out thatKc = (1 -Dresidual)/(1 -D _primary),Ks= Kc (D _primary/D _residual). The restoration of residual organic carbon and hydrocarbon-generating potential of the Cambrian and Ordovician highly mature marine carbonate in the Tarim Basin and North China region shows that the lower limit value of hydrocarbon generating potential and the organic matter abundance of carbonate source rock are basically the same as that of clastic rock. The technical difficulty in hydrocarbon generating evaluation of highly mature and overmature carbonate is solved.     

地性线的山地区域的卫星影像几何精纠正

提出了一种山地区域基于DEM地性线的控制纠正新方法,该方法以数字地形模型DEM为无几何变形的控制基准纠正卫星影像。阐述了提取沟谷、山脊、山峰和凹地区域的地性线的原理和算法,给出了山地区域基于地性线进行卫星图像几何精纠正实施步骤,进一步讨论了地性线提取、控制点采集存在的问题,以及解决问题的途径。实验结果表明,对于山地区域,地性线的空间数量数倍于水系、道路等常规地图层;地性线来源于DEM,其空间稳定性和可靠性更高,可以用于山地区域的卫星影像的严格控制纠正。用该方法进行几何纠正处理,几何误差能控制在一个像元的水平上。     

Metallurgy at the Crossroads: New Analyses of Copper‐based Objects at Tianshanbeilu,Eastern Xinjiang,China

Tianshanbeilu is the largest Bronze Age site in eastern Xinjiang, China. Stretching across the entire second millennium BC, it performed a prominent role in connecting the Hexi corridor, Central China and the steppe. A further insight into the metallurgical tradition and the metal supply network is of vital importance to improve our understanding of its multi-connected nature. This paper offers a new set of chemical and isotopic data on the copper-based objects at Tianshanbeilu, including alloyi...