花岗质熔体的结构特征与其产铀潜力

本文从花岗质熔体结构特征的角度,探讨了熔体成分与其产铀潜力之间的关系。分析了熔体中的K,Na对铀富集的控制作用,八面体、四面体空隙和晶体场效应,O/Si比值对铀活动性的影响。讨论了决定熔体粘度的一些因素,提出了熔体相对粘度值的计算方法,结合实例介绍了熔体相对粘度值的意义及地质应用。总结了有利于产铀的熔体结构特征标志。     

The fidelity of melt inclusions as records of melt composition

A series of experiments created melt inclusions in plagioclase and pyroxene crystals grown from a basaltic melt at 1,150°C, 1.0 GPa to investigate diffusive fractionation during melt inclusion formation; additionally, P diffusion in a basaltic melt was measured at 1.0 GPa. Melt inclusions and melts within a few 100 microns of plagioclase–melt interfaces were analyzed for comparison with melt compositions far from the crystals. Melt inclusions and melt compositions in the boundary layer close to the crystal–melt interface were similar, but both differ significantly in incompatible element concentrations from melt found greater than approximately 200 microns away from the crystals. The compositional profiles of S, Cl, P, Fe, and Al in the boundary layers were successfully reproduced by a two-step model of rapid crystal growth followed by diffusive relaxation toward equilibrium after termination of crystal growth. Applying this model to investigate possible incompatible element enrichment in natural melt inclusions demonstrated that at growth rates high enough to create the conditions for melt inclusion formation, ∼10⁻⁹–10⁻⁸ m s⁻¹, the concentration of water in the boundary layer near the crystal was similar to that of the bulk melt because of its high diffusion coefficient, but sulfur, with a diffusivity similar to major elements and CO₂, was somewhat enriched in the boundary layer melt, and phosphorus, with its low diffusion coefficient similar to other high-field strength elements and rare earth elements, was significantly enriched. Thus, the concentrations of sulfur and phosphorus in melt inclusions may over-estimate their values in the bulk melt, and other elements with similar diffusion coefficients may also be enriched in melt inclusions relative to the bulk melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

辽西壳幔熔体相互作用过程和背景的探讨

以辽西阜新地区115Ma快速喷发的玻基方辉安山岩和其下伏的玄武岩为研究对象,通过岩相学研究,发现不同阶段形成的,以不同形式赋存的高镁和高硅玻璃,通过它们追溯地壳-幔熔体混合的过程,在此基础上再进一步探讨壳-幔熔体混合的环境及其底侵作用的构造背景。     

西藏达如错地区晚侏罗世高镁安山岩——班公湖—怒江洋壳俯冲消减的证据

对出露于拉萨地块北部的达如错接奴群安山岩进行了年代学、元素地球化学和锆石原位Hf同位素研究。用LA-ICP-MS技术测得的安山岩锆石206Pb/238U年龄为163.3±1.7Ma,即火山活动时限为晚侏罗世早期。安山岩地球化学研究结果表明,其具有典型高镁安山岩的地球化学特征,所有样品均具有较高的MgO、Mg#值,低的TFeO/MgO值（小于1.5）;所有样品都显示轻稀土元素富集,具有Eu负异常,富集大离子亲石元素、亏损高场强元素的特征;锆石εHf(t)值为较均一的负值（εHf(t)=-8.5~-6.7）。研究表明,达如错高镁安山岩很可能是班公湖—怒江洋壳在俯冲消减背景下,由俯冲沉积物熔融产生的熔体与地幔橄榄岩发生交代作用的产物,形成于与班公湖—怒江洋壳俯冲消减有关的活动大陆边缘（安第斯型）的构造环境。由此认为,晚侏罗世接奴群火山岩是班公湖—怒江洋壳俯冲消减的产物,从而为班公湖—怒江洋壳的俯冲消减提供了直接的火山岩证据。     

地球初期壳幔演化的物理过程

原始地幔处于全球性的高温熔融状态,其上层的冷却演化过程可大致分为3个阶段：高熔点矿物结晶沉降阶段、岩浆不混溶阶段和固化成壳阶段。在此过程中,原始地幔逸出挥发性物质,形成了地球的超临界流体圈。通过岩浆不混溶作用所形成的富Si—Al质岩浆最终固化为原始大陆壳。超临界流体圈的分解,分别形成酸性H2O圈和CO2大气圈。     

Relative contributions of crust and mantle to the origin of the Bijli Rhyolite in a palaeoproterozoic bimodal volcanic sequence (<Emphasis Type="Italic">Dongargarh Group</Emphasis>), central India

New mineralogical, bulk chemical and oxygen isotope data on the Palaeoproterozoic Bijli Rhyolite, the basal unit of a bimodal volcanic sequence (Dongargarh Group) in central India, and one of the most voluminous silicic volcanic expressions in the Indian Shield, are presented. The Bijli Rhyolite can be recognized as a poorly sorted pyroclastic deposit, and comprises of phenocrystic K-feldspar + albite ± anorthoclase set in fine-grained micro-fragmental matrix of quartz-feldspar-sericite-chlorite-iron-oxide ± calcite. The rocks are largely metaluminous with high SiO₂, Na₂O + K₂O, Fe/Mg, Ga/Al, Zr, Ta, Sn, Y, REE and low CaO, Ba, Sr contents; the composition points to an ‘A-type granite’ melt. The rocks show negative Cs-, Sr-, Eu- and Ti- anomalies with incompatible element concentrations 2–3 times more than the upper continental crust (UCC). LREE is high (La/Yb ∼ 20) and HREE 20–30 times chondritic. δ¹⁸O_whole-rock varies between 4.4 and 7.8‰ (mean 5.87±1.26‰). The Bijli melt is neither formed by fractionation of a basaltic magma, nor does it represent a fractionated crustal melt. It is shown that the mantle-derived high temperature basaltic komatiitic melts/high Mg basalts triggered crustal melting, and interacted predominantly with deep crust compositionally similar to the Average Archaean Granulite (AAG), and a shallower crustal component with low CaO and Al₂O₃ to give rise to the hybrid Bijli melts. Geochemical mass balance suggests that ∼ 30% partial melting of AAG under anhydrous condition, instead of the upper continental crust (UCC) including the Amgaon granitoid gneiss reported from the area, better matches the trace element concentrations in the rocks. The similar Ta/Th of the rhyolites (0.060) and average granulite (0.065) vs. UCC (0.13) also support a deep crustal protolith. Variable contributions of crust and mantle, and action of hydrothermal fluid are attributed for the spread in δ¹⁸O^whole-rock values. The fast eruption of high temperature (∼ 900°C) rhyolitic melts suggests a rapid drop in pressure of melting related to decompression in an extensional setting.     

Experimental investigation of the effect of metasomatism by carbonatic melt on the composition and structure of the deep mantle

The compositions of various transition-zone and lower-mantle phases and coexisting carbonatic melts were determined by exploratory melting experiments in chemically complex CO₂-bearing systems at 20–24.5 GPa and 1600–2000 °C. The melts are highly ultramafic, enriched in K, Na, Ca, Fe, and Mg, and depleted in Al and Si. Melting experiments were also carried out with the compositions on the join Mg₂SiO₄–Na₂CO₃ at 3.7 GPa and 1200–1600 °C. The solidus assemblage of MgCO₃ and Na₂MgSiO₄ melts incongruently to produce forsterite and Na-rich melt. The new results and other recent studies in CO₂-bearing systems suggest that carbonatic melt could be present, either transiently or permanently, in the whole Earth's upper mantle and at least the uppermost lower mantle. Carbonate-melt metasomatism is recognized as a process that could have a major effect on the composition and structure of the deep mantle, and thus play an important role in its evolution. Due to the unique properties of the carbonatic melt, its circulation in an otherwise static mantle could be a more efficient process than the solid-state convection for maintaining equilibrium in most of the mantle not involved directly in plate tectonics.     

富锂氟含稀有矿化花岗质岩石的对比和成因思考

Li-F花岗质岩石以超酸性、过铝、富含H2O、F、B、P等挥发性组分和富含Li、Rb、Cs、Be、Ta、Nb、Sn、W等亲石稀有金属元素为主要特征，以黄玉－锂云母－钠长石花岗岩为典型代表。从该类岩石地质产状的多样性和可对比性、空间分布的规律性、矿物岩石的结构构造、硅酸盐－熔体包裹体特征以及实验岩石学的研究成果等方面，综合论证该类岩石主要是从经过分异演化而形成的残余熔浆中直接结晶而在的；充分的分离结晶作用，是产生这种残余熔浆的主要机制；岩体的空间分带特征和各带之间的渐变过渡关系，为分离结晶作用的途径和演化方向提供了重要信息；熔体中挥发性组分的大量存在，是分离结晶作用能充分进行的关键因素；亲石稀有金属元素在流／熔配分中倾向于进入熔体相，是残余熔体中逐步富集这些稀有金属元素的主要原因；岩浆－热液过渡阶段出溶的流体相与已晶出的共存固相之间的相互作用，造成了广泛的交代蚀变现象；残余熔浆在不同地质和物理化学环境中的侵位、结晶和演化，造成了Li-F花岗质岩石在产状、结构构造和矿物组合等方面的多样性。     

Compositional effect on the pressure derivatives of bulk modulus of silicate melts

Although the bulk moduli (K_T0) of silicate melts have a relatively narrow range of values, the pressure derivatives of the isothermal bulk modulus (K_T0^′) can assume a broad range of values and have an important influence on the compositional dependence of the melt compressibility at high pressure. Based on the melt density data from sink/float experiments at high pressures in the literature, we calculate K_T0^′ using an isothermal equation of state (EOS) (e.g., Birch–Murnaghan EOS and Vinet EOS) with the previously determined values of room-pressure density (ρ₀) and room-pressure bulk modulus (K_T0). The results show that best estimates of K_T0^′ vary considerably from ~ 3 to ~ 7 for different compositions. K_T0^′ is nearly independent of Mg # (molar Mg/(Mg + Fe)), but decreases with SiO₂ content. Hydrous melts have anomalously small K_T0^′ leading to a high degree of compression at high pressures. For anhydrous melts, K_T0^′ is ~ 7 for peridotitic melts, ~ 6 for picritic melts, ~ 5 for komatiitic melts, and ~ 4 for basaltic melts.     

A crustal source for ca. 165 Ma post-collisional granites related to mineralization in the Jianglang dome of the Songpan-Ganzi Orogen,eastern Tiebtan Plateau

The Wenjiaping and Wulaxi granite plutons are located in the Jianglang dome, which is a key domain for providing deep insight into the tectonic evolution of the Songpan-Ganzi Orogen. Two granites are composed chiefly of K-feldspar, quartz, biotite with minor plagioclase and hornblende. This study presents zircon U-Pb chronology, geochemistry and Hf isotope data to explore their petrogenesis and metallogenic implications. Zircon U-Pb dating provides crystallization ages of 164.5 ± 0.9 Ma and 163.4 ± 0.9 Ma for the Wenjiaping granite, and 164.3 ± 1.7 Ma for the Wulaxi granite. This indicates that they were formed synchronously. They also contain inherited zircons related to the Rodinia and Gondwana supercontinents and the Emeishan large igneous province. Their mineral assemblages lack peraluminous (e.g., garnet and cordierite) and high-temperature (e.g., pyroxene and fayalite) minerals. They are characterized by low A/CNK (1.10–0.99), FeO^T/MgO (8.55–2.83) and K₂O/N₂O ratios (1.34–0.51) with low Zr + Nb + Ce + Y concentrations (average 258 ppm) and zircon saturation temperatures (781–651 °C). Their Al₂O₃, P₂O₅ and SiO₂ contents show negative correlations, and they thus fit the I-type granite definition. Some major and trace elements exhibit strong correlations, implying extensive fractional crystallization (e.g., hornblende and ilmenite) during the magma evolution. Two granites show enrichment in light rare earth elements and large ion lithophile elements, and depletion in high field strength elements. They have low Mg^# values (38.7–17.3) and Y/Nb ratios (0.45–0.16), and yield dominantly negative ε_Hf(t) values (1.4–−13.9), indicating a heterogeneous source and their derivation from remelting of ancient continental crust (e.g., Mesoproterozoic Liwu Group in this region) with minor juvenile crust. Combined with prior studies, we conclude that the Wenjiaping and Wulaxi granites were formed in a post-collisional extensional regime, and were responsible for the 163.7–151.1 Ma magmatic hydrothermal Cu-W mineralization in the Jianglang dome. In addition, two granite plutons intrude this dome and they are undeformed, implying that the doming was during the Early to Middle Jurassic.