高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.     

大麻坪橄榄石冲击波实验研究与高压态物态方程参数的确定

利用冲击波进行的动高压实验对研究超高压下的物质性质也是十分有效的.本文报告了对大麻坪采集的橄榄石进行压力在10~45GPa范围的冲击波动高压实验结果.结合前人等温冷压实验结果,确定了实验过程的温度,对于冲击波实验压力从10GPa变化到30GPa时,温度在摄氏几十度到摄氏800多度之间.测量了岩石超高压下密度变化,在3.627~4.009g·cm~(-3)之间.通过回收实验和确定的温度,表明小于30GPa压力实验条件下,没有发生相变过程.同时也确定了状态方程的参数.最后,指出了实验结果在上地幔地球内部物质运动过程的含义,即冷板块中的亚临界橄榄岩可以存在地幔转换带中.     

歧口凹陷新生界火成岩油藏特征及分布规律

歧口凹陷新生界发育了两类与火成岩相关的油藏：基性火山岩油藏和浅成侵入相辉绿岩蚀变带油藏,两者都为构造-岩性油藏。这两类油藏区域上受岩浆活动带控制,主要集中于NE向和EW向断裂转换带,并受烃源岩分布范围的影响而紧邻烃源岩分布;垂向上受区域盖层控制,集中于沙一中亚段和东三段。在转换带沙一中亚段和东三段内,火成岩能否富集成藏主要取决于储集系统的类型。开放式储集系统一方面利于流体替换使火成岩储集空间中的矿化水被及时排出减少次生矿物的形成,从而保护储集空间;另一方面利于富含有机酸流体进入火成岩储集体,通过溶蚀先期形成的杏仁体、裂缝充填物及火成岩中不稳定的矿物组分,使其储集空间扩大、容积增加,使火成岩的储集性能得以改善;另外,火成岩中的断裂通过与烃源岩的沟通为烃类注入富集成藏提供了必要的输导通道,致使这类储集系统能够富集烃类成藏。封闭式储集系统缺少这些条件,岩浆期后热液流体与成岩流体被包裹在火成岩储集空间内不能被排出,易形成次生矿物充填并堵塞这些空间,丧失其储集性能。部分未被充填的空间往往相互之间难以连通,并与生排烃地层隔绝而成为烃类难以注入的死孔隙,从而使这类储集系统难以聚集成藏。     

A new look at the phenomenon of offshore pile plugging

Abstract

Open‐pipe piles are widely used for offshore structures. During the initial stage of installation, soil enters the pile at a rate equal to the pile penetration. As penetration continues, the inner soil cylinder may develop sufficient frictional resistance to prevent further soil intrusion, causing the pile to become plugged. The open‐ended pile then assumes the penetration characteristics of a closed‐ended pile. The mode of pile penetration significantly alters the soil‐pile interaction during and after installation. This affects the ultimate static bearing capacity (mainly in granular materials), the time‐dependent pile capacity (in clays), and the dynamic behavior and analysis of the piles.

Following a summary demonstrating the effects of pile plugging, a review of the common view of offshore pile plugging is undertaken. The interpretation of plugging by referring to the average plug length has led to the erroneous conclusion that in most piles significant plugging action does not occur.

Establishment of an analogy between soil samplers and open‐ended piles enabled correct identification of plugging by referring to the incremental changes in plug length. Examination of case histories of plugging of offshore piles revealed that beyond a certain penetration depth‐to‐diameter ratio, most piles are plugged.     

复合土钉墙在市区深基坑支护工程中的应用

以济南市区深基坑支护工程实例为背景,分析了在周边环境复杂,使用土地范围受限情况下的市区开展深基坑支护工程,采用复合土钉墙支护技术,利用其形式多样、组合灵活的特点,充分发挥组合中各部件的优点,取长聚优,在保证安全的前提下以期达到技术经济的最佳;同时总结了施工中各个工序的施工要点和关键技术措施。监测数据显示基坑位移变形小,未对周边环境造成不良影响,说明支护体系发挥了良好的实施效果。     

井筒式地下连续墙水平承载能力模型试验研究

井筒式地下连续墙利用构造接头把地下连续墙段连接成一个平面为封闭形状挡土结构,其刚度大,承载力高。由于基础内部含有大面积的土芯,存在墙内土芯、墙体以及外部土体的相互作用。采用水平单向单循环维持荷载法,通过3个不同截面尺寸的单孔闭合墙水平静载试验,研究闭合地下连续墙基础的水平承载特性。基于墙身内力及位移测试结果,研究了井筒式地下连续墙基础在水平荷载作用下的承载机理,分析了水平荷载-位移特性、墙身位移、墙身弯矩、剪力、转角随深度的分布规律。试验结果表明,闭合墙基础呈整体倾斜破坏特性,墙身弯矩随墙深呈非线性变化,墙身剪力在加载处最大,在墙身弯矩极大值处墙身剪力为0,0点以下,墙身剪力随深度呈“大肚形”变化,并且闭合墙的承载力随着闭合墙边长的增大,深度的提高而提高。     

Effect of Initial Azo Dye Concentration and Biomass Acclimation on Sludge Digestion and Dye Co‐treatment

The effect of a reactive azo dye (the hydrolyzed form of Reactive Orange 107, HRO107) on the digestion of municipal waste sludge (WS) was studied. The study also focused on the effect of acclimation of the anaerobic mixed culture on dye treatment. Anaerobic batch assays were carried out in serum bottles under mesophilic conditions. Unacclimated and acclimated anaerobic mixed cultures were used for the study. Both unacclimated and acclimated anaerobic cultures completely reduced HRO107 during WS digestion. Inhibitory HRO107 concentration was found to be 800 mg/L for unacclimated mixed culture. Acclimation increased the inhibitory concentration level from 800 to 3200 mg/L. Sulfanilic acid and four other unidentified dye reduction end products were detected at the end of the assays. The results of this study indicated that anaerobic municipal WS digesters have the potential to be a cost efficient and effective pre treatment method.     

Incorporation of Heavy Metals Bioavailability into Risk Characterization

The bioavailability of field‐aged Cd and Cu was calculated, and compared to the total concentrations determined by acid digestion. Only 0.60–4.15% for Cd and 0.59–9.43% for Cu were found to be bioavailable when determined by stomach‐phase extraction. The incorporation of bioavailability reduced more than 90% of the calculated risk of the metals at the site of study. It should be noted that such a reduction may not be generalized and the site‐specific bioavailability needs to be determined case by case.     

川西新场地区须五段泥页岩超压成因及其对含气性的影响

页岩气储集层中往往发育异常高的地层压力,其压力的大小不仅直接影响了泥页岩中有机质的热演化生烃作用,而且还决定着页岩气的保存和富集程度。为了研究川西新场地区须五段泥页岩的异常高压成因及其对含气性的影响,选取该地区3口井的页岩岩心样品进行现场解吸、X衍射矿物分析和等温吸附等一系列分析测试来辅助说明超压产生的原因。然后结合前人研究成果和测试数据,对泥页岩的异常高压成因进行了定性分析,初步探讨了泥页岩异常高压发育与含气量之间的关系。分析表明：造成川西新场地区须五段泥页岩异常高压现象的原因主要有欠压实作用、生烃作用、粘土矿物脱水作用和构造挤压作用。页岩含气量与异常高压的发育程度呈正相关关系,页岩异常高压越发育,其含气量越大,产气量也越高。同时压力系数可以作为保存条件的综合判别指标,川西新场地区须五段泥页岩压力系数较高,保存条件较好。     

双轴应力下非贯通节理岩体压缩损伤本构模型

针对目前节理岩体损伤变量定义中大多仅考虑节理长度、倾角等几何性质,而未考虑节理抗剪强度等力学性质的不足,基于断裂力学中的由于单个节理存在引起的附加应变能增量与损伤力学中的损伤应变能释放量相关联的观点,推导出了在双轴应力下含单条非贯通闭合节理岩体的损伤变量计算公式,并根据断裂力学理论对双轴压缩荷载下的单个节理尖端应力强度因子计算方法进行了研究,得出了应力强度因子KⅠ、KⅡ的计算公式;同时考虑多节理间的相互作用,给出了单组单排及单组多排非贯通节理尖端应力强度因子计算公式,由此建立了相应的节理岩体双轴压缩损伤本构模型,并利用该模型进行了相应的算例分析。结果表明：对含单条非贯通闭合节理的岩体而言,当节理倾角小于其内摩擦角时,岩体强度与完整岩石相同,岩体损伤为0,而后随着节理倾角增加,岩体强度、损伤随节理倾角的变化分别呈开口向上及向下的抛物线,当节理倾角约为60°时,岩体损伤最大,强度最低。随着节理长度增加,岩体损伤增加,而随着节理内摩擦角的增加,岩体损伤则减小;对含单组单排非贯通闭合节理的岩体而言,当节理总长度一定时,随着单条节理长度的减小及节理条数的增加,岩体损伤则逐渐减小,但其减小幅度与节理条数并不呈线性关系。