Deciphering the geochronology of a large granitoid pluton (Karkonosze Granite,SW Poland): an assessment of U–Pb zircon SIMS and Rb–Sr whole-rock dates relative to U–Pb zircon CA-ID-TIMS

Granitoid plutons are often difficult to radiometrically date precisely due to the possible effects of protracted and complex magmatic evolution, crustal inheritance, and/or partial re-setting of radiogenic clocks. However, apart from natural/geological issues, methodological and analytical problems may also contribute to blurring geochronological data. This may be exemplified by the Variscan Karkonosze Pluton (SW Poland). High-precision chemical abrasion (CA) ID-TIMS zircon data indicate that the two main rock types, porphyritic and equigranular, of this igneous body were both emplaced at ca. 312 Ma, while field evidence points to a younger age for the latter. This is in contrast to the earlier reported SIMS (SHRIMP) zircon dates that scattered mainly between ca. 322 and 302 Ma. In an attempt to overcome this dispersion, at least in part caused by radiogenic lead loss, the CA technique was used before SHRIMP analysis. The ²⁰⁶Pb/²³⁸U age obtained in this way from a sample of porphyritic granite is 322 ± 3 Ma, ~16 Ma older than the untreated zircons; another porphyritic sample yielded a mean age of 319 ± 3 Ma, and the mean age was 318 ± 4 Ma for an equigranular granite sample – all three somewhat older than the age obtained by ID-TIMS. Older SIMS dates of ca. 318–322 Ma might indicate either faint inheritance or that zircon domains crystallized during earlier stages of Karkonosze igneous evolution. The ID-TIMS results have been used to re-assess the whole-rock Rb–Sr data. Excluding a porphyritic granite with excess radiogenic ⁸⁷Sr, it appears that isotopic homogeneity was achieved for most samples during the 312 Ma event, as shown by a pooled 21-point isochron with an age of 311 ± 3 Ma and an initial ⁸⁶Sr/⁸⁶Sr of 0.7067 ± 4. Local crustal contamination by stopping of metapelitic material might account for the more radiogenic Sr isotope signature observed in biotite-rich schlieren. A critical re-evaluation of all available SHRIMP data using the ID-TIMS age of 312 Ma as a benchmark suggests that the observed scatter may be partly attributed to analytical and methodological problems, in particular failing to distinguish subtly discordant spots from truly concordant ones, which is a serious limitation of the microbeam analytical approach. Other likely pitfalls contributing to geochronological scatter are identified in the published Re–Os ages on molybdenite and the ⁴⁰Ar/³⁹Ar data on micas. A scenario postulating a 15–20 milliion year evolution of the Karkonosze Pluton cannot be established on the basis of available geochronological data, which rather supports a brief igneous event, although a more protracted pre-emplacement evolution is possible. A short timescale for crystallization of large igneous bodies, as suggested by the ID-TIMS data from the Karkonosze Granite, is in line with models of transport of granitic magmas through dikes to form large plutons.     

高临界循环荷载水平下钻孔桩的抗拔性状分析

为了研究抗拔桩在循环加载过程中桩身的性状,选取杭州萧山某工地两根抗拔桩作为试桩进行循环加载试验。在抗拔桩桩身埋设钢筋应力计,测量循环加载过程中桩身应力的变化情况;在桩身预埋钢管,测量桩顶及桩端上拔量。通过对桩身应力及桩顶、桩端上拔量的分析,研究循环加载对抗拔桩承载力及上拔量的影响。综合分析抗拔桩承受循环荷载时的桩顶、桩端上拔量、桩身轴力以及桩侧摩阻力分布可知,当抗拔桩承受循环荷载时,且临界循环荷载水平较大（接近或者达到1）,抗拔桩经过2～3次循环加载后就发生破坏,其研究结果可供其他类似工程参考。     

Chemical indexes of Paleoproterozoic sedimentary rocks from Liaohe Group,North China Craton:Implications for paleoclimate and provenance

Paleoproterozoic supracrustal materials have been widely identified in North China Craton, such as the Liaohe-, Hutuo-and Lyuliang groups. The Liaohe Group in the eastern part of the North China Craton is dominated by deformed and metamorphosed sedimentary and volcanic successions. Compared with that of the coeval volcanic rocks, geochemistry of the sedimentary rocks from the Liaohe Group has rarely been studied in detail, which can possibly provide information on the paleoclimate and provenance. The authors analyzed the whole-rock and detrital zircon geochemistry of sedimentary rocks from the Liaohe Group against a uniform process and proposed their different ways of paleoweathering of the lower and upper formations. That is to say, although the lower and upper formations within the Liaohe Group might be derived from the similar source composition in a tectonically active setting, the paleoclimate that they experienced was not exactly the same. The predominant derivations are the Paleoproterozoic granitoids and basalts within the Liaohe Group, with minor input of Archean continental crust. This study highlights the contributions of the Paleoproterozoic mafic sources, which has been generally overlooked in the previous researches.     

化工园区重大事故风险分析

目前我国对化工园区风险分析的理论研究尚处于起步阶段。针对化工园区这一特殊区域,从整体角度出发,分析研究了化工园区内多个重大事故风险源造成的区域风险,并进行了实例应用。综合考虑多个重大事故风险源产生的风险,分析了其产生风险的叠加效应,绘制出化工园区的个人风险等值线;同时根据ALARP（合理可接受风险水平）准则对化工园区的风险水平进行评估,并据此给出化工园区安全规划、风险控制和应急救援工作的实施建议。所提出的化工园区重大事故风险分析方法,在建立和完善化工园区风险分析中具有一定的理论和现实意义。     

Experimental investigation on seismic behavior of single piles in sandy soil

This paper describes a quasi-static test program featuring lateral cyclic loading on single piles in sandy soil. The tests were conducted on 18 aluminum model piles with different cross sections and lateral load eccentricity ratios, e/d, (e is the lateral load eccentricity and d is the diameter of pile) of 0, 4 and 8, embedded in sand with a relative density of 30% and 70%. The experimental results include lateral load-displacement hysteresis loops, skeleton curves and energy dissipation curves. Lateral capacity, ductility and energy dissipation capacity of single piles under seismic load were evaluated in detail. The lateral capacities and the energy dissipation capacity of piles in dense sand were much higher than in loose sand. When embedded in loose sand, the maximum lateral load and the maximum lateral displacement of piles increased as e/d increased. On the contrary, when embedded in dense sand, the maximum lateral load of piles decreased as e/d increased. Piles with a higher load eccentricity ratio experienced higher energy dissipation capacity than piles with e/d of 0 in both dense and loose sand. At a given level of displacement, piles with circular cross sections provided the best energy dissipation capacity in both loose and dense sand.     

复方化学消毒剂中苯扎氯铵的高效液相色谱测定

建立了一种测定复方化学消毒剂中苯扎氯铵成分十二烷基二甲基苄基氯化铵、十四烷基二甲基苄基氯化铵和十六烷基二甲基苄基氯化铵的反相离子对高效液相色谱法。色谱柱为Platisil ODS(5μm,250 mm×4.6mm),流动相为甲醇-0.2 mol/L己烷磺酸钠(含1%三乙胺,V/V,用高氯酸调节至pH=6.0,体积比85∶15),紫外220 nm检测。用己烷磺酸钠作为离子对试剂,增强了苯扎氯铵成分的保留,三乙胺作为扫尾剂,通过抑制固定相表面残存的硅羟基对苯扎氯铵成分的吸附,减少了色谱峰拖尾。3种苯扎氯铵成分分离良好,标准曲线的线性范围分别为0.002～5 mg/mL、0.005～10 mg/mL和0.005～10 mg/mL,检测限分别为0.0005 mg/mL、0.001mg/mL和0.001 mg/mL。方法具有良好的准确度和精密度,在测定低浓度样品时优势明显。实际用于测定苯扎氯铵消毒液和医用消毒纸巾中3种苯扎氯铵成分的含量,回收率为99.3%～104.1%,日内和日间测定相对标准偏差(RSD)均小于2.0%。     

Numerical simulations and parametric study of SDCM and DCM piles under full scale axial and lateral loads

The new kind of reinforced Deep Cement Mixing (DCM) pile namely, Stiffened Deep Cement Mixing (SDCM) pile is introduced to mitigate the problems due to the low flexural resistance, quality control problem and unexpected failure of DCM pile. The SDCM pile consists of DCM pile reinforced with concrete core pile. Previously, the full scale pile load test and the full scale embankment loading test were successfully conducted in the field. To continue the study on the behavior of SDCM and DCM piles, the 3D finite element simulations using PLAXIS 3D Foundation Software were conducted in this study. The simulations of full scale pile load test consisted of two categories of testing which are the axial compression and the lateral loading. For DCM C-1 and C-2 piles, the clay–cement cohesion, C_DCM, and clay–cement modulus, E_DCM, were obtained from simulations as 300 kPa and 200 kPa as well as 60,000 kPa and 40,000 kPa, respectively. For the SDCM piles, the simulation results show that increasing length ratio, L_core/L_DCM, increased the bearing capacity whereas the sectional area ratio, A_core/A_DCM, has only small effects on the bearing capacity for the axial compression loading. The verified parameters such as the clay–cement cohesion, C_DCM, and clay–cement modulus, E_DCM, from simulations of axial compression tests were 200 kPa and 30,000 kPa, respectively. On the other hand, increasing the sectional area ratio, A_core/A_DCM, significantly influenced the ultimate lateral resistance while the length ratio, L_core/L_DCM, is not significant in the ultimate lateral load capacity when the length of concrete core pile is longer than 3.5 m. In addition, the tensile strength of DCM, T_DCM, and concrete core pile, T_core, are very important to the lateral pile resistance. The back-calculation results from simulations of tensile strength were 5000 kPa and 50 kPa for the T_core and T_DCM, respectively.     

高浓度化学浆液的研制与应用效果

淮北某煤矿因第四含水层水量过大,通过F5断层导入采煤工作面,使采煤生产陷入停顿。为解决采煤工作面涌水量过大问题,研制了高浓度化学浆液,经钻孔注浆收到良好的止水效果,使近200万t煤炭资源恢复开采,取得了很好的经济和社会效益。     

苏通大桥超长桩桩底后压浆试验及效果

在苏通大桥松散软弱的地层条件,实施超长（〉100 m）、超大（2.5 m）摩擦桩桩底后压浆工程,在我国是首次运用。结合工程实践,就压浆工程的设计、施工的技术要点进行全面介绍。通过对钻孔取样分析,指出浆液初凝时间地表实验与地下实际存在较大差异;通过施工体验,结合取样显示的浆液扩散渗透状况,提出可渗透地层以注浆量为控制参数,压力不列为控制参数的思路。     

圆形煤场中桩-网复合地基原体试验研究

在大型圆形煤场中采用桩-网复合地基是火电厂地基方案设计的新思路,该方案不仅要考虑地基土层的强度满足上部荷载的要求,还需要考虑堆载区内土体的变形对环基的影响。通过对圆形煤场中桩-网复合地基原体试验研究,介绍了在大面积堆载下如何进行桩、土及垫层中应力与应变的测试,设计了2套堆载与测试方案,在试验1区铺设了2层土工格栅,而在试验2区未铺设土工格栅。根据在2个试验区所获得的测试成果,研究了大面积堆载对堆载区内外土体变形的影响深度与范围,对比分析了不同高程处垫层与土体的竖向及侧向应力随深度的变化规律,结合堆载区中桩与边桩的桩身轴力变化,计算出上部桩侧土体对桩所产生的负摩阻力,并依据承台顶面附近测得的垫层与土层的应力,计算出桩土分担荷载的比例,以及桩土应力比的大小与变化规律。在此基础上得到土工格栅对大面积堆载区内外土体应变与应力的影响程度,从而可以为大型圆形煤场桩-网复合地基方案的设计与施工提供客观的技术参数与建议。