Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.     

Evidence from the Northeastern Atlantic basin for variability in the rate of the meridional overturning circulation through the last deglaciation

A first study from the subtropical western Atlantic, using ²³¹Pa/²³⁰Th ratios as a kinematic proxy for deep water circulation, provided compelling evidence for a strong link between climate and the rate of Meridional Overturning Circulation (MOC) over the last deglaciation. However, these results warrant confirmation from additional locations and water depths because the interpretation of the sedimentary ²³¹Pa/²³⁰Th ratio in terms of circulation vigor can be biased by variations in particle flux and composition. We have measured ²³¹Pa/²³⁰Th in a core from the Iberian margin, in the Northeastern Atlantic basin, and have compared these new results to the data from the western Atlantic basin. We find that the reduction in the circulation during H1 and YD and the subsequent increases first recognized in the sediment deposited on Bermuda Rise are also evident in the eastern basin, in a totally different sedimentary regime, confirming that sedimentary ²³¹Pa/²³⁰Th ratios record basin-wide changes in deep water circulation. However, some differences between the eastern and western records are also recognized, providing preliminary evidence to differentiate between renewal rates in the two North Atlantic basins and between shallower and deeper overturning. Our results suggest the possible existence of two sources of Glacial North Atlantic Intermediate Deep Water (GNAIW), one in the south Labrador Sea and another west of Rockall Plateau. Both sources contributed to the meridional overturning but the two had different sensitivity to meltwater from the Laurentide and the Fennoscandian ice sheets during the deglaciation. These results indicate that additional information on the geometry and strength of the ventilation of the deep Atlantic can be obtained by contrasting the evolution of sediment ²³¹Pa/²³⁰Th in different sections of the Atlantic Ocean.     

Tidal Stress/Strain and the b-values of Acoustic Emissions at the Underground Research Laboratory, Canada

The correlation between the b-values of acoustic emissions (AEs) and the phase of the moon was investigated at the Underground Research Laboratory (URL) in Canada. The same data as those used in Iwata (2002) were examined, which showed that the occurrence of AEs is correlated with the phase of the moon. It was expected, therefore, that the b-value of the AEs would also be sensitive to tidal stress/strain fluctuations. We investigated the variation of the b-values as a function of the phase of the moon. Results show that b-values immediately following the times of full/new moon are higher than those at other times. Using AIC (Akaike Information Criterion) and random (Monte Carlo) simulations, it was confirmed that this feature is statistically significant. We also investigated whether or not there was a change in the b-values immediately before the times of full/new moon, but no statistically significant change was observed. The results suggest that the effect of stress/strain fluctuations on AE occurrences at the URL is asymmetric to the times of full/new moon.All authors are members of the Academic Robotics Group. In listing The Academic Robotics Group, the authors are endeavoring to place each of the participant institutions on an equal footing in terms of effort and authorship. M. A. Talamini is serving as presenter.     

Knowledge Representation Methods in Expert System for Earthquake Prediction ESEP 3.0

INTRODUCTIONKnowledgerepresentationandknowledgeacquisitionarekeyissuesinbuildinganexpertsystem .Theyarecloselyrelatedtothedomainproblem solvinglevelandcompetenceoftheexpertsystem .Intheknowledgeacquisitionprocess,thedomainexpertwillfirstofferandorganizepr…     

石墨炉原子吸收光谱法测定土壤样品中镉

采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉，方法检出限DL=0．012μg／g，精密度RSD在3．55％～7．33％，满足了土壤样品中镉测定的镉质量要求。     

石灰改良膨胀土力学性质的研究

膨胀(?)主要是由强亲水性粘土矿物蒙脱石和伊利石组成的,是具有膨胀性、多裂隙性和超固结性的高塑性粘性土。在铁路施工中,膨胀土不能直接作为路基填土,必需进行改良。通过室内试验的方法来讨论石灰改良膨胀土的力学性质在各种影响因素下的变化规律。     

在卸荷产生拉剪情况下裂隙岩体的力学行为

据岩体在卸荷情况下的拉剪应力状态,确定了节理岩体的线弹性断裂力学模型。依照此模型,可以得到相对远离裂隙(该位置的点到裂隙中心的距离比裂缝长度大)且受裂隙影响区域内应力、应变和变形方程。这些对评估裂隙岩石变形有重要的参考意义。通过用理论方程的计算结果和卸荷情况下试验观测所得的数据对比,证明该模型应用于实际工程中具有可行性。     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.