黄磷电炉烟尘中各种磷化合物的化学物相分析

对黄磷电炉烟尘中各种形态的磷化合物进行了化学物相分析，得出元素磷、水溶性低价磷化合物、水溶性高价磷化合物、酸溶性高价磷化合物、酸溶性低价磷化合物、酸不溶性磷化合物在黄磷电炉烟尘中的含量，并对黄磷电炉烟尘的综合利用提出了建议。     

Improvement of calcareous expansive soils in semi-arid environments

The semi-arid climate and geology of Cyprus have caused the formation of calcareous expansive soils on the island. In some areas, swelling has caused serious foundation problems. The industrial by-product Soma fly ash has been used to improve the engineering properties of the soil. Fly ash treatment has shown tremendous potential as an economical method for the stabilization of the soil. Significant reduction in the swell potential and an increase in the hydraulic conductivity values are obtained. Use of fly ash with a small percentage of lime produces even more dramatic results. Cation exchange capacity (CEC) values substantiate the formation of the new pozzolanic reaction minerals which result in more stable silt-sand like structures.     

Element budgets of pine stands on lignite and pyrite containing mine soils

To analyze the development of pine ecosystems on lignite and pyrite containing mine soils, four pine stands with ages of 3–35 years were investigated in a chronosequence approach. Bulk precipitation, throughfall and soil solution in depths of 20, 40, 70 and 100 cm were studied over a three-year period to determine element fluxes in these forest ecosystems on extreme acidic and saline soils.Element budgets are controlled by the processes induced by pyrite oxidation such as intensive weathering of primary minerals, precipitation and leaching of secondary phases.Despite low water fluxes, element outputs can reach extraordinary high values due to very high concentrations in the soil solution. Although element outputs decrease drastically with stand age, respectively, site age, they exceed those of comparable pine stands on non-mine sites. Nitrogen release from the lignite fraction represents a special characteristic of the examined substrates. Nitrogen losses beneath the rooted zone can be 34 kg N ha⁻¹ yr⁻¹ in 100 cm depth. Element input and output in the examined ecosystems are far from balance. Closed cycling of nutrients seems to be recognizable in the case of potassium.     

依据密度测井资料评估煤层的含气量

煤层甲烷长期以来认为是对采煤工作的危害，只是近十多年来才被认为是一种潜在的能源。煤层不仅是甲烷的储层，而且是甲烷的源岩。煤的物理结构是一种双重孔隙结构，即煤层中含有由基质孔隙和裂缝孔隙组成的孔隙系统。煤层中的气（甲烷）主要吸附在基质孔隙的内表面，是吸附气，而不是存在于骨架粒间的孔隙空间内，因而传统的评价天然气储层含气量的方法虽然不能适合于评估煤层的气含量。本文利用密度测井资料和煤样煤质化验资料确定     

白龙江沿岸垂直气候与花椒立体栽植

通过对白龙江沿岸垂直气候分析和花椒生长的实地调查以及栽植试验，将该地花椒的立体种植划分出四个层次。每个层次有其适宜的品种，以期每个层次栽植的花椒尽可能充分利用该层次的气候资源，获得较好的收益。     

Nutrients adsorption from seawater by new porous carrier made from zeolitized fly ash and slag

This study investigated the adsorption and precipitation of phosphate by blast furnace slag (BFS) separately.

In order to evaluate the adsorption capacity of BFS, BFS was treated before its use by acid. The authors aim to develop a new porous carrier to adsorb simultaneously ammonium and phosphate from seawater under eutrophic conditions. The current paper deals with a promising new approach to improve the utilization of some industrial solid wastes such as BFS and zeolite synthesized from fly ash [ZFA(Fe)] by their solidification to cylindrical porous carriers using a hydrothermal hot-pressing (HHP) method.

Attempts to produce porous carriers using an arranged HHP method with different porosities (24%, 40% and 52% (v/v)) were carried out. Physical properties of carriers such as porosity, compressive strength and height have been investigated. Laboratory studies showed strong evidence that the porous carrier was very selective towards phosphate and ammonium. The results demonstrated the role of porosity in enhancing phosphate and ammonium adsorption by the increase of the surface area per weight. The estimates of the parameters and the correlation coefficients according to the Freundlich equations revealed that adsorption was related to the porosity of carriers and phosphate and ammonium were adsorbed well on the carriers having large porosity.

The results suggested that developing carrier with high porosity was a promising way to enhance nutrients adsorption.     

大面积深厚杂填土地基处理技术

通过一项具体的工程实例,论述了深厚杂填土地基的基本工程特性。介绍了一种处理深厚杂填土地基的新技术———重锤冲扩挤密灰渣土桩复合地基技术,并对施工过程的控制,以及施工效果的检测结果进行了分析,得出了对于大面积深厚杂填土地基采用此技术处理后,能够消除地基深部湿陷性,复合地基承载力可以满足200 kPa。     

濮阳近50a风速变化特征及突变分析

利用线性分析方法,分析了濮阳近50 a平均风速、大风日数的变化特征,并利用滑动的t检验法分析了风速突变,结果显示:年平均风速以0.498(m/s)/10 a的倾向率减少,大风和扬沙日数分别以2.7 d/10 a和5.6 d/10 a的倾向率减少;平均风速,大风、扬沙日数在20世纪80年代初期发生突变。     

从高铝粉煤灰中提取非晶态SiO2的实验研究

为了有效提高高铝粉煤灰的Al/Si比,为提取氧化铝奠定基础,研究了用NaOH从高铝粉煤灰中提取非晶态SiO2的最佳工艺条件,并对提硅反应的机理进行了探讨。首先根据高铝粉煤灰的化学与物相组成特点,确立了利用NaOH提取非晶态SiO2的基本技术路线;然后用正交实验法确定了提硅的最佳条件:NaOH的浓度25%,灰碱质量比1∶0.5,反应温度95℃,反应时间4 h。经最佳条件反应之后,SiO2的提取率达到了41.8%,灰中Al2O3的含量由48.5%增加到了57.38%,Al2O3/SiO2质量比由1.29提高到了2.39。     

含粉煤灰与伊利石的高吸水复合材料性能测试

粉煤灰具有一定的吸水能力,且含多种营养元素,对土壤有很好的改良效果;伊利石也具有吸水性,且含钾量高。采用溶液聚合法首次合成的粉煤灰-伊利石/丙烯酸-丙烯酰胺高吸水复合材料,其吸蒸馏水、自来水、生理盐水倍率分别为1 782,450,117,而国家“863计划”关于高吸水材料的技术指标分别为300,150,50;同时对复合材料的保水性、热稳定性、耐寒性及其二次吸液性能进行测试,结果表明:复合材料具有优越的保水性,25℃条件下干燥8 d,吸水凝胶还可以保持50%的吸水量;在0～120℃范围性能稳定;具有较高的二次吸液能力,可以多次使用。