In polluted aquatic systems, toxic metals are often accumulated in bottom sediments. They are, however, not necessarily stored definitively because diagenetic processs can modify redox, pH and even the amount of complexing ligands, releasing the trace metals back into the pore waters and the water column. Especially the labile metal fraction in the pore waters is important since this is the bioavailable fraction determining the bio-toxicity of the sediments. The goal of our study was therefore to assess, with novel sampling techniques, this bioavailable metal fraction in the pore waters as well as the flux towards the overlying water column. High-resolution profiles of trace metals in pore waters of marine and riverine sediments were assessed by DET (diffusive equilibrium in thin films) and DGT (diffusive gradients in thin films) gel techniques. The DET technique uses a diffusive gel layer that equilibrates with the aquatic system and with this technique the concentrations of total dissolved trace metals are obtained directly. The DGT technique uses an acrylamide diffusive gel backed by a resin gel (Chelex) which binds trace metals. With the DGT technique only labile species of selected metals can be captured. According to the redox potential measurements, the marine sediments were suboxic (200 mV to -220 mV versus Ag/AgCl electrode), while the riverine sediments were completely anoxic (-160 mV to -220 mV versus Ag/AgCl electrode). This redox potential was apparently controlling the trace metals species in the pore waters: for example a strong correlation between Mn and Co was found in the riverine sediments (for DET and DGT sampling), while in the marine sediments trace metals presented various behaviors. 相似文献
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream (pH 2.98-3.40), 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization. 相似文献
The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide (VMS) occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain (RM) and Sheep Creek (SC). Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 (as low as 2.4 at RM and 2.5 at SC), high conductivity (up to 11000 μS/cm), and very high (Is to 100s mg/L) dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents (summed REE median 3200 μg/L, n=33). At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain (both around 3 million tonnes) and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC. 相似文献
A study of the dynamic rock fracture initiation and propagation due to explosive energy is presented through a detailed state-of-the-art review. Explosive energy dissipation in crushing and fracturing is examined and the various means to enhance the explosive energy utilization for dynamic rock fracturing are reviewed. The study highlights the need for a better understanding of the dynamic fracturing process particularly in the presence of in situ stresses in the rock mass. 相似文献
Argillaceous rocks cover about one thirds of the earth's surface. The major engineering problems encountered with weak- to medium-strength argillaceous rocks could be slaking, erosion, slope stability, settlement, and reduction in strength. One of the key properties for classifying and determining the behavior of such rocks is the slake durability. The concept of slake durability index (SDI) has been the subject of numerous researches in which a number of factors affecting the numerical value of SDI were investigated. In this regard, this paper approaches the matter by evaluating the effects of overall shape and surface roughness of the testing material on the outcome of slake durability indices.
For the purpose, different types of rocks (marl, clayey limestone, tuff, sandstone, weathered granite) were broken into chunks and were intentionally shaped as angular, subangular, and rounded and tested for slake durability. Before testing the aggregate pieces of each rock type, their surface roughness was determined by using the fractal dimension. Despite the variation of final values of SDI test results (values of Id), the rounded aggregate groups plot relatively in a narrow range, but a greater scatter was obtained for the angular and subangular aggregate groups. The best results can be obtained when using the well rounded samples having the lowest fractal values. An attempt was made to analytically link the surface roughness with the Id parameter and an empirical relationship was proposed. A chart for various fractal values of surface roughness to use as a guide for slake durability tests is also proposed. The method proposed herein becomes efficient when well rounded aggregates are not available. In such condition, the approximate fractal value for the surface roughness profile of the testing aggregates could be obtained from the proposed chart and be plugged into the empirical relation to obtain the corrected Id value. The results presented herein represent the particular rock types used in this study and care should be taken when applying these methods to different type of rocks. 相似文献
In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na+, SiO2 and Cl−, as well as the increase of K+, Ca2+, Mg2+, SO
42−
and HCO
3−
. Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO2. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed. 相似文献
The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt.
It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial
multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed
pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the
test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been
put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation
energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the
rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters
assumed constant in the basic law. 相似文献
Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock
fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then
introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity
index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model
are analysed. The average number of intersections per fracture, Xf, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that
Xf is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity
index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a
practical example is used to demonstrate the method of computing the connectivity index. 相似文献
Based on the high temperature data of June to August in 1961-2000 in North China, the high temperature weather processes are investigated, and a more complete data set for severe high temperature processes is created. The climatic characteristics of adverse high temperature weather in Beijing, Tianjin, Shijiazhuang, Jinan and Taiyuan are analyzed respectively. The major features of the East-Asia Subtropical High and Transformed Continental High are discussed. The outcomes indicate that the influence of both East Asia Subtropical High and Transformed Continental High on these weather events varies, by a larger margin, from one city to another over North China and they are also closely related to the relative humidity. It is found that the behaviours of East-Asia Subtropical High and Transformed Continental High are the major important systems that give rise to the summer high temperature weather over the region. Based on these findings, the 5-day, 10-day and monthly assessment models for such high impact events have been developed. The assessment outcomes prove to be useful in assessing severe high-temperature events in major cities of North China. 相似文献