山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。     

Analysis of uncertainties in the hydrological response of a model‐based climate change impact assessment in a subcatchment of the Spree River,Germany

Climate change impact assessments form the basis for the development of suitable climate change adaptation strategies. For this purpose, ensembles consisting of stepwise coupled models are generally used [emission scenario → global circulation model → downscaling approach (DA) → bias correction → impact model (hydrological model)], in which every item is affected by considerable uncertainty. The aim of the current study is (1) to analyse the uncertainty related to the choice of the DA as well as the hydrological model and its parameterization and (2) to evaluate the vulnerability of the studied catchment, a subcatchment of the highly anthropogenically impacted Spree River catchment, to hydrological change. Four different DAs are used to drive four different model configurations of two conceptually different hydrological models (Water Balance Simulation Model developed at ETH Zürich and HBV‐light). In total, 452 simulations are carried out. The results show that all simulations compute an increase in air temperature and potential evapotranspiration. For precipitation, runoff and actual evapotranspiration, opposing trends are computed depending on the DA used to drive the hydrological models. Overall, the largest source of uncertainty can be attributed to the choice of the DA, especially regarding whether it is statistical or dynamical. The choice of the hydrological model and its parameterization is of less importance when long‐term mean annual changes are compared. The large bandwidth at the end of the modelling chain may exacerbate the formulation of suitable climate change adaption strategies on the regional scale. Copyright © 2013 John Wiley & Sons, Ltd.     

A distributed parameter model of a frame pin‐supported wall structure

Many reinforced‐concrete frames collapse via a soft‐story mechanism during severe earthquakes. Such collapses are mainly attributed to concentrated deformation in a soft story. Deformation control is thus important in preventing collapse. The frame pin‐supported wall structure is a type of rocking structure that releases constraints at the bottom of the wall. Previous research has obtained good results for the deformation control of this type of structure. However, the interior forces and strength demands of the pin‐supported wall have not been systematically explored. In this paper, a distributed parameter model is developed to investigate the strength demand of the wall in a frame pin‐supported wall structure. In the model, the pin‐supported wall is simplified as a bending beam and the frame is simplified as a shear beam. The two beams are joined by distributed shear connectors, so that the shear force can be transferred at any location on the interface. The model can be solved using differential equations based on equilibrium and compatibility. The accuracy of the model is verified using SAP2000 (Computers and Structures Inc., Berkeley, CA, USA). Displacement distribution of the structure and distributions of the moment and shear force within the pin‐supported wall are obtained for two typical external force profiles. It is found that the pin‐supported wall can effectively reduce the drift concentration factor. Distributions of the displacement, moment, and shear force are closely correlated with the relative stiffness of the wall and frame. Finally, recommendations on the stiffness and strength of a pin‐supported wall are made. Copyright © 2015 John Wiley & Sons, Ltd.     

高温高压下石英砂岩的电导率实验研究

利用交流阻抗谱实验技术,在0.5~2.0 GPa、573~873 K和10-1~106 Hz条件下,借助YJ-3000t紧装式六面顶高压设备和Solartron-1260阻抗/增益-相位分析仪测定了石英砂岩的电导率。实验结果表明:在测定的频率范围,样品的复阻抗的实部、虚部、模和相角对频率有很强的依赖性。随着温度升高,电导率增大,lgσT与1/T之间符合Arrhenius线性关系。通过拟合计算,获得了表征样品电学性质的指前因子、活化焓、活化能、活化体积等物性参数。杂质离子导电机制对高温高压下石英砂岩的导电行为提供了合理的解释。     

Towards more systematic perceptual model development: a case study using 3 Luxembourgish catchments

The synthesis of experimental understanding of catchment behaviour and its translation into qualitative perceptual models is an important objective of hydrological sciences. We explore this challenge by examining the cumulative understanding of the hydrology of three experimental catchments and how it evolves through the application of different investigation techniques. The case study considers the Huewelerbach, Weierbach and Wollefsbach headwater catchments of the Attert basin in Luxembourg. Subsurface investigations including bore holes and pits, analysis of soil samples and Electrical Resistivity Tomography measurements are presented and discussed. Streamflow and tracer data are used to gain further insights into the streamflow dynamics of the catchments, using end‐member mixing analysis and hydrograph separation based on dissolved silica and electrical conductivity. We show that the streamflow generating processes in all three catchments are controlled primarily by the subsolum and underlying bedrock. In the Huewelerbach, the permeable sandstone formation supports a stable groundwater component with little seasonality, which reaches the stream through a series of sources at the contact zone with the impermeable marls formation. In the Weierbach, the schist formation is relatively impermeable and supports a ‘fill and spill’‐type of flow mechanism; during wet conditions, it produces a delayed response dominated by pre‐event water. In the Wollefsbach, the impermeable marls formation is responsible for a saturation‐excess runoff generating process, producing a fast and highly seasonal response dominated by event water. The distinct streamflow generating processes of the three catchments are represented qualitatively using perceptual models. The perceptual models are in turn translated into quantitative conceptual models, which simulate the hydrological processes using networks of connected reservoirs and transfer functions. More generally, the paper illustrates the evolution of perceptual models based on experimental fieldwork data, the translation of perceptual models into conceptual models and the value of different types of data for processes understanding and model representation. Copyright © 2014 John Wiley & Sons, Ltd.     

Late Holocene slip rate and average recurrence interval of great earthquakes on the Shangzhi segment of the Yilan‐Yitong Fault Zone,northeastern China: Constraints from paleo‐earthquakes and historical written records

The Yilan‐Yitong Fault Zone (YYFZ) is considered to be the key branch of the Tancheng‐Lujiang Fault Zone (TLFZ) in northeastern China. Although the Mesozoic and early Cenozoic deformation of the YYFZ has been studied intensively over the past century, few estimates of slip rate and recurrence interval of large earthquakes in the late Quaternary, which are the two most important parameters for understanding the potential seismic hazard of this crucial structure, were obtained. Based on integrated interpretations of high resolution satellite images and detailed geologic and geomorphic mapping, linear landforms were identified, including fault scarps and troughs, along the Shangzhi segment of the YYFZ, which exceeds 25 km in length. Synthesized results of trench excavations and differential GPS measurements of terrace surfaces indicate that two events (E1, E2) occurred along the Shangzhi segment during the late Holocene, which resulted in 3.2 ±0.1 m of total vertical co‐seismic displacement with clear features of thrust motion. ¹⁴C dating of samples suggests that event E1 occurred between 440 ±30 years BP and 180 ±30 years BP and that event E2 occurred between 4 090 ±30 years BP and 3 880 ±30 years BP, which indicates that the minimum vertical slip rate of the Shangzhi segment of the YYFZ has been approximately 0.8 ±0.03 mm/year during the late Holocene. Constraints from paleo events and the slip rate suggest that the average recurrence interval of major earthquakes on the YYFZ is 3 800 ±200 years. Historical documents in Korea show that event E1 possibly corresponds to the earthquake that occurred in AD 1810 (the Qing Dynasty in Chinese history) in the Ningguta area, which had surface‐wave magnitude (Ms) of 6.8–7.5. Studies of kinematics show that the right‐lateral strike‐slip with a reverse component has been dominant along the YYFZ during the late Holocene.     

Spatial distribution of crustaceans associated with shallow soft‐bottom habitats in a coral reef lagoon

The ecology and diversity of the shallow soft‐bottom areas adjacent to coral reefs are still poorly known. To date, the few studies conducted in these habitats dealing with macroinvertebrate fauna have focused on their abundance spatial patterns at high taxonomic levels. Thus, some aspects important to evaluate the importance and vulnerability of these habitats, such as species diversity or the degree of habitat specialization, have often been overlooked. In this study we compared the crustacean assemblages present in four different habitats at Magoodhoo Island coral reef lagoon (Maldives): coral rubble, sandy areas and two different seagrass species (Thalassia hemprichii and Cymodocea sp.). Forty‐two different crustacean species belonging to 30 families and four orders were found. ‘Site’ was a significant factor in all of the statistical analyses, indicating that tropical soft‐bottom habitats can be highly heterogeneous, even at a spatial scale between tens and hundreds of meters. Although traditionally it has been considered that seagrass beds host greater species diversity and abundance of organisms than adjacent unvegetated habitats, no differences in the univariate measures of fauna (abundance of organisms, number of species and Shannon diversity) were observed among habitats. However, sandy areas, coral rubble and seagrass beds exhibited different species composition of crustacean communities. The percentage of taxa considered as potential habitat specialists was 27% and the number of species exclusively occurring in one habitat was especially high in seagrass beds. Thus, degradation of this vegetated habitat would result in a great loss of biodiversity in tropical shallow soft‐bottom habitats.     

Multi‐temporal scale changes of streamflow and sediment load in a loess hilly watershed of China

Global climate change and diverse human activities have resulted in distinct temporal–spatial variability of watershed hydrological regimes, especially in water‐limited areas. This study presented a comprehensive investigation of streamflow and sediment load changes on multi‐temporal scales (annual, flood season, monthly and daily scales) during 1952–2011 in the Yanhe watershed, Loess Plateau. The results indicated that the decreasing trend of precipitation and increasing trend of potential evapotranspiration and aridity index were not significant. Significant decreasing trends (p < 0.01) were detected for both the annual and flood season streamflow, sediment load, sediment concentration and sediment coefficient. The runoff coefficient exhibited a significantly negative trend (p < 0.01) on the flood season scale, whereas the decreasing trend on the annual scale was not significant. The streamflow and sediment load during July–August contributed 46.7% and 86.2% to the annual total, respectively. The maximum daily streamflow and sediment load had the median occurrence date of July 31, and they accounted for 9.7% and 29.2% of the annual total, respectively. All of these monthly and daily hydrological characteristics exhibited remarkable decreasing trends (p < 0.01). However, the contribution of the maximum daily streamflow to the annual total progressively decreased (?0.07% year^?1), while that of maximum daily sediment load increased over the last 60 years (0.08% year^?1). The transfer of sloping cropland for afforestation and construction of check‐dams represented the dominant causes of streamflow and sediment load reductions, which also made the sediment grain finer. Copyright © 2015 John Wiley & Sons, Ltd.     

Scales of predator detection behavior and escape in Fissurella limbata: A field and laboratory assessment

The consumptive effects of predators are widely acknowledged, but predation can also impact prey populations through non‐consumptive effects (NCEs) such as costly antipredator behavioral responses. The magnitude of antipredator behavioral responses by prey is determined by an assessment of risk using sensory cues, which in turn is modulated by the environmental context. We studied the detection behavior and escape response of the keyhole limpet Fissurella limbata from the predatory sea star Heliaster helianthus. Through laboratory and field experimental trials, we quantified the distance and time of predator detection behavior by the prey, and measured their active escape responses when elicited. We found that predator detection by the limpet was chiefly mediated by distance, with experimental individuals capable of detecting predator presence effectively up to distances of at least 50 cm in the field and 70 cm under laboratory conditions. Our results indicate that this prey species is able to evaluate the proximity of its predator and use it as an indication of predation risk; therefore, predator–prey distance appears to be a primary predictor of the magnitude of the antipredator response. Given the tight relationship between predator distance and prey movement and the important role herbivores can play, particularly in this ecosystem, we expect that NCEs will cascade to the patterns of abundance and composition of rocky shore communities through changes in prey foraging behavior under risk.     

低纬高原冰雹与暴雨对比分析

通过对低纬高原地区多个冰雹和暴雨个例的多方面的对比分析,发现冰雹和暴雨的发生在大气环境背景、大气层结、大气不稳定性及云图特征上既有一些相似之处,也存在一些明显的区别.研究发现,发生冰雹时,中纬度低槽较偏南,受北方天气系统影响明显;发生暴雨时,受热带系统影响明显,中纬度低槽稍偏北.在冰雹发生前,大气中层较干、低层较湿,但层结仍为较稳定的状态;在暴雨发生前,大气中、低层均较湿,层结为弱稳定状态.冰雹的发生要求下层大气气温相对较低,以使雹粒在溶化之前可到达地面,而暴雨的发生要求大气富含水汽.冰雹以冬春多见,夏季较少;暴雨以夏季较多,而冬春较少.与此对应,产生暴雨的强对流其对流强度要强于产生冰雹的,但对于同一季节发生的冰雹和暴雨,两者的对流强度是相近的.