原子探针层析技术及其在矿床研究中的应用

原子探针层析技术（APT）是一种能够以亚纳米分辨率提供定量的三维元素和同位素分析的测试分析技术,具有极高的空间分辨率和低的检出限。虽然原子探针主要用于材料科学和半导体领域,但随着近年来在矿床研究中应用的不断增加,正逐渐成为矿床研究的有用手段。与传统的地质分析技术相比,原子探针具有独特的技术优势,可以测量体积＜0.0007μm3的矿物的元素组成,能够在纳米尺度上揭示矿物成分的复杂性,为理解地质演化过程提供全新的认识。本文在简述原子探针层析技术的基本原理、样品的选择和处理以及针尖样品制备的基础上,重点从成矿元素赋存状态、纳米尺度包裹体和稳定同位素组成三个方面阐述了原子探针在矿床研究中的代表性应用成果。迄今为止,原子探针在矿床学中的应用主要集中在成矿元素赋存状态的分析上,尤其是与金矿相关的黄铁矿或其他化学组成相对简单的矿物。而在纳米尺度包裹体和稳定同位素组成方面,原子探针应用成果虽不如前者丰富,但也取得了一些重要的全新认识,表现出良好的应用前景。原子探针在矿床学领域迅速发展的同时,也存在一些亟需解决的问题,如复杂质谱峰的标定、三维重建失真等。尽管如此,相信随着技术的不断进步,原子探针将逐渐成为矿床研究的重要工具。     

津巴布韦塔卡金矿地球化学异常特征及找矿标志

本文以津巴布韦塔卡金矿的区域地球化学资料为基础,对矿区地球化学特征、金成矿条件及找矿标志进行了分析,发现矿体主要赋存于元古宙Umkondo群的绢云石英片岩中,并受南北向区域构造控制。区内Au、W 、Hg 、Sb等异常共生组合元素,均可作为Au的找矿指示元素。通过对塔卡金矿的区域地质-地球化学异常特征和找矿标志的研究,建立了该金矿的地球化学异常模型及找矿标志,对已取得的1:25万区域化探异常的筛选和评价,以及进一步提高化探找矿效果,均具有一定的启示意义。     

Analysis of the positive ionospheric response to a moderate geomagnetic storm using a global numerical model

Current theories of F-layer storms are discussed using numerical simulations with the Upper Atmosphere Model, a global self-consistent, time dependent numerical model of the thermosphere-ionosphere-plasmasphere-magnetosphere system including electrodynamical coupling effects. A case study of a moderate geomagnetic storm at low solar activity during the northern winter solstice exemplifies the complex storm phenomena. The study focuses on positive ionospheric storm effects in relation to thermospheric disturbances in general and thermospheric composition changes in particular. It investigates the dynamical effects of both neutral meridional winds and electric fields caused by the disturbance dynamo effect. The penetration of short-time electric fields of magnetospheric origin during storm intensification phases is shown for the first time in this model study. Comparisons of the calculated thermospheric composition changes with satellite observations of AE-C and ESRO-4 during storm time show a good agreement. The empirical MSISE90 model, however, is less consistent with the simulations. It does not show the equatorward propagation of the disturbances and predicts that they have a gentler latitudinal gradient. Both theoretical and experimental data reveal that although the ratio of [O]/[N₂] at high latitudes decreases significantly during the magnetic storm compared with the quiet time level, at mid to low latitudes it does not increase (at fixed altitudes) above the quiet reference level. Meanwhile, the ionospheric storm is positive there. We conclude that the positive phase of the ionospheric storm is mainly due to uplifting of ionospheric F2-region plasma at mid latitudes and its equatorward movement at low latitudes along geomagnetic field lines caused by large-scale neutral wind circulation and the passage of travelling atmospheric disturbances (TADs). The calculated zonal electric field disturbances also help to create the positive ionospheric disturbances both at middle and low latitudes. Minor contributions arise from the general density enhancement of all constituents during geomagnetic storms, which favours ion production processes above ion losses at fixed height under day-light conditions.     

江西于都某钨矿区土壤重金属特征及生态风险评价

金属矿产资源的持续开发活动通常会导致矿区土壤重金属含量累积,厘清土壤重金属环境污染特征并评价其生态风险,可为监测土壤环境质量和预防土壤污染提供依据。选择江西于都某百年开采钨矿山,采用单因子污染指数法、内梅罗综合指数法和Hakanson潜在生态风险指数法,对其周边土壤中Cr、Ni、Cu、Zn、Cd、Pb、As、Hg污染特征及潜在生态风险进行调查评价。评价结果表明,研究区土壤受到Cu、Zn、Cd、Pb、As等重金属的污染,单因子污染指数分别为6.74、3.72、45.1、3.36、8.88;综合污染评价表明,Cd是主要污染贡献因子,其次为As、Cu、Pb、Zn;土壤综合潜在生态风险指数平均值高达2065,属很强生态风险;强生态风险及以上区域主要分布在矿山周边及矿山下游河道附近,分布面积约占研究区总面积的43.89%;研究区土壤重金属相关性分析表明,Cu、Zn、Cd、Pb之间具有显著的相关性。综合研究结果可知,该区域土壤Cd具有一定的潜在生态风险,应引起充分重视,矿山开发利用可能是导致Cu、Zn、Cd、Pb污染的主要原因。     

基于时间序列法的北京市需水量预报(英文)

It is essential to establish the water resources exploitation and utilization planning,which is mainly based on recognizing and forecasting the water consumed structure rationally and scientifically.During the past 30 years(1980-2009),mean annual precipitation and total water resource of Beijing have decreased by 6.89% and 31.37% compared with those perennial values,respectively,while total water consumption during the same period reached pinnacle historically.Accordingly,it is of great significance for the harmony between socio-economic development and environmental development.Based on analyzing total water consumption,agricultural,industrial,domestic and environmental water consumption,and evolution of water consumed structure,further driving forces of evolution of total water consumption and water consumed structure are revealed systematically.Prediction and discussion are achieved for evolution of total water consumption,water consumed structure,and supply-demand situation of water resource in the near future of Beijing using Time Series Forecasting Method.The purpose of the endeavor of this paper is to provide scientific basis for the harmonious development between socio-economy and water resources,for the establishment of rational strategic planning of water resources,and for the social sustainable development of Beijing with scientific bases.     

工程建筑沉降预测的非等间距灰色建模

介绍了传统灰色GM(1,1)模型建立的基本思路及其精度评定方法,着重探讨了非等间距数列的灰色预测建模问题,给出了详细的建模过程。并结合高层建筑沉降监测实例进行分析,取得了较好效果。     

航天遥感技术在叶尔羌河中下游地区Au、Cu等多金属矿找矿有利地段预测中的应用研究

板块构造成矿理论认为西昆仑叶尔羌河中下游地区属于Ａｕ、Ｃｕ及多金属矿成矿远景区,但因其野外地质条件恶劣,交通状况差,地质勘探极其困难而影响了找矿工作的深入开展,为此我们利用航天遥感技术的优势进行了找矿有利地段预测研究。在研究中首先对区域地质遥感影像特征进行了综合分析,并根据板块构造成矿理论对矿化作用进行了空间划分和成矿条件总结。在此基础上,通过成矿相关影像特征信息的提取,圈定出Ａｕ、Ｃｕ及多金属矿成矿有利地段。     

安宁磷矿区基于3S技术的矿山地质灾害隐患三维判识

以云南省安宁磷矿区为例,基于3S技术构建三维模型,在ArcGIS软件中利用高分辨率遥感图像建立矿山地质灾害隐患三维判识标志,圈定并量算出地质灾害隐患体及影响对象的范围,实地了解并验证地质灾害隐患信息的可靠程度,取得的成果为矿山企业和相关管理部门提供了基础信息和决策支持,具有一定的推广应用价值.     

基于IRCGA优化的GM(1,1)变形预测方法与应用研究

阐述了引入时间距离权的传统GM(1,1)模型的建模过程以及灰色模型等级的判断方法,深入分析了白化背景参数λ取值对建模精度的影响;同时针对传统λ取值的缺陷,提出使用基于实数编码的改进遗传算法(IRCGA)对其进行优化处理,并用多个工程实例分析验证了优化后的GM(1,1)模型相对传统的灰色模型及其优化模型拟合效果更好,更加贴近真实数据序列。     

基于ARMA模型的基坑沉降监测预测研究

应用ARMA模型对地铁车站基坑监测数据进行预测分析。在参考利用已有的ARMA模型算法进行预报分析的基础上,联合最小二乘原理对模型算法进行改进,结合基坑工程算例,验证了新模型算法的可行性、有效性及稳定性。说明改进之后的新模型算法较老模型算法提高了预测精度且提升了运算效率。