The main structure and tectonic features of the Chernorud-Mukhor site on the western shore of Lake Baikal from TEM and SP measurements

Transient electromagnetic (TEM), self-potential (SP) and geoelectrical mapping measurements were carried out at the Chernorud-Mukhor site in the Priolkhonje area on the western shore of the Lake Baikal. All measurements were made along several profiles across the main strike of the regional Primorsky fault. TEM measurements were carried out in a time range from a few tens of microseconds to several tens of milliseconds. The most important result of the 1D modelling of TEM soundings is the discovery of nearly horizontal boundaries that divide high resistive overlying and well conducting underlying rocks. The resistivity of the former is in the range from 100 Ωm to 1000 Ωm, while the resistivity of the latter varies from less than 1 Ωm to several tens of Ωm. This good conductive zone could also be verified by geoelectrical mapping using Schlumberger array (AB/2=100 m). Due to high conductivity of the underlying rocks only the upper boundary of the conductive layer could be determined by TEM soundings. A regional SP anomaly with amplitude of about −450 mV has also been observed above the low resistivity zone indicating the electron nature of its conductance. Geologically, the conductive zone is represented by a graphite-bearing layer within the region of archean rocks. Since that layer extends over a large area, it may be used as a key in studying structures and tectonics of the Priolkhonje area. A 1D TEM geoelectric section shows a wide, gently sloping syncline as a probable base structure of the Chernorud-Mukhor site. Neotectonic faults divide the syncline into vertically displaced blocks that form a wide complicated graben with a total amplitude of about 250 m.     

Lower palaeozoic and precambrian petroleum source rocks and the coalification path of alginite

Organic-rich samples derived from a Middle Cambrian Formation in the Georgina Basin, and from the Middle Proterozoic of the McArthur Basin in northern and central Australia, yielded alginite ranging from immature oil shale material to overmature residue. A maturation scale has been developed based on the thermal evolution of alginite as determined from reflectance and fluorescence. The coalification path of alginite is marked by jumps in contrast to the linear path of wood-derived vitrinite. Six zones have been recognised, ranging from undermature (zone I), through the mature (zones II/III), followed by a stable stage of no change (zone IV) to the overmature (zones V and VI). The onset of oil generation in alginite as evident from the present study is at 0.3% R_{o Alg.} and is expressed in a change of fluorescence from yellow to brown, and a coalification jump from 0.3 to 0.6% R_o of Alg. In many boreholes zone III can be distinguished between 0.6 and 0.8% R_o of Alg. where subsequent oil generation occurs. Zones II and III represent the oil window.A zone of little or no change designated zone IV, at of alginite follows zones II/III. A marked coalification jump characterises zone V, where a pronounced change in reflectance occurs to >1.0% R_{o Alg.}, signifying peak gas generation. The border of oil preservation lies at the transition of zone V and VI, at 1.6% R_{o Alg.} In zone VI gas generation only occurs.Comparison of reflectance results with experimental and geochemical pyrolysis data supports high activation energies for hydrocarbon generation from alginite, and therefore a later onset of oil generation than other liptinite macerals (i.e. cutinite, exinite, resinite) as well as a narrow oil window.Transmission electron microscopy (TEM) confirms that alginite does not go through a distinct intermediate stage but that the percentage of unreacted organic matter decreases as maturation proceeds. A clear distinction can be made in TEM between immature alginite, alginite after oil generation, and alginite residue following gas generation. Alginite beyond 1.6% R_o acquires very high densities and the appearance of inertinite in TEM.Bitumens/pyrobitumens make a pronounced contribution to the organic matter throughout the basins and have been shown to effect pyrolysis results by suppressing T_max. The bitumens/pyrobitumens have been divided into four groups, based on their reflectance and morphology, which in turn appears to be an expression of their genetic history. Their significance is in aiding the understanding of the basins' thermal history, and the timing of oil and gas generation.     

3-D approximate inversion for transient electromagnetic soundings

IntroductionThe issues of forward and inverse interpretation for homogeneous half space models and layered models of the Earth have well been solved in trAnsient electromagnetic sounding (TEM), butinterpreting data from more complicated 2-D or 3-D models are difficult because their responsefunctions are complicated and expensive to calculate. For the sake of simplification, based on thetheories of smoke ring (Nabighian, 1979), we regard current lines in the Earth induced by transmitting sou…     

瞬变电磁法寻找铝土矿效果与分析

铝土矿属于风化矿床,覆存于奥陶灰岩风化壳附近的不整合面之上。受沉积环境和剥蚀程度等因素影响,在风化壳低洼部位富集。铝土矿体电性上呈高电阻率特征,与下部灰岩电性较为接近,因此。用电法寻找该类矿床无直接有效的手段。瞬变电磁法是寻找低电阻率金属矿的有效方法之一,对高电阻率目标体分辨能力比较弱,特别是在有低电阻率层覆盖的情况下效果不理想。选择渭北某铝土矿区投入瞬变电磁方法剖面工作,建立适当地电模型,分析瞬变电磁衰减曲线及电阻率断面特征,对灰岩界面进行划分,推断矿体富集部位。经过钻孔验证,取得了较好的找矿效果。     

大亚湾水域两种拟菱形藻的形态学鉴定及毒素分析

对2005年分离自广东大亚湾的两种潜在产毒拟菱形藻进行了形态学观察和毒性分析.通过透射电子显微镜(TEM)观察确认藻种为细弱拟菱形藻(Pseudo-nitzschia cuspidata)和多纹拟菱形藻(P.multistriata).采用高效液相色谱法(HPLC)对这两种藻的常规培养样进行软骨藻酸毒素检测,结果均未检测到软骨藻酸.鉴于以上两种拟菱形藻存在着潜在产毒特性,不同培养条件的诱导实验尚需继续.     

几种典型近地表有限导体瞬变电磁特征响应研究

近地表有限导体的瞬变电磁响应中包含其形状、结构特征,如何建立这些特征与其响应之间的关系是近地表有限导体探测与识别的核心问题.本文建立了几种典型有限导体响应的三维感应偶极子模型,通过有限导体早期幂函数衰减的幅度与速率、晚期指数衰减的幅度与时间常数共四个模型参数表征有限导体的形状和结构特征,利用最小二乘拟合算法提取这些模型参数,揭示有限导体的形状、结构特征与模型参数之间的内在联系.理论与实验研究结果表明：具有绕球心旋转对称性的球形目标体,其三维感应偶极子响应完全相同,早期响应呈幂函数衰减,晚期呈e指数衰减,信号幅度和时间常数均能很好反映球体半径与材料特性;具有绕轴旋转对称性目标体,其三维感应偶极子响应部分相同,早期幂函数衰减的幅度与速率主要体现目标体的长度特征,晚期e指数衰减的时间常数体现了目标体的外径与壁厚特征;非轴对称性目标体,其三维感应偶极子响应均不相同,各个感应偶极子参数差异较大.本文的研究对提高瞬变电磁系统区分轴对称目标体与金属碎片能力,降低系统探测虚警率具有重要意义.

     

Hydrous olivine (Mg1? y? Fe2+y)2? x ?v x ? SiO4H2 x – a new DHMS phase of variable composition observed as nanometer-sized precipitations in mantle olivine

 An olivine grain from a peridotite nodule 9206 (Udachnaya kimberlite, Siberia) was investigated by TEM methods including AEM, HRTEM, SAED and EELS techniques. A previous study of the 9206 olivine sample revealed OH absorption bands in the IR spectrum and abundant nanometer-sized OH-bearing inclusions, of hexagonal-like or lamellar shape. Inclusions, which are several hundred nm in size, consist of 10 ? phase, talc and serpentine (chrysotile and lizardite). The lamellar (LI) and hexagon-like small inclusions of several ten nm in size (SI) are the topic of the present paper. AEM investigations of the inclusions reveal Mg, Fe and Si as cations only. The Mg/Si and Fe/Si atomic ratios are lower in the inclusions than in the host olivine. The Si concentration in the olivine host and both lamellar inclusions and small inclusions is the same. A pre-peak at 528eV was observed in EEL spectra of LI and SI, which is attributed to OH⁻ or Fe³⁺. From these data it is concluded that there is a OH⁻- or Fe³⁺-bearing cation-deficient olivine-like phase present. HRTEM lattice fringe images of LI and SI exhibit modulated band-like contrasts, which are superimposed onto the olivine lattice. Diffraction patterns (Fourier-transforms) of the HREM images as well as SAED patterns show that the band-like contrasts in HRTEM images of the inclusions are caused by periodic modulations of the olivine lattice. Three kinds of superperiodicity in the olivine structure such as 2a, 3a and 3c, were observed in SAED patterns. The corresponding olivine supercells labelled here as Hy-2a, Hy-3a and Hy-3c were derived. The M1-vacancies located in the (100) and (001) octahedral layers of the olivine lattice are suggested to form ordered arrays of planar defects (PD), which cause the band-like contrasts in HRTEM patterns as well as the superperiodicity in the SAED patterns. The vacancy concentrations as well as the chemical composition of Hy-2a, Hy-3a and Hy-3c olivine supercells were calculated using crystal chemical approaches, assuming either {(OH)^< _O−V^" _Me−(OH)^< _O}^↔, or {F e ^< _Fe −H _Me ^′}^↔ or {2F e ^< _Fe −V _Me ^"}^↔ point defect associates. The calculated theoretical compositions Mg_1.615Fe⁺² _0.135v_0.25SiO₄H_0.5 (Hy-2a) and Mg_1.54Fe²⁺ _0.12v_0.33SiO₄H_0.66 (Hy-3a and Hy-3c) are in a good agreement with the AEM data on inclusions. Hy-2a, Hy-3a and Hy-3c are considered to be a hydrous olivine with the extended chemical formula (Mg_1-yFe²⁺ _y)_2−xv_xSiO₄H_2x. The crystal structure of hydrous olivine is proposed to be a modular olivine structure with Mg-vacant modules. The crystal chemical formula of hydrous olivines in terms of a modular structure can be written as [MgSiO₄H₂] · 3[Mg_1.82Fe_0.18SiO₄] for Hy-2a, [MgSiO₄H₂] · 2[Mg_1.82Fe_0.18SiO₄] for Hy-3a and Hy-3c. Hydrous olivine is suggested to be exsolved from the olivine 9206, which has been initially saturated by OH-bearing point defects. The olivine 9206 hydration as well as the following exsolution of hydrous olivine inclusions is suggested to occur at high pressure-high temperature conditions of the upper mantle. Received: 15 January 2001 / Accepted: 2 July 2001     

剩余视纵向电导比定义——TEM新导出参数ΔSτrt及一维直接反演特性

视纵向电导是瞬变电磁法勘探理论的基本参数之一,在以中心回线装置应用为主的金属物探界很少应用。为改变此状况,创立了剩余视纵向电导比ΔSτrt定义及其具体计算方法。ΔSτrt是TEM方法中第一个相对参量,大量的模型计算和野外数据试算表明,其效果与视电阻率一维直接反演相当。此计算方法简单且是单解。本参量主要适用于中心回线和重叠回线的中、近带数据处理,略加修改亦适用于其他装置,乃至电偶源装置及磁参数的处理。     

直流电测深法与中心回线瞬变电磁法联合反演

分析了直流电测深法(VES)与中心回线瞬变电磁法(TEM)对地层的响应特征,结果显示:TEM对低阻层反应灵敏,而VES对高阻层具有较高的分辨能力.基于TEM与VES对地层响应特征互补的特点,尝试将TEM与VES数据进行联合反演,模型试算结果表明,联合反演的效果明显比单一方法反演的效果好.     

电偶源瞬变电磁测深研究(四)--瞬变电磁测深视电阻率

给出了由电偶源垂直磁场Ｈｚ（ｔ）计算全区（期）视电阻率的数值计算方法;将时间范围扩展到几十秒,以满足大偏移距（ｒ）探测大深度的需要。模拟计算结果显示,全区视电阻率能清晰地反映地电断面的结构,有助于定性定量解释