常量元素记录的毛乌素沙地东南缘全新世气候变化

毛乌素沙地处于中国季风边缘的半干旱区,对气候变化响应敏感,是研究过去全球气候变化的理想场所。对沙地东南缘锦界剖面全新统砂质黄土-古风成砂-古土壤互层沉积序列进行研究,在OSL测年基础上,通过沉积物常量元素氧化物含量及其比值分析,结合粒度、磁化率特征,探讨了毛乌素沙地东南缘7.9ka BP以来气候变化。结果表明：（1）地层常量元素氧化物以SiO₂和Al₂O₃为主,其他元素含量依次为Na₂O、K₂O、Fe₂O₃、CaO、MgO。各种元素活动性不同,K、Na活动性较强,易淋失;Si活动性较稳定,风成砂中易富集;Ca、Mg、Al、Fe活动性较弱,古土壤中富集。（2）7.9ka BP以来气候变化分为6个阶段。7.9～7.3 ka最温暖湿润时段;7.3～6.8 ka,气候转冷干;6.8～4.3 ka,整体上温暖湿润,期间存在2次由暖湿变冷干的波动,并出现过6次风沙活动,即6.6～6.3、6.1、5.9、5.7～5.5、5.3～5.0、4.7～4.4 ka;4.3～2.5ka BP,气候转冷干;2.5～1.8ka BP出现过短暂湿润期,但暖湿程度不及全新世中期;1.8ka BP以来气候渐趋干旱并接近现代气候。（3）全新世气候变化与毗邻的萨拉乌苏河流域、浑善达克沙地等记录的气候变化具有很好的一致性,这是通过东亚冬夏季风强弱消长变化对全球变化的区域响应。     

大岗山水电站坝肩边坡开挖支护有限元模拟

大岗山水电站坝肩边坡地质条件复杂,断层、岩脉、卸荷裂隙密集带、深部卸荷带及节理裂隙发育。为对该边坡在开挖支护过程中的应力、变形情况进行分析,采用弹黏塑性有限元软件EVP3D,利用弹塑性有限元法进行边坡稳定性的三维有限元计算,揭示边坡可能的失稳部位,对初拟的施工程序的合理性进行评价,并对边坡的支护方案提出建议。     

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

石笋氧同位素和微量元素记录的陕南地区4200～2000a B.P.高分辨率季风降雨变化

基于陕南祥龙洞石笋XL2的19个230Th年龄、218个氧同位素分析以及896个Sr/Ca分析数据,高分辨率重建了4200～1972a B.P.期间陕南地区季风降雨变化.重建结果显示陕南地区这一时期季风降雨有显著的127～105a和57a周期,可能分别受控于太阳活动、PDO和/或AMO的变化.重建时段有3次百年尺度的干旱事件,分别发生于2200～2100a B.P.,2900～2700a B.P.和3600～3400a B.P.,其中2900～2700a B.P.干旱事件对应于北大西洋地区2.8ka冷事件.对比研究显示,尽管祥龙洞石笋和董哥洞石笋δ18O记录整体一致,但除了2900～ 2700aB.P.干旱事件之外,其他两次干旱事件在董哥洞石笋记录中并不明显.而尽管总体上祥龙洞和和尚洞石笋δ18O记录的差异要大,但XL2的3次干旱事件在和尚洞记录都有明显体现.有精确年代控制的祥龙洞、董哥洞及和尚洞石笋氧同位素记录的差异,揭示晚全新世我国季风降雨在十一百年尺度存在区域差异.     

Sensitivity Analysis of the Super Heavy Rainfall Event in Henan on 20 July (2021) Using ECMWF Ensemble Forecasts

An unprecedented heavy rainfall event occurred in Henan Province, China, during the period of 1200 UTC 19-1200 UTC 20 July 2021 with a record of 522 mm accumulated rainfall. Zhengzhou, the capital city of Henan, received 201.9 mm of rainfall in just one hour on the day. In the present study, the sensitivity of this event to atmospheric variables is investigated using the ECMWF ensemble forecasts. The sensitivity analysis first indicates that a local YellowHuai River low vortex(YHV) in the southe...     

北京市再生水灌溉对地下水的重金属污染风险

通过野外取样分析再生水灌溉、长期污水灌溉条件下土壤剖面和地下水中重金属含量,预测再生水灌溉对地下水的重金属污染风险。结果表明：污染严重的Cr、Cu和Zn等3种元素主要在土壤表层0～20cm累积,0～180cm土层呈先降低后升高,之后再降低的变化趋势。污染较轻的As、Ni和Pb在0～60cm土层含量差异不大,0～180cm土层大致呈先升高后降低的变化趋势。所有重金属在土壤剖面90cm左右的土层中均存在高值区,该层含量高于上、下土层,高值区的分布位置与北京剖面土壤发生层的分布特征一致,与成土母质自然发育有关,并非表层土壤重金属向下淋溶沉积而成。综合土壤剖面重金属分布特征和调查区地下水重金属浓度情况,重金属向下层土壤迁移的趋势很小,即使凉水河灌区污染严重的Cr、Cu、Zn,主要在土壤表层累积,并未导致地下水重金属污染。在当前的水质条件下,农田再生水灌溉输入的重金属量低于大气沉降和有机肥施用,再生水灌溉导致地下水的污染风险小于大气沉降和有机肥施用。因此相对于大气沉降、有机肥施用等输入途径,再生水灌溉导致地下水重金属污染的可能性不大。     

大亚湾扁脑珊瑚中重金属的年际变化及其海洋环境指示意义

通过对南海北部大亚湾海区1976～1998年扁脑珊瑚Platygyra骨骼Cu,Pb和Cd含量的研究及其与观测记录的比较,初步认为珊瑚可以记录大亚湾海区重金属的年际变化特征;发现1979年和1991年是重金属含量比较高的年份;由扁脑珊瑚记录推测珊瑚中Cd含量短时间内可能受到了核电站兴建的影响,但近20多年来的大亚湾扁脑珊瑚及海水中重金属状况的总体变化过程可能与整个广东海域水质的变化背景基本一致,而与核电站的兴建和运行似乎没有明显的关系。     

湘江中下游农田土壤和蔬菜的重金属污染

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.     

四川地区一次特大暴雨天气过程分析

利用四川省加密气象站逐时降水资料、FY-2G卫星TBB产品及NCEP/NCAR的1°×1°逐6 h再分析资料,对2020年8月15—18日四川地区的一次特大暴雨天气过程进行诊断分析。结果表明：此次过程具有降水强度大、范围广、持续时间长、夜雨特征明显等特征。高空影响槽东移叠加在低空低涡之上,为强降水过程发生发展提供了有利的环流背景和天气尺度动力抬升条件;西太平洋副热带高压（以下简称“副高”）稳定少动是强降水过程长时间维持的主要原因。孟加拉湾低涡槽前西南暖湿气流与副高外围偏南暖湿气流共同为此次强降水过程提供了充足的水汽。中尺度对流系统强烈发展是造成强降水的主要原因,云图TBB≤-52℃的冷云区和TBB等值线梯度极大值区与强降水落区对应关系较好,可为强降水监测预警工作提供参考。     

Crude-oil hydrocarbon composition characteristics and oil viscosity prediction in the northern Songliao Basin

Crude oil hydrocarbon composition characteristics and oil viscosity prediction are important bases in petroleum exploration.A total of 54 oil/heavy-oil samples and 17 oil sands were analyzed and quantified using both comprehensive 2D gas chromatography(GC×GC)and comprehensive 2D gas chromatography/time-of-flight mass spectrometry(GC×GC/TOFMS).The results show that crude oil in the West slope is mainly heavy oil and its hydrocarbon composition is characterized overall by paraffinsmono-aromaticsnaphthenesnon-hydrocarbonsdi-aromaticstri-aromaticstetra-aromatics.Aromatics are most abundant and non-hydrocarbons are least abundant,whilst content differences among paraffins,naphthenes,aromatics,and non-hydrocarbons are less than 15%.There are two types of heavy oil,secondary type and mixing type.Biodegradation is the main formation mechanism of heavy oil.Biodegradation levels cover light biodegradation,moderate biodegradation,and severe biodegradation.With increasing biodegradation,paraffin content decreases while contents of aromatics and nonhydrocarbons increase.In contrast,naphthene content increases first and then decreases with increasing biodegradation.In severe biodegradation stage,naphthenes decrease more quickly than aromatics and non-hydrocarbons.This provides a new method for studying oil/heavy-oil biodegradation mechanism and biodegradation resistance of different hydrocarbons at different biodegradation stages.In the Longhupao-Daan terrace and Qijia-Gulong depression,most crude oil is conventional oil.Its composition is dominated by paraffins with the lowest content of aromatics.In some casual oil wells from the Longhupao-Daan terrace,crude oil from Saertu oil reservoirs is moderately biodegraded whereas crude oil from Putaohua oil reservoir is lightly biodegraded.Chemical parameters using saturate hydrocarbons and aromatics are usually not suitable for determining organic type and thermal maturity of biodegraded oil,especially of moderately or severely biodegraded oil,whilst Ts/(Ts+Tm)ratio can be used to determine thermal maturity of both conventional crude oil and heavy oil.