The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

沙漠增温效应特征及绿洲农业热量资源分异规律的研究

为了进一步认识绿洲高效农业特殊的热量资源，通过研究沙漠增温效应特征表明：沙漠增温效应强弱随距离沙漠远近而不同，100km范围内沙漠对绿洲的平均增温为1．76℃；另外增温效应导致绿洲日、年温差大、干热风及冷害等气候特征；由于沙漠的面积、地貌特点等的差异，使增温效应产生原因及作用程度不尽相同，表现出绿洲农业资源分异规律，并将西北干旱区绿洲分为5个类型区。     

Relationship between solar radiation and the development and morphology of small cirque glaciers (Maladeta Mountain massif, Central Pyrenees, Spain)

Abstract Spatial and temporal variations in radiative fluxes influence glacier mass‐balance in mountain areas. The primary goal of this study was to assess differences in solar radiation on three glacial cirques located in the Maladeta Mountain massif (Central Spanish Pyrenees), and analyse their implications on glacier development and morphology. A quantitative approach is adopted to obtain the values of solar radiation (direct, diffuse and global radiation), combining several field data parameters (measured at 55 control‐points) with the solar radiation modelling package Ecosim. The data obtained confirm that the morphologies of the glacial bodies developed in the three cirques have a good correlation with the spatial variation on solar radiation inputs, favouring also the conservation (Aneto and Coronas cirques) or total vanishing (Llosás cirque) of the glacial remnants analysed here. The study shows how strongly in this Alpine‐Mediterranean context solar radiation — firstly as a function of latitude and time of year, and locally as a function of topographic slope, aspect and shadowing — controls the mass‐balance and the spatial distribution of melting in small glaciers, having an effect on the development of their morphologies.     

利用现有重力场模型求定CHAMP卫星加速度计修正参数

CHAMP卫星加速度计数据的标定是通过确定其尺度因子和偏差参数来完成的.本文基于能量守恒方程,给出利用现有重力场模型标定CHAMP卫星加速度数据的基本原理和数学模型;提出相邻历元间差分算法,大大简化了观测方程,同时避免积分常量的计算.该算法既能同时解算尺度因子和偏差参数,也可任意求解其中之一.基于实测的CHAMP卫星加速度数据,利用EGM96模型和最新公布的EIGEN-2模型进行计算与比较,验证该方法的有效性.     

Possible Impacts of the Arctic Oscillation on the Interdecadal Variation of Summer Monsoon Rainfall in East Asia

The influences of the wintertime AO (Arctic Oscillation) on the interdecadal variation of summer monsoon rainfall in East Asia were examined. An interdecadal abrupt change was found by the end of the 1970s in the variation of the AO index and the leading principal component time series of the summer rainfall in East Asia, The rainfall anomaly changed from below normal to above normal in central China, the southern part of northeastern China and the Korean peninsula around 1978. However,the opposite interdecadal variation was found in the rainfall anomaly in North China and South China.The interdecadal variation of summer rainfall is associated with the weakening of the East Asia summer monsoon circulation. It is indicated that the interdecadal variation of the AO exerts an influence on the weakening of the monsoon circulation. The recent trend in the AO toward its high-index polarity during the past two decades plays important roles in the land-sea contrast anomalies and wintertime precipitation anomaly. The mid- and high-latitude regions of the Asian continent are warming, while the low-latitude regions are cooling in winter and spring along with the AO entering its high-index polarity after the late 1970s. In the meantime, the precipitation over the Tibetan Plateau and South China is excessive, implying an increase of soil moisture. The cooling tendency of the land in the southern part of Asia will persist until summer because of the memory of soil moisture. So the warming of the Asian continent is relatively slow in summer. Moreover, the Indian Ocean and Pacific Ocean which are located southward and eastward of the Asian land, are warming from winter to summer. This suggests that the contrast between the land and sea is decreased in summer. The interdecadal decrease of the land-sea heat contrast finally leads to the weakening of the East Asia summer monsoon circulation.     

Numerical Simulation of Wind and Temperature Fields over Beijing Area in Summer

1. IntroductionThe basic role of urban-rural boundary layer re-search is to study all kinds of physical process changesin the atmosphere boundary layer over urban and itssurrounding areas. Urban heat island (UHI) is a well-known feature of urban-rural climate. Attempts toincrease the understanding of the causes of the UHIand other urban-rural boundary layer phenomena haveused observational, theoretical and modelling methodssince long before. Seaman (1989) used a hydrostaticmodel, with real …     

The reflection of plane waves in a poroelastic half-space saturated with inviscid fluid

This paper discusses surface displacements, surface strain, rocking, and energy partitioning during reflection-of-plane waves in a fluid-saturated poroelastic half-space. The medium is modeled by Biot's theory, and is assumed to be saturated with inviscid fluid. A linear porosity-modulus relation based on experimental data on sandstones is used to determine the material parameters for Biot's model. Numerical results in terms of angle of incident waves and Poisson's ratio are illustrated for various porosities and degrees of solid frame stiffness. The results show that the amount of solid frame stiffness controls the response of a fluid-saturated porous system. A poroelastic medium with essentially dry-frame stiffness behaves like an elastic medium, and the influence of pore fluid increases as dry-frame stiffness is reduced. The effects of a second P-wave become noticeable in poroelastic media with low dry-frame stiffness.     

Study on comparison between absolute and relative input energy spectra and effects of ductility factor

Introduction Estimation of an attenuation relationship for strong ground motion parameters has been an interesting research subject in the field of engineering seismology and has played a very important role in seismic safety evaluation, seismic zoning, seismic hazard evaluation of major constructions, etc. At present, the generally used parameters include peak acceleration, peak velocity and elastic response spectrum. Such parameters mentioned above are essentially independent of the duration…     

On the applicability of KirchofPs law and the principle of heat balance in thermal infrared remote sensing:A non-isothermal system

This paper proposes a basic equation of thermal radiation interaction between surface objects on the basis of the principle of heat balance in the interface. The solution of this equation takes account of the contribution of sensible heat flux and latent heat flux more completely, compared with traditional solution for surface cooling and heating processes. By the aid of the experimental data conducted in the Xiaotangshan experimental site, Beijing, both the non-applicability of Kirchoff's law and the measurability of surface emissivity in a non-isothermal system have been highlighted. Two methods called ventilation and time-delay compensations have been proposed to reduce the error induced by change of surface temperatures of non-isothermal objects during the measurement of emissivity. Based on the solution of the basic equation, this paper has analyzed and pointed out the misunderstanding in comprehension and application of Kirchoff's law published in literature.