Bond—Valence Sum and Distortion of Coordination Polyhedra

By using the Lagrange‘s intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion .The applicabilities of the bond-valence model are discussed in the following two cases:the modeling of crystal structure ,and the indication of distortion degree of a coordination polyhedron.Also it is shown that a distorted polyhedron should be in favor of a longer average bond length or a smaller coordination number.     

雷诺数对藻类垂向分布特性的影响

为研究紊流水体中藻类的垂向分布特性,依据三峡水库次级河流回水段的水动力状况,自行设计了水流实验装置,选取次级河流回水区水华高发时段的气候状况和营养盐水平为实验条件,研究了雷诺数对蓝藻、绿藻和硅藻垂向分布的影响以及雷诺数对不同水深处藻类的悬浮和聚集行为的作用.研究结果表明:在水温为20℃、光照强度为5000 lx的富营养水体中,当断面平均流速在0～0.005 m/s、雷诺数在0～1750时,蓝藻主要悬浮聚集在0.2～0.8 m的表层水体中;而当断面平均流速在0.1～0.5 m/s、雷诺数在35000～175000时,硅藻主要悬浮聚集在0.2～0.8 m的表层水体中;与蓝藻和硅藻相比,绿藻适宜的雷诺数范围更宽,当断面平均流速在0～0.05 m/s、雷诺数在0～17500时,绝大部分的绿藻都能悬浮聚集在0.2～0.8 m的表层水体中.     

2010年4月14日青海玉树7.1 级地震前震中附近地区小震活动的周、月频次分布特征

根据Kolmogorov-Smirnov分布检验法,利用2000年以来1.7≤ML≤2.9地震目录,对2010年4月14日青海玉树MS7.1前震中附近地区2000年以来地震活动的月频次和2007年7月以来地震活动的周频次分布进行了检验。结果表明,地震活动周频次和月频次都不符合泊松分布和正态分布,但周、月频次累积次数的对数与周、月频次之间呈线性关系,类似于G-R关系。分析了周、月频次的标准差σ、CV值、偏度Sk、峰度Ku和bm值等参数随时间的变化,发现在2010年4月14日青海玉树地震前,这些参数都出现了不同程度的异常变化,其中周频次的分布参数随时间的变化似乎呈现出了某种周期性特征。     

The effect of expansion ratio on the critical Reynolds number in single fracture flow with sudden expansion

Flow in a single fracture (SF) is an important research subject in groundwater hydrology, hydraulic engineering, radioactive nuclear waste repository and geotechnical engineering. An abruptly changing aperture is a unique type of SF. This study discusses the relation between the values of the critical Reynolds number (Re_c) for the onset of symmetry breaking of flow and the expansion ratio (E) of SF, which is defined as the ratio between the outlet (D) and inlet (d) apertures. This study also investigates the effect of inlet aperture d on Re_c for flow in an SF with abruptly changing apertures (SF‐ACA) using the finite volume method. Earlier numerical and experimental results showed that flow is symmetric in respect to the central plane of the SF‐ACA at small Reynolds number (Re) but becomes asymmetric when Re is sufficiently large. Our simulations show that the value of Re_c decreases with the increasing E, and the relationship between the logarithm of Re_c and E can be described accurately using either a quadratic polynomial function or a logarithmic function. However, the relationship of Re_c and d for a given E value is vague, and Re_c becomes even less sensitive to d when E increases. This study also reveals that the hydraulic gradient (J) and flow velocity (v) follow a super‐linear relationship that can be fitted almost perfectly by the Forchheimer equation. The inertial component (J_i) of J increases monotonically with Re, whereas the viscous component (J_v) of J decreases monotonically with Re. The Re value corresponding to equal inertial and viscous components of J (named as the transitional point Re) decreases when E increases, and such a transitional point Re should be closely related to the critical Reynolds number Re_c, although a rigorous theoretical proof is not yet available. Copyright © 2015 John Wiley & Sons, Ltd.     

An alternative Boussinesq equation considering the effect of hysteresis on coastal groundwater waves

This paper presents an alternative Boussinesq equation considering hysteresis effect via a third‐order derivative term. By introducing an improved moisture–pressure retention function, this equation describes, with reasonable precision, groundwater propagation in coastal aquifers subject to Dirichlet boundary condition of different oscillation frequencies. Test results confirmed that it is necessary to consider horizontal and vertical flows in unsaturated zone, because of their variable influences on hysteresis. Hysteresis in unsaturated zone can affect the water table wave number of groundwater wave motion, such as wave damping rate and phase lag. Oscillations with different periods exert different hysteresis effect on wave propagation. Truncation/shrinkage of unsaturated zones also affects the strength of hysteresis. These impacts can be reflected in the alternative Boussinesq equation by adjusting the parameter representing the variation rate of moisture associated with pressure change, as opposed to traditional computationally expensive hysteresis algorithms. The present Boussinesq equation is simple to use and can provide feasible basis for future coupling of groundwater and surface water models. Copyright © 2016 John Wiley & Sons, Ltd.     

城市浅层地震勘探过障碍变观设计

在城市浅层地震勘探数据采集中,地震测线经常会遇到河流、桥、交叉路口等地表障碍。为了尽量减小地表障碍造成的影响,需要对观测系统作变观设计。作者分析总结了城市浅层地震勘探中常见障碍以及过障碍变观模式,并开发了浅层地震过障碍变观设计软件,利用此软件可在采集现场快捷地进行过障碍变观。将这种方法应用于实际工作中,有效减小了资料缺失造成的影响,提高了资料的信噪比。该软件能够根据实际工作环境和设备条件在野外现场对观测系统进行灵活变观,设计出合理的过障碍观测系统,有效地提高了变观设计的效率。     

热流测量中垂向地下水运动干扰的校正方法

本文提出了一种地表热流测量中垂向地下水干扰的校正方法。并以江西萍乡和福建安溪的二个钻孔为例,说明了热流校正的具体过程。由于地下水对流传热的影响,垂向地下水渗透层内温度和热流随深度均呈指数分布。通过对钻孔测温数据的一维垂向Peclet数分析,可以确定渗透层内传导和对流热流分量以及热流的构成,从而得到未受地下水对流干扰的区域背景热流。这一方法不仅适用于渗透率结构均一的介质,也可用于水平层状介质。     

河北邯邢铁矿区矿山环境生态地球化学评价

在河北邯邢西石门及周边铁矿区系统地采集了各类生态环境地球化学样品,包括土壤（n=242）、玉米（n=110）、地表水（n=37）、地下水（n=31）和水系沉积物（n=81）。通过对矿区各样品元素含量特征和元素富集程度的研究,利用区域地球化学基准值和地质累积指数定量评价了矿山污染扰动程度。研究表明,矿区土壤、玉米、地表水、地下水、水系沉积物中相对富集较高的与成矿作用有关的元素及主要的伴生元素,部分重金属元素超标,土壤和水系沉积物中Se、As、Cd、Cu、As、Cd、Cu、Co元素超标,玉米中F、Cr、Cd元素接近食品卫生限值,地表水和地下水部分指标浓度接近三类水质限值。研究表明,造成污染的主要来源是铁矿尾矿沙和煤矸石中的硫化物发生氧化作用,导致重金属淋滤转移,另一来源是燃煤降尘的积聚。     

九江市网纹红土标准贯入击数与力学参数关系分析

针对九江市网纹红土层标准贯入试验实测锤击数与试验孔深、土的压缩模量、抗剪强度关系之间进行了相关性分析。结果表明：网纹红土标准贯入击数与试验孔深为正显著线性相关关系,与土的压缩模量为正弱线性相关关系,与抗剪强度为正弱线性相关关系。分析成果对在九江市开展岩土工程勘察活动具有很好的指导和借鉴意义。     

Parametric studies of disturbed rock slope stability based on finite element limit analysis methods

This study employs the finite element upper bound and lower bound limit analysis methods to investigate the stability of inhomogeneous rock slopes. The differences in the stability numbers of the upper and lower bound solutions are bracketed within ±10.5% or better, and the stability numbers obtained are presented in rock slope stability charts. These stability charts can provide a convenient tool for preliminary stability designs of inhomogeneous rock slopes. Various recommended blasting damage zones are considered, and disturbance factors are used to represent damage levels. Results showed that rock mass disturbance could significantly influence the evaluation of rock slope stability.