酸不溶物对碳酸盐岩风化壳发育程度的影响

通过对贵州岩溶区（包括湘西）不同地层系统碳酸盐岩发育的红色风化壳、以及结合本区和处于同一气候带的邻区不同岩类红色风化壳的对比研究,结果表明：（1）碳酸盐岩红色风化壳的发育程度明显受基岩酸不溶物成分的控制,酸不溶物的风化成熟度越高,红色风化壳的发育程度一般也越强。由于不同地层系统碳酸盐岩的酸不溶物组成不同,在此基础上发育的红色风化壳的风化强度自然存在着差异;（2）风化壳相对于母岩的进一步风化潜力或空间,随着基岩酸不溶物风化成熟度的增大而降低,从而更容易达到风化平衡;（3）在碳酸盐岩风化壳突变的岩-土界面,伴随碳酸盐的充分淋失、酸不溶物的地球化学指标发生了突变。因此,碳酸盐的溶解不但未阻滞和延缓了硅酸盐组分的分解,而且促进其快速风化。（4）在达到高岭石化甚至弱红土化阶段的酸不溶物基础上,发育的风化壳比结晶岩类风化壳具有更高的风化起点,也就表现出更高的风化强度。因此,笼统地把碳酸盐岩风化壳看作是弱于玄武岩及花岗岩等结晶岩类风化壳发育程度的弱风化类型是不妥的。     

Relationships between radium and radon occurrence and hydrochemistry in fresh groundwater from fractured crystalline rocks, North Carolina (USA)

Naturally-occurring radionuclides (uranium, radium, and radon), major dissolved constituents, and trace elements were investigated in fresh groundwater in 117 wells in fractured crystalline rocks from the Piedmont region (North Carolina, USA). Chemical variations show a general transition between two water types: (1) slightly acidic (pH 5.0–6.0), oxic, low-total dissolved solids (TDS) waters, and (2) near neutral, oxic to anoxic, higher-TDS waters. The uranium, radium, and radon levels in groundwater associated with granite (Rolesville Granite) are systematically higher than other rock types (gneiss, metasedimentary, and metavolcanic rocks). Water chemistry plays a secondary role on radium and radon distributions as the ²²²Rn/²²⁶Ra activity ratio is correlated with redox-sensitive solutes such as dissolved oxygen and Mn concentrations, as well as overall dissolved solids content including major divalent cations and Ba. Since ²²⁴Ra/²²⁸Ra activity ratios in groundwater are close to 1, we suggest that mobilization of Ra and Rn is controlled by alpha recoil processes from parent nuclides on fracture surfaces, ruling out Ra sources from mineral dissolution or significant long-distance Ra transport. Alpha recoil is balanced by Ra adsorption that is influenced by redox conditions and/or ion concentrations, resulting in an approximately one order of magnitude decrease (~ 20,000 to ~ 2000) in the apparent Ra distribution coefficient between oxygen-saturated and anoxic conditions and also across the range of dissolved ion concentrations (up to ~ 7 mM). Thus, the U and Th content of rocks is the primary control on observed Ra and Rn activities in groundwater in fractured crystalline rocks, and in addition, linked dissolved solids concentrations and redox conditions impart a secondary control.     

对磺基苯偶氮变色酸分光光度法测定岩石样品中的氟

采用对磺基苯偶氮变色酸分光光度法对岩石样品中氟的含量进行测定。确定的最佳测定条件为:测定波长570 nm,放置2 h后测定,盐酸介质浓度0.84 mol/L,显色剂用量5.0 mL。氟离子浓度在0~1.4 mg/L时符合比尔定律,方法检出限为0.06μg/g。以岩石标准物质代替氟标准溶液制作标准曲线,可有效降低杂质元素的干扰。对国家一级标准物质和日本玄武岩标准物质6次测定的相对标准偏差(RSD)为2.37%~6.32%。     

准噶尔盆地天然气成藏体系和成藏过程分析

准噶尔盆地目前已发现的天然气以中—小型的中浅层晚期次生气藏为主。研究表明,以区域盖层上三叠统白碱滩组泥岩为界可划分为下部近源原生天然气成藏体系和上部远源次生天然气成藏体系,前者一般具有异常高压的特征,后者则具有正常的压力系统。通过对盆地东部地区、腹部地区、西北缘地区、莫索湾凸起天然气成藏过程的解剖获得了比较一致的认识,即上部次生天然气是在下部原生天然气的改造和调整的基础上形成的,下部天然气成藏体系的原生大—中型天然气藏是未来准噶尔盆地天然气的勘探方向。值得注意的是南缘冲断带的上部成藏体系既有源自侏罗系煤系烃源岩的原生天然气聚集,又伴随有次生天然气藏的形成。     

松辽盆地朝阳沟阶地扶余-杨大城子油层油源分析与油气运移模式

基于生物标志化合物参数,系统对比分析了朝阳沟阶地扶余-杨大城子油层原油与三肇凹陷及朝阳沟阶地青山口组-段源岩的关系,表明朝阳沟阶地扶余油层有两个主要油源,即三肇凹陷青-段源岩与朝阳沟本地区青-段源岩,且两者对扶余油层的贡献量可能基本相同.朝阳沟地区杨大城子油层原油与三肇凹陷青-段源岩有密切的亲缘关系,与朝阳沟青-段源岩亲缘关系不明显.这与朝阳沟阶地源岩超压值相对较小、导致油气下排距离浅、进入杨大城子油层的油气量较小相符.在油源对比的基础上,结合断裂和砂体分布等各种地质条件,将朝阳沟阶地油气运移模式分为远源长距离侧向运移和近源短距离侧向运移两种类型.     

Brittle Rock Failure in the Steg Lateral Adit of the Lötschberg Base Tunnel

Summary  During the crossing of brittle rock formations at the L?tschberg base tunnel, failure phenomena have been observed both at the tunnel face and at the walls. A detailed analysis has been undertaken to explain these behaviours, based on the recent developments of Canadian research on brittle failure mechanisms. At the tunnel walls, a very good agreement is found between the calculated and observed damage and between two prediction methods, i.e. a semi-empirical failure criterion and elastic calculations with the “brittle Hoek-Brown parameters.” Near the face, due to the 3D nature of the stress conditions, some limitations of these approaches have been highlighted, and the growth of wall failure has been analysed. This research allowed a better understanding of the brittle rock mass behaviour at the L?tschberg base tunnel and showed that brittle failure processes dominate the behaviour of deep, highly stressed excavations in massive to moderately jointed rock. It also illustrates where improvements to the adopted approaches are required.     

Storage-discharge characteristics of an active rock glacier catchment in the Innere Ölgrube,Austrian Alps

The active rock glacier “Innere Ölgrube” and its catchment area (Ötztal Alps, Austria) are assessed using various hydro(geo)logical tools to provide a thorough catchment characterization and to quantify temporal variations in recharge and discharge components. During the period from June 2014 to July 2018, an average contribution derived from snowmelt, ice melt and rainfall of 35.8%, 27.6% and 36.6%, respectively, is modelled for the catchment using a rainfall-runoff model. Discharge components of the rock glacier springs are distinguished using isotopic data as well as other natural and artificial tracer data, when considering the potential sources rainfall, snowmelt, ice melt and longer stored groundwater. Seasonal as well as diurnal variations in runoff are quantified and the importance of shallow groundwater within this rock glacier-influenced catchment is emphasized. Water derived from ice melt is suggested to be provided mainly by melting of two small cirque glaciers within the catchment and subordinately by melting of permafrost ice of the rock glacier. The active rock glacier is characterized by a layered internal structure with an unfrozen base layer responsible for groundwater storage and retarded runoff, a main permafrost body contributing little to the discharge (at the moment) by permafrost thaw and an active layer responsible for fast lateral flow on top of the permafrost body. Snowmelt contributes at least 1/3rd of the annual recharge. During droughts, meltwater derived from two cirque glaciers provides runoff with diurnal runoff variations; however, this discharge pattern will change as these cirque glaciers will ultimately disappear in the future. The storage-discharge characteristics of the investigated active rock glacier catchment are an example of a shallow groundwater aquifer in alpine catchments that ought to be considered when analysing (future) river runoff characteristics in alpine catchments as these provide retarded runoff during periods with little or no recharge.     

从重力异常探讨威宁地区深部地质构造

从1：20万布格重力异常分离出来的剩余重力异常和水平梯度重力异常为主要研究对象,结合威宁地区的地质、物化探、遥感资料,揭示该区深部存在8条断裂,火山机构1个,基性-超基性侵入岩体1个。     

塔北、塔中地区碳酸盐岩及其原油中的二苯并噻吩类化合物

塔里木盆地塔北、塔中地区四口井(库南1井,轮南46井,塔中12井和塔参1井)寒武-奥陶系12个碳酸盐岩烃源岩(泥灰岩,泥质灰岩和云岩)岩芯样品抽提物芳烃组分中的二苯并噻吩类化合物组成和丰度变化特征可分为三种类型:Ⅰ二苯并噻吩、甲基二苯并噻吩型;Ⅱ二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩+三甲基芴混合物型;Ⅲ二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩和三甲基二苯并噻吩型。研究的塔北、塔中隆起11个海相油二苯并噻吩类化合物分布类型均为二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩和三甲基二苯并噻吩型,和海相烃源岩二苯并噻吩类化合物第Ⅲ种分布类型完全相同。据此推断:塔北隆起8个海相油可能主要来源于塔北轮南地区下奥陶统;塔中隆起3个海相油可能来源于塔中地区中-上奥陶统。     

西藏南部康马岩体岩石类型及其同位素测年

康马岩体位于西藏南部康马县城北侧 ,其内部可划分出 5种不同的岩石类型 :(1)片麻状黑云二长花岗岩 ;(2 )眼球状黑云二长花岗岩 ;(3)片麻状二云母二长花岗岩 ;(4 )弱片麻状细粒黑云二长花岗岩 ;(5 )变质的暗色辉长辉绿岩。前两类为康马岩体的主体岩石类型 ,侵位时代为加里东早期 (约4 78～ 4 6 1Ma) ;其余均呈脉状产出 ,其中片麻状二云母二长花岗岩与康马岩体主体岩石类型属于同期产物 ,弱片麻状细粒黑云二长花岗岩形成于海西早期 ((339.0± 1.2 )Ma) ,暗色辉长辉绿岩的形成时代目前还不十分清楚。不同类型的岩石其Ar Ar冷却年龄约为 18～ 14Ma。