Small-strain dynamic characterization of clayey soil from the Texcoco Lake,Mexico

The area occupied by the former Texcoco Lake was part of a system of lakes inside the Basin of Mexico. The subsoil there has been studied in the past but there is still a need for more and more thorough investigations into the dynamic properties of its highly compressible clays. This paper describes the results of an experimental laboratory research in which a triaxial cell fitted with bender elements was used to measure shear wave velocities (V_s) in clay specimens from the former Texcoco Lake. Soil specimens were subjected to isotropic loading–unloading cycles and values of V_s were determined during the saturation stage and after each stress increment or decrement. Our results show that irrespective of the testing method, shear waves velocities differ in no more than 7–15%.     

贵州开阳白马洞铀矿化岩层地球化学特征

贵州开阳白马洞铀矿是重要的蚀变型铀矿,通过对白马洞清虚洞组黑色蚀变岩及白云岩风化红粘土和寒武系牛蹄塘组黑色页岩的常量元素、微量元素和稀土元素组成的分析研究,发现铀元素含量与Re、Se、Pb、Cu、As、Sb、Tl、Zn、Ni、Mo、Co、S含量为正相关关系,铀含量高,则Re、Se、Pb、Cu、As、Sb、Tl、Zn、Ni、Mo、Co、S含量也高,其中As、Co、Mo、Ni、Re、Tl、Zn、S具有显著的正相关性,而且地表土壤中Se、V、Mo 等元素的富集是铀矿找矿的主要标志之一。根据白马洞清虚洞组、寒武系牛蹄塘组黑色页岩、灯影组硅化白云岩的稀土元素配分模式分析,硒富集和铀矿化矿源层不仅是牛蹄塘组黑色页岩,可能有更深部的矿源存在。认为硒富集区是铀矿找矿远景区域;古代炼汞矿渣富集铀矿,值得开发利用和治理。     

西北沙巴盆地油气成藏模式及勘探方向

以油气地质理论为指导, 在构造、沉积、石油地质特征分析基础上, 从典型油气藏解剖入手, 构建了西北沙巴盆地3种类型的油气成藏模式, 即岩性型、地层型和滚动背斜型油气成藏模式。盆地经历了裂谷期、挤压反转期和拗陷期3个演化阶段, 发育Stage Ⅰ、StageⅡ、StageⅢ、StageⅣ等4套新生代沉积地层。盆地以StageⅣ泥/页岩为主要烃源岩; 有利储集层为由StageⅣC、StageⅣD、StageⅣE砂岩构成的上砂岩单元、由StageⅣA砂岩构成的下砂岩单元及StageⅣC/ⅣD地层滑塌形成的深水浊积砂体; 空间配置方面, 烃源岩与储集体平面相接、空间叠置, 为油气运移成藏提供了有利条件。通过油气富集条件及分布规律的综合分析, 认为"内带"构造区的地层油气藏及"外带"构造区的岩性油气藏是盆地未来的油气勘探重点。      

汉江上游谷地与渭河谷地黄土化学风化程度比较

比较汉江上游谷地及渭河谷地典型黄土剖面的元素组成、化学风化强度及常量元素迁移特征,揭示秦岭南北两侧黄土-古土壤剖面的成壤强度及其所指示的环境演变特征,两者差异及共性如下：① 两剖面化学组成均以SiO₂、Al₂O₃和Fe₂O₃为主,元素组成均一且高度混合,与上部陆地壳（UCC） 的化学成分十分接近,该些证据均指示两区域黄土是来源广泛并经过充分混合的风尘堆积产物。② 据CIA 值可判定MTS 及YHC 剖面均经历了中等风化作用,比较两剖面CIW值、A-CN-K三角图投点特征及元素迁移率知,汉江上游谷地的黄土-古土壤序列经历的化学风化作用更强,Ca 及Na 元素的丢失率更高,Al、Na、Mg、Si 等常量元素的迁出率更大。③ 依据Fe、Na迁移率的全剖面变化曲线知,汉江上游谷地与渭河谷地自全新世以来经历了相同的气候演变阶段,均记录了6000-5000a BP的干冷气候事件。     

荒漠-绿洲交错带土壤N、P、K含量的高光谱反演模型

利用新疆奇台县荒漠-绿洲交错带的75个土壤样本,选取土壤可见光-近红外光谱的反射率（R）、光谱反射率倒数之对数（lg（1/R））、光谱反射率一阶导数（FDR）和光谱波段深度（Depth）4个指标,分析了其与土壤N、P、K元素含量的关系,分别建立了反演模型并对其精度进行了检验。结果表明：可见光-近红外反射光谱快速估算荒漠-绿洲交错带土壤N、P、K元素含量的潜力大,其预测精度由高到低的排列顺序为：N>P>K。不同光谱指标反演模型的精度各异,指标Depth和FDR的预测效果明显优于lg（1/R）和R,对N和P元素的拟合效果为：lg（1/R）相似文献   

碳酸岩与铂族元素地球化学

碳酸岩（carbonatite）被视为一种研究大陆地幔地球化学的“探针岩石”,通过对这类岩石的研究,在探讨地幔组成与演化、地幔交代作用与不均一性以及岩浆形成的动力学背景、岩浆来源及演化和有关矿产的成矿作用等方面,具有重要的理论意义和实际价值。铂族元素（Platinum—group elements,简称PGE）在研究核-幔分异、地幔组成与演化以及幔源岩石（主要为基性-超基性岩）形成的大地构造背景、岩浆起源及演化,以及探讨K／T界线与陨石撞击事件等方面具有重要意义。本文在概述国内外碳酸岩和PGE地球化学研究现状的基础上,结合地质事实和地球化学研究成果,认为碳酸岩熔体具有一定携带PGE的能力,可利用PGE地球化学来探讨碳酸岩的源区特征和岩浆形成与演化过程;同时指出,碳酸岩PGE地球化学研究过程中还存在许多悬而未决的科学问题。     

四川万州中侏罗统上沙溪庙组粘土岩中火山灰的岩矿和地球化学证据

四川盆地东北缘万州地区中侏罗世上沙溪庙组产出稳定层状浅色粘土岩。利用X射线、X荧光光谱、等离子光谱（ICP）等方法对矿物成分、常量、微量和稀土元素进行了测试分析,粘土岩主要矿物为蒙脱石、伊利石和绿泥石。通过与澳大利亚后太古代平均页岩（PAAS）、北美平均页岩（NASC）、地壳粘土岩背景值以及其它具有代表性岩石的对比发现,本区粘土岩微量元素具有明显的低V,低Ti和低铁族元素的特点,高Al2O3／TiO2比值和低Ti／Th比值特征显著,某些层位具有明显的Eu负异常。推断本区粘土岩沉积物源具有火山灰和陆源碎屑的二元混合成因,各层位成分的差异显示了不同沉积时间内二者的混合比例发生变化。区域对比和地球化学资料显示火山灰可能来自于西部600km远的特提斯洋岛弧火山。     

三溴偶氮胂分光光度法测定稀土元素的研究

在1.0 mol/L盐酸介质中,显色剂三溴偶氮胂与稀土元素能发生高灵敏度显色反应,形成稳定的蓝紫色络合物,表观摩尔吸光系数ε_La为1.69×10⁵ L·mol^-1·cm^-1.试剂和络合物的最大吸收波长分别位于525 nm和625 nm.确定了络合物的组成为1:3.在25 mL溶液中,稀土元素在0~17 μg范围内符合比尔定律.本方法受酸度及共存离子影响小,并且有准确、快速、简单的特点.对两个标样做了分析,精密度RSD分别为2.82%和2.57%,准确度RE分别为-2.34%和-5.82%.本方法可不经分离富集,直接用于稀土矿样分析,结果令人满意.     

Geochemical baseline of trace elements in the sediment in Dexing area,South China

A baseline might be used as a point of reference to monitor change from some specific data without concern for whether the baseline determination is natural or has been changed by human activity. We selected 326 sediment samples from Dexing area, South China, and analyzed for 17 chemical elements. The geochemical baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The results indicate Al was the best reference element for the normalization procedure among four potential reference elements (Al, Fe, Ti, and Mn). The baseline value range obtained from the normalization procedure method included both the regional geochemical background of the sediment and the median value of the measured contents. The median value of baselines obtained from relative cumulative frequency method was lower than that obtained from normalization procedure method. In contrast to the geochemical patterns of heavy metals in 1987, the spatial distribution of anomalies sprawled in 2004 in study area, especially for Cu, Pb, Zn, Cd, As, Fe, and Cr.     

Hydrochemical variation in the springs water between Jerusalem–Ramallah Mountains and Jericho Fault,Palestine

The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage and garbage resulting in variable dissolved CO₂ and associated HCO₃ ⁻ concentration. High CO₂ yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO₂ concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks. Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater.