福建平潭青峰老红砂物源示踪分析

本研究分别在平潭青峰、坛南湾和闽江口琅岐岛采集18个老红砂样品、19个海滩砂样品以及40个河滩砂样品,并对这些样品进行粒度和稀土元素(REE)测量。结果发现老红砂与闽江口琅岐岛河口砂的稀土元素含量特征十分接近;分别对老红砂与闽江河口砂REE数据以及坛南湾海滩砂与闽江口砂(REE)进行了判别函数分析,老红砂的∑REE平均值为84.25μg/g,琅岐岛河口砂的∑REE平均值为89.81μg/g,相似性明显;坛南湾海滩砂的∑REE平均值为16.41μg/g,与闽江河口砂含量差别较大。研究表明:青峰老红砂沉积物主要来源于闽江口河口砂,末次间冰期暖湿气候下闽江输砂量增大,河口外沿岸流增强,大量河砂进入海坛海峡,在强劲的季风搬运下,沉积于平潭岛北部,形成以青峰为代表的平潭岛北部老红砂;而坛南湾海滩砂代表海洋波浪搬运的泥沙,不是老红砂的物源。     

面向城市导游的无缝服务研究

智能导游服务已从传统的单一景区导游发展为城市多景区导游,因此,包含了景区间导游和景区内导游两大部分;表现为更加注重面向散客服务、兼容多移动智能终端以应用程序(App)的方式运行。由于景区间导游和景区内导游往往自成系统,在游客进出景区的过程中存在着两种系统的切换,且主要采用手动方式完成,尚没有实现城市多景区导游过程的无缝衔接。为了应对这个挑战,本文设计了一个面向城市多景区的无缝导游服务模式,分析了其架构以及工作机制;并着重讨论了城市无缝导游服务的关键技术,如系统间无缝切换的条件,包含判断游客进入、离开景区等;以及导游服务过程无缝衔接的机制,包含导游动态数据结构的设计,游客游览需求、导游过程状态在多导游系统间的传递等。最后通过实例验证了该方法的有效性,作为新的导游服务模式,同时为动态集成已有的导游App提供了解决方法。     

基于伪语义相似度模型的中文地址匹配方法

地址匹配中,由于传统相似度模型受字符重叠数影响大,在处理简写、缩写地址要素单元时,错误匹配问题突出;深度学习方法需要大量样本支撑,但庞大的数据量和多样的形式,导致生成样本的成本过高。为解决上述问题,本文首先应用基于条件随机场和双向长短时记忆神经网络的模型,对地址进行分词;然后通过建立一种伪语义相似度,对地址要素进行分级匹配。通过对公安业务中地址数据进行测试,在对缩写、简写等不规范地址描述方面,本文模型能较理想地完成任务,各参考指标均高于0.9。     

Chalcophile element partitioning between sulfide phases and hydrous mantle melt: Applications to mantle melting and the formation of ore deposits

Understanding the geochemical behavior of chalcophile elements in magmatic processes is hindered by the limited partition coefficients between sulfide phases and silicate melt, in particular at conditions relevant to partial melting of the hydrated, metasomatized upper mantle. In this study, the partitioning of elements Co, Ni, Cu, Zn, As, Mo, Ag, and Pb between sulfide liquid, monosulfide solid solution (MSS), and hydrous mantle melt has been investigated at 1200 °C/1.5 GPa and oxygen fugacity ranging from FMQ−2 to FMQ+1 in a piston-cylinder apparatus. The determined partition coefficients between sulfide liquid and hydrous mantle melt are: 750–1500 for Cu; 600–1200 for Ni; 35–42 for Co; 35–53 for Pb; and 1–2 for Zn, As, and Mo. The partition coefficients between MSS and hydrous mantle melt are: 380–500 for Cu; 520–750 for Ni; ∼50 for Co; <0.5 for Zn; 0.3–6 for Pb; 0.1–2 for As; 1–2 for Mo; and >34 for Ag. The variation of the data is primarily due to differences in oxygen fugacity. These partitioning data in conjunction with previous data are applied to partial melting of the upper mantle and the formation of magmatic-hydrothermal Cu–Au deposits and magmatic sulfide deposits.I show that the metasomatized arc mantle may no longer contain sulfide after >10–14% melt extraction but is still capable of producing the Cu concentrations in the primitive arc basalts, and that the comparable Cu concentrations in primitive arc basalts and in MORB do not necessarily imply similar oxidation states in their source regions.Previous models proposed for producing Cu- and/or Au-rich magmas have been reassessed, with the conclusions summarized as follows. (1) Partial melting of the oxidized (fO₂ > FMQ), metasomatized arc mantle with sulfide exhaustion at degrees >10–14% may not generate Cu-rich, primitive arc basalts. (2) Partial melting of sulfide-bearing cumulates in the root of thickened lower continental crust or lithospheric mantle does not typically generate Cu- and/or Au-rich magmas, but they do have equivalent potential as normal arc magmas in forming magmatic-hydrothermal Cu–Au deposits in terms of their Cu–Au contents. (3) It is not clear whether partial melting of subducting metabasalts generates Cu-rich adakitic magmas, however adakitic magmas may extract Cu and Au via interaction with mantle peridotite. Furthermore, partial melting of sulfide-bearing cumulates in the deep oceanic crust may be able to generate Cu- and Au-rich magmas. (4) The stabilization of MSS during partial melting may explain the genetic link between Au-Cu mineralization and the metasomatized lithospheric mantle.The chalcophile element tonnage, ratio, and distribution in magmatic sulfide deposits depend on a series of factors. This study reveals that oxygen fugacity also plays an important role in controlling Cu and Ni tonnage and Cu/Ni ratio in magmatic sulfide deposits. Cobalt, Zn, As, Sn, Sb, Mo, Ag, Pb, and Bi concentrations and their ratios in sulfide, due to their different partitioning behavior between sulfide liquid and MSS, can be useful indices for the distribution of platinum-group elements and Au in magmatic sulfide deposits.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Properties of iron alloys under the Earth's core conditions

The Earth's core is constituted of iron and nickel alloyed with lighter elements. In view of their affinity with the metallic phase, their relative high abundance in the solar system and their moderate volatility, a list of potential light elements have been established, including sulfur, silicon and oxygen. We will review the effects of these elements on different aspects of Fe–X high pressure phase diagrams under Earth's core conditions, such as melting temperature depression, solid–liquid partitioning during crystallization, and crystalline structure of the solid phases. Once extrapolated to the inner–outer core boundary, these petrological properties can be used to constrain the Earth's core properties.     

江西武宁县石门寺钨铜矿区风化作用过程中W、Cu等元素的表生地球化学行为(之一)

以江西省武宁县石门寺钨铜矿区燕山期和晋宁期岩体风化作用过程中W、Cu等元素的表生地球化学行为为研究对象,通过反映风化程度的化学风化指数CIA、风化作用过程中组分得失的估算、不同介质中W、Cu等成矿元素的含量变化及大离子亲石元素表生地球化学行为等方法的研究表明,石门寺钨铜矿区2个时期岩体元素淋失与风化强度有关,土壤剖面中碱金属、碱土金属元素大量淋失,而W、Cu等成矿元素在土壤B层中显著富集;从岩石到土壤、再到水系沉积物风化过程中,W、Cu等成矿元素含量逐渐升高,为此,一级水系沉积物和B层土壤是赣北九岭W、Sn、Cu、Mo多金属矿集区地球化学找矿的绝佳采样介质,是矿集区内找矿新突破的有效手段。     

长江经济带土壤质量评价及产地适宜性初步研究

开展土壤质量评价对科学划定永久基本农田及统筹优化农业生产布局具有重要指导意义。本文采用内梅罗综合污染指数法、分级法、累积频率法和综合判定法,参照《土壤环境质量农用地土壤污染风险管控标准》(试行)(GB 15618—2018)和《绿色食品产地环境质量》(NY/T 391—2013),对长江经济带土壤重金属污染、酸碱度、有益元素丰缺和绿色农产品产地适宜性进行评价。研究区土壤质量总体良好,清洁土壤面积34.84万km²,其重金属含量继承了自然背景特征; 三级及以下土壤面积6.94万km²,呈斑块及星点状分布于赣东北、赣南、湖南长沙—郴州一带、沿江及贵阳、昆明等地,其重金属为自然富集或受矿业开发、煤炭和石油的燃烧及工业“三废”排放的影响。酸性土壤面积33.56万km²,分布于江西、湖南、宁波—台州沿海和金华衢州盆地,碱性土壤面积15.69万km²,分布于苏北平原、环洞庭湖、成都平原以及沿长江一线,其土壤酸碱度与土壤类型有关。土壤有益元素丰缺与第四系沉积物成土母质有关,土壤有益元素适量及以上区域面积34.44万km²,分布于四川阿坝、成都盆地、环洞庭湖、环鄱阳湖、安徽沿江、苏北沿海和杭嘉湖平原; 土壤有益元素缺乏区面积13.89万km²,分布于赣南、江淮、鄂东北以及云南玉溪等地。绿色农产品产地最适宜区、适宜区和不适宜区面积分别为22.49万km²、18.78万km²和18.28万km²。依据区内绿色农产品产地适宜性、土壤环境质量和立地条件划分出7片永久农田保护建议区。     

微波消解-电感耦合等离子体质谱测定铜精矿中7种稀有金属元素

准确快速测定铜精矿中7种稀有金属元素（镓铟锗硒碲铊镧）的分布情况对于铜精矿的综合利用及减少技术性贸易壁垒等方面具有重要意义,因锗和铊等目标元素含量低至10^-7级,要求分析方法具有高灵敏度。本文应用微波消解-电感耦合等离子体质谱方法实现了7种稀有金属元素的快速准确测定。以盐酸-硝酸混合酸（体积比3：2）作为样品的微波消解试剂,选取合适的分析质量、调谐仪器及数学校正方程等三种方式消除质谱干扰。在优化的实验条件下,目标元素加标回收率为80.2%~123.3%,相对标准偏差小于13.4%。硒的检出限为1.3 mg/kg,另外6种目标元素的检出限均低于0.08 mg/kg。本法目标元素的检出限均低于电感耦合等离子体发射光谱或原子吸收光谱法测定相应元素的检出限。该方法降低了试剂空白,简化了操作流程,提高了分析灵敏度,实现了铜精矿目标元素的同时分析。     

新疆阿克陶县有色矿石的非金属元素成分分析

岩矿测试和分析更多关注矿石矿物中的金属离子,但其中阴离子及其存在形式的研究对于理解矿石的组成、成因和金属离子的存在状态具有重要意义。本文采用红外光谱、X射线电子能谱和热重分析等方法对新疆阿克陶县奥依塔克镇的有色矿石中非金属元素进行成分分析。研究结果表明,矿石含有H、C、O、Si等非金属元素,主要以—C—O、C═O、Si—O—C和Si—O阴离子的形式存在,并与Mg、Al、Ca等主要金属元素形成γ-Al2O3、CaO·SiO2、MgCO3、CaCO3等化合物。样品煅烧到900℃,导致样品损失水分并使其中的MgCO3发生分解,而CaCO3不分解,分解产生的MgO与Si—O结合生成MgO·SiO2,表明矿石主要含有碳酸盐和硅酸盐,是具有白云石矿石特性的混合型矿石。