Rock Mass Characteristics in Beishan, A Preselected Area for China’s High-Level Radioactive Waste Disposal

Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China’s high-level radioactive waste (HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and 4) a synthesis index, Joint Structure Rating (JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China’s HLW disposal repository site.     

Geochemical Characteristics of Wuyang Siliceous Rocks in the Southern Margin of North China Craton and its Constraint on the Formation Environment of BIF of Tieshanmiao Formation

Precambrian banded iron formation(BIF) is one of the most important mineral resources in China, mostly abundant in the North China Craton(NCC) with relatively less common in South China. Since the BIF and siliceous rocks both originated from chemical deposition, the syngenetic BIF and Siliceous rocks can help evaluate their environment of formation. We examine here the mineralogy and geochemistry of siliceous rocks associated with the Tieshanmiao Formation BIF, aiming to decipher the conditions of formation of both BIF and Siliceous rocks in the Wuyang area in the NCC. Analysis of the geochemical characteristics of whole rock shows that the Si O2 content of the siliceous rock ranges from 90.11% to 94.85% and is relatively high overall. Trace element contents of Ba and U are also high, the Ba/Sr ratio ranges from 3.89 to 25.28 and the U/Th ratio ranges from 0.09 to 0.20. Finally, the ΣREE value of rare earth elements ranges from 57.03 ppm to 152.59 ppm, and these indexes all indicate that siliceous rock resulted from hydrothermal deposition. Plots of Al2 O3-Si O2, Si O2/(K2 O+Na2 O)-Mn O2/Ti O2 and Mn-10×(Cu+Co+Ni)-Fe in discrimination diagrams also verify this interpretation. However, both the Mg O content, ranging from 0.16 to 0.32, and the Fe/Ti ratio, ranging from 2.50 to 9.72, suggest that terrigenous material was added during the depositional process. Major and trace element parameters of siliceous rock, such as the Al/(A1+Fe+Mn) ratio(from 0.81 to 0.93), Mn O/Ti O2(from 0.00 to 0.17), Al/(Al+Fe)(from 0.82 to 0.93), Sc/Th ratio(from 0.21 to 0.50), U/Th(from 0.09 to 0.20),(La/Yb)N(from 0.83 to 3.04), and the(La/Ce)N(from 0.01 to 0.02) all imply that the siliceous rock formed in a continental margin. In addition, the Sr/Ba ratio from 0.08 to 0.26, the δCe value from 0.31 to 0.90, and the δEu value from 0.14 to 0.58, all indicate that the siliceous rock was formed at a relatively deeper water depth and under weak hydrodynamic conditions. Siliceous rock and BIF formed in the same geological setting, with the Si O2/(K2 O+Na2 O) ratio of siliceous rock ranging from 28.61 to 47.43, the Si O2/Al2 O3 ratio from 16.53 to 32.37, and the Si O2/Mg O ratio from 287.28 to 592.81, which are all in agreement with chemical deposition associated with volcanic eruptions. The Al2 O3/Ti O2 ratio from 37.82 to 50.30 indicates that the magma source of siliceous rock was of slightly intermediate composition. During the Late Archean in the Wuyang area, the high concentration and high purity Si O2 quickly precipitated from hydrothermal fluids to finally result in the accumulation of siliceous rock in a marginal sea, while the input corresponding to iron formation components was deposited to form iron formation layers, and limestone was only the product formed during the deposition intervals of siliceous rock and iron formations. In this study, the synsedimentary siliceous rocks of BIF act as a new way to provide direct evidence to understand the formation environment of BIF due to its high geochemical stability.     

济南西北部碳酸盐岩热储浅埋区热异常机理研究

为了探寻济南岩体北部碳酸盐岩热储浅埋地热异常区形成机理,利用地质钻探编录、抽水试验、测温、水质分析测试等手段,对碳酸盐岩浅埋地热异常区地质特征、热储物性特征、地温场特征、水化学特征等进行研究,结果表明：碳酸盐岩浅埋区热储层发育在奥陶纪灰岩地层中,热储层岩溶裂隙发育,热储埋深150~1000m,地热异常区盖层地温梯度为7. 2~11. 5℃/100m,水化学类型为SO4- Ca型,TDS为1. 3~1. 5g/L,地热水中含有对人体有益的微量元素,地热水来源为大气降水,地热水中50年以前入渗的“古水”占主导;明确了热源除正常的地温传导之外,济南岩体阻挡迫使水流深循环加热后上涌,断裂沟通深部热源等也是地热异常区形成的重要因素。     

动能歧视模式ICP-MS测定地球化学样品中14种痕量元素

应用传统ICP-MS法测定勘查地球化学样品中Ag、Cd等痕量元素,基体效应和多原子离子干扰严重,准确测定的难度较大。本文基于当前ICP-MS消除干扰技术,分析了ICP-MS标准模式(STD)及动能歧视模式(KED)测定地球化学样品中Ag、Cd等14种痕量元素的有效性,通过比较这两种模式的测定效果,在此基础上确定了各元素的有效测定模式。结果表明:在KED模式下,基体元素如Zr、Nb氧化物的产率降低,基本上消除了Zr、Nb氧化物对痕量元素Ag、Cd的多原子离子干扰。KED模式提高了信噪比,降低了方法检出限,如Ag、Cd的检出限分别为0. 004mg/kg、0. 005mg/kg,其他12种元素的检出限也低于多目标地球化学调查76种元素分析方案中的检出限。测定痕量元素的准确度显著优于STD模式。实验中采用简单的硝酸-氢氟酸-高氯酸消解样品,残渣用王水复溶,结合KED模式下优选出干扰较小的同位素作为测定同位素,以Rh作为内标校正仪器产生的信号漂移,将样品溶液稀释至1000倍,基体效应降低至最小。本方法经国家一级标准物质的验证,测定结果与认定值相符,可为勘查地球化学提供高质量数据。     

云南省石漠化区耕地休耕对策研究

我国石漠化得到初步遏制的同时,发生在耕地上的石漠化面积却在增加。石漠化区的云南省和贵州省是我国休耕制度试点区域之一,但传统的石漠化治理缺乏休耕环节,耕地利用方式未能实现根本转型。基于休耕试点区域的实地调研,总结概括了云南省休耕试点工作的主要特点:（1）因地制宜整片推进;（2）签订休耕协议强化约束;（3）政府与农户联动落实休耕区域和面积;（4）休耕培肥方式元化化;（5）与农业结构调整对接;（6）与经济社会发展相统筹。但云南休耕试点也存在一些问题,主要是:（1）休耕区域的选择存在主观性;（2）配套资金缺口大;（3）休耕补助大幅减少造成群众心理落差;（4）休耕工作队伍建设薄弱。基于以上问题,建议:（1）建立休耕地诊断识别技术体系,明确休耕的规模和时序安排;（2）加强涉农项目和资金整合,增加配套资金投入,缓解基层财政压力;（3）建立动态的、反映土地市场价格的休耕补助机制,优化补助方式;（4）充实完善基层休耕组织机构,加强基层休耕工作队伍建设;（5）加快休耕监测体系建设,适时开展休耕制度运行绩效评估。      

西南地区某岩溶水库渗漏分析

西南地区某水库位于云贵高原中北部,库区可溶盐岩分布较广且岩溶较发育,中部有一条近南北走向的区域性断裂（F1）穿过两岸,为论证此水库成库的可能性,通过地表调查及物探,结果表明:此水库向低邻谷渗漏的可能性小,沿F1断裂带向南部或向下游渗漏的可能性问题不大,存在沿灰岩溶蚀通道向下游和向库外渗漏的可能性,沿左岸大理岩与灰绿岩接触带或大理岩向坝下游绕坝渗漏的可能性不大;水库正常蓄水位在Kc1底板高程以下有成库的可能。      

吉林省红旗岭矿区7号岩体群地质特征及对地质找矿的指导意义

红旗岭矿区的南东部存在7、32、33号三个岩体,一般统称为7号岩体群。7号岩体是矿区发现含铜、镍矿最大的岩体,32与33号岩体分布在7号岩体的北西部。通过对这三个岩体的地质特征进行分析,利用3Dmine软件建模技术,对三个岩体、岩相、矿体建立三维模型。对模型进行观察、分析,结合成岩成矿地质理论,发现三个岩体是由来自7号岩体的南东部深部岩浆源生成的,岩浆由7号岩体的南东部深部向北西方向侵入,地质历史上三个岩体是一个大岩体,只是经过长期的风化剥蚀和地质构造改造形成目前的3个岩体,显示7号岩体的南东部深部具有找矿潜力。     

综合物探法在小秦岭地区中酸性岩体圈定及空间解析中的应用

蟒岭地区西部地处秦岭腹心,位于不同构造单位结合处,构造变动剧烈,岩浆活动频繁,多数矿产与中酸性岩体息息相关。综合物探工作通过地面高精度磁测、激发极化法和高精度重力测量三种地球物理综合测量方法,开展了研究区的磁场、重力场、极化率和电阻率的分布特征研究。深入分析了地质和地球物理特征的异同,并结合物性工作总结了中酸性岩体与地层的差异,了解了深部隐伏岩体的信息,圈定了岩体在地表的位置,推断出地下深层空间的地质结构,为进一步查找岩体以及其他与之有关的工程勘查活动提供借鉴,为该地区及类似地质背景下隐伏岩体定位预测提供了可靠的方法。     

北秦岭双龙-夏馆地区大面积榴闪岩的发现及锆石U-Pb年代学研究

通过详细的野外地质调查,在北秦岭双龙-夏馆地区精确圈定出大面积榴闪岩,榴闪岩常以似层状、条带状、豆荚状和透镜状产于秦岭岩群郭庄岩组混合片麻岩内,空间上可划分三个带:南带与松树沟一带的麻粒岩构成一个较宽的高压-超高压变质带,北带则与官坡-双槐树一带的榴辉岩构成一线,而中带向西可能延伸至丹凤大寺沟一带。区内榴闪岩主体受秦岭岩群郭庄岩组的展布形态控制,呈面状遍布于整个郭庄岩组内,而非局限于某一侧或两侧,暗示秦岭岩群可能整体卷入早古生代的俯冲和碰撞作用。野外宏观特征、岩相学及锆石U-Pb年代学研究表明榴闪岩原岩为辉长岩,成岩年龄为654.1±5.6Ma、656.1±6.7Ma,获得峰期高压麻粒岩相变质年龄为472.9±6.0Ma、485.0±33.0Ma,其后分别在455.4±9.0Ma、416.7±1.9Ma和401.1±6.2Ma遭受了多期次退变作用的叠加。结合区域研究成果,初步认为北秦岭高压-超高压基性岩石的原岩至少存在于新元古代中期和晚期,其成岩时代分别与扬子地块北缘新元古代中、晚期的镁铁-超镁铁质岩床群一致,并具有相似的地球化学特征,而两者是否为同一大地构造背景下的同期侵位的产物,尚待进一步研究。     

黄骅坳陷新生界火成岩岩相与储集性能分析

通过取芯段火成岩岩芯观察、测井以及地震相分析,将黄骅坳陷新生界火山岩划分为爆发相、溢流相、火山通道相和火山沉积相4种,并根据储集空间特征进一步划分为10种亚相,将侵入岩划分为3个相带。在此基础上建立黄骅坳陷火成岩岩相模式,并分析不同岩相火成岩的储集性能。研究认为：研究区溢流相上下区亚相和爆发相储集物性优越,构造裂缝和原生气孔发育,气孔、溶蚀孔缝、构造缝为主要储集空间;侵入相和次火山岩相火成岩由于热液作用造成围岩发生变质,原岩结构构造发生变化,使原来孔渗条件极差的泥岩变质为具有一定储集性能的储集岩;主要储集空间为收缩裂隙和构造裂隙。