XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.     

Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.     

灌丛对川西北高寒草甸土壤资源的影响

以川西北高原红原县为研究区,用方格取样法,在相邻的高寒灌丛草地和高寒草甸样地中分别随机取0~20 cm土样50个,并分析了这些土样的土壤性状。利用SPSS(11.0)软件对实验数据进行了统计、分析和比较,研究了两个样地的各种土壤养分的平均含量、空间异质性和相关关系。结果表明,草甸样地的粘粒含量、Ptotal、Ntotal、ORG、Pavail、Navail、Kavail的含量都高于灌丛样地,且两样地速效养分差异极显著,但草甸样地土壤的ORG、Navail、Kavail的变异系数(CV)却明显小于灌丛样地,特别是Kavail的CV值,灌丛样地比草甸样地高出了53.37%;相关分析还表明,相对于草甸,灌丛样地中各养分元素之间的相关性明显增强。说明灌丛对高寒草甸土壤资源的异质性有明显的影响,其存在降低了草甸土壤养分的均值含量并增强了土壤养分的变异性和侵蚀潜力,不利于高寒草甸土壤养分的保持。     

Asking the right questions: environmental conflict in the case of Azerbaijan

This paper contributes an empirical test of key themes of the literature on natural resource conflict. Survey and interview data from an ongoing project in Azerbaijan provide insights into an unexpected lack of conflict in Azerbaijan related to the environment, resources and energy despite the predictions of resource conflict literature. We contend that questions about public perceptions about the environment and other daily concerns are critical if we are to understand who is likely (or unlikely) to be involved in conflict and why. The data presented in this paper demonstrate that Azerbaijani citizens rank environmental and resource issues among their immediate concerns and their top concerns for the country. However, compared to other day-to-day concerns such as the Nagorno-Karabakh conflict and economic concerns, environment-related concerns do not appear to be sufficient to motivate widespread violent conflict or citizen dissent related to environmental or natural resource conditions.     

河北省邯邢东部平原区（冀南凹陷）地热资源的利用与开发

邯邢东部平原区温增温率3℃／100m，被任为是不宜开采利用的“非地热异常区”。但近几年来在该区已成功施工了井深1500～1800m的探采结合地热井拾余口，井口出水温度达50℃以上，证实了邯邢东部平原区地热开发利用前景广阔。根据该区域地热条件背景及地热资源赋存特点，结合该区近几年地热探采施工体会，对地热井成井工艺和合理开发利用地热资源的提出了有益见解，对类似平原区地热资源的开发利用具有一定的启发和借鉴意义。     

推进煤矸石资源化利用的对策建议

煤矸石是我国排放量和堆存量最大的工业固体废弃物之一，但又是可以利用的资源，只要加以资源化利用，就能会变废为宝。在研究我国煤矸石综合利用现状的基础上，指出了煤矸石综合利用中存在的主要问题，从制定规划、完善经济政策、加强法制建设等方面提出了加快推进煤矸石资源化利用的建议。     

河北省煤炭资源勘查及开发现状

河北省含煤面积广，煤类齐全，从晚古生代到新生代共有6个聚煤期，是我国主要产煤省之一，根据河北省煤炭资源特征、开发利用情况，指出目前河北省煤炭工业发展中存在的诸如探采比例失调、新建井基地严重不足、后备资源不足等的问题，以及加强煤炭资源管理的建议。     

张家口地下热水资源成因探讨

张家口地热资源丰富，通过对区内地热成矿机制，成矿规律的分析认为，以祁吕系为主的多构造体系复合部位控制了本区地下热水的形成与分布，本区地下热水是大气降水经深循环而成，经计算深循环的深度达为2600m，张家口南部地区有很多个热水异常点，是具有远景意义的地热区。