1991—1992年ENSO事件的特征

根据美国国家海洋大气局气候分析中心（ＣＡＣ）和中国气象局气候监测公报所提供的海－气资料，综合分析了１９９１－１９９２年ＥＮＳＯ事件的形成、发展过程。这次ＥＮＳＯ事件的主要特点是：①在ＥＮＳＯ事件爆发前一年内热带太平洋海气特性频频呈现异常，暖水堆积在赤道中太平洋（５°Ｎ－５°Ｓ，１６０°Ｅ－１６０°Ｗ）约１２个月，然后自西向东传输，爆发１９９１－１９９２年ＥＮＳＯ事件。②对ＥＮＳＯ事件作出响应的西太     

绿砷钡铁石在广西的发现

本文研究了在广西德保铜锡矿床氧带化中发现的绿砷钡铁石,给出了它的物理性质、化学成分和晶胞参数等矿物学数据。     

我国大陆及其邻区6级以上地震的“缺震事件”——一种大地震中期预测指标的分析研究

在内陆强震活动的起伏中,6级以上地震的大范围长时间缺震,具有重要的意义。有的研究者已将其作为将发生7级地震前的标志之一。作者系统地清理了1897—1988年8月间中国大陆及其邻区6级以上地震“缺震事件”的始末,较多的震例表明,限定“缺震事件”起止的地震具有中期预报意义。它们在地震构造上的原因可能是代表区域最活跃的破裂,突然处于阻碍、闭锁状态,其持续时间大于10个月,再次发生6级以上地震为解锁,并随即出现新的一轮大地震活动。故可以作为一种大地震中期预测的指标。     

三道溜河地区太古宙岩浆－构造事件

三道溜河地区处于中朝准地台北东缘，北西起自著名的夹皮沟金矿，南东至四道砬子河，太古宇出露广泛。笔者在此进行１：５万区调时，共发现了六次岩浆－构造事件，由老至新依次为：７８７角闪辉石岩、岭东片麻岩、大朝阳沟斜长角闪岩、三道溜河ＴＴＧ岩组、唐胡店沟二长花岗岩、五道砬子河变辉长辉绿岩（发生在元古宙早期，在时空上与太古宇关系密切）。上述事件，表现为基性岩类与酸性岩类交替出现。基性岩事件依次为超基性岩－基性岩－偏碱性基性岩，稀土元素总量由高至低，微量元素Ｂａ、Ｍｎ、Ｚｒ递增，Ｐｂ、Ｚｎ递减。酸性岩事件依次为中酸性岩－酸性岩－偏碱性酸性岩，稀土元素的Ｌａ／Ｌｕ、ΣＣｅ／ΣＹ由低到高，总量变化不大，微量元素Ｃｏ、Ｃｒ、Ｎｉ、Ｃｕ递减。本区的构造运动与岩浆侵入活动相辅相成，古穹窿构造及北西向韧性剪切带控制了Ａｕ、Ａｇ、Ｃｕ等矿产的展布。     

中国大陆8级巨震生成背景研究

中国大陆８级巨震群体活动的盛衰起伏，紧随全球整体活动的变化而变，并明显地受到太阳活动长期变化的调制。就个体巨震孕育而言，其供能机制可造成周围数千公里构造应力场持续多年的剧烈增强。因此，对于震级为８级的巨大地震的预测问题，必须在极为广阔的研究视野中探讨。     

关于太古宙—元古宙界线的新认识

２５００Ｍａ作为太古宙－元古宙界线的提议被２８届国际地质大会通过，但并不意味着２５００Ｍａ作为太古宙－元古宙界线是永恒的最佳选择。事实上，太古宙－元古宙界线划在何处还存在很多争论，现行的界线划分依据也期分期标准相悖。大量资料表明），２３００Ｍａ时曾发生全球地质环境的灾变，灾变前后的地质作用（尤其是表生地质作用），有明显变化，导致了太古宙与元古宙的一系列差别。该灾变与元古宙－显生宙，古生代－中生代，     

Structural relationships between a brown coal and its kerogen and humic acid fractions

A South Australian Tertiary brown coal is fractionated into humic acid and kerogen fractions. These related samples are then subjected to a number of different analytical techniques including infrared and¹³C-Nuclear Magnetic Resonance spectroscopies and pertrifluoroacetic acid oxidation. Structural conclusions are drawn from an integrated consideration of the data. Brown coal aliphatic structure is concentrated in the kerogen and the solvent soluble polar acid fractions. The humic acids are the most aromatic and contain a high degree of hydrogen bonding. Only very minor amounts of long polymethylene chain structures are observed in the humic acids, in complete contrast to the kerogen fraction. Different organic detrital origins are proposed for the coal fractions.     

Importance of the oxidation/maturation pair in the evolution of humic coals

The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO₂ and H₂O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena.     

Methoxy formation in the reaction of CH3O2 radicals with NO

Formation of methoxy (CH₃O) radicals in the reaction (1) CH₃O₂+NOCH₃O+NO₂ at 298 K has been observed directly using time resolved LIF. The branching ratio % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaeqOXdyMaae% 4qaiaabIeadaWgaaWcbaGaae4maaqabaGccaqGpbGaaeiiaiaabIca% ieqacaWF9aGaa8hiaiaa-nbicaWFGaGaeuiLdqKaai4waiaaboeaca% qGibWaaSbaaSqaaiaabodaaeqaaOGaae4taiaac2facaWFVaGaeuiL% dqKaai4waiaaboeacaqGibWaaSbaaSqaaiaabodaaeqaaOGaae4tam% aaBaaaleaacaqGYaaabeaakiaac2facaqGPaaaaa!4E31!\[\phi {\rm{CH}}_{\rm{3}} {\rm{O (}} = -- \Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}]/\Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}_{\rm{2}} ]{\rm{)}}\] has been determined by quantitative cw-UV-laser absorption at 257 nm of CH₃O₂ and CH₃ONO, the product of the consecutive methoxy trapping reaction (2) % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaae4qaiaabI% eadaWgaaWcbaGaae4maaqabaGccaqGpbacbeGaa83kaiaa-bcaieaa% caGFobGaa43taiaa+bcacaGFOaGaa83kaiaa+1eacaGFPaGaa4hiai% abgkziUkaabccacaqGdbGaaeisamaaBaaaleaacaqGZaaabeaakiaa% b+eacaqGGaGaaeOtaiaab+eacaqGGaGaa4hkaiaa-TcacaGFnbGaa4% xkaiaa+5cacaGFGaGaa4hiaiabeA8aMnaaBaaajqwaacqaaiaaboea% caqGibWaaSbaaKazcaiabaGaae4maaqabaqcKfaGaiaab+eaaSqaba% aaaa!55AC!\[{\rm{CH}}_{\rm{3}} {\rm{O}} + NO ( + M) \to {\rm{ CH}}_{\rm{3}} {\rm{O NO }}( + M). \phi _{{\rm{CH}}_{\rm{3}} {\rm{O}}} \] is found to be (1.0±0.2). The rate constant k ₁ is (7±2) 10^-12 cm³/molecule · s in good agreement with previous results.