广西大瑶山东南缘侏罗纪埃达克质花岗岩的特征、成因及构造意义

对钦杭结合带西南段大瑶山东南缘的中晚侏罗世埃达克质花岗岩（165~153 Ma）进行了岩石学、地球化学研究,并探讨了埃达克质和TTG岩类的特征属性。岩石SiO₂含量63.76%~72.13%,总体具高Al₂O₃（Al₂O₃≥15%）、低MgO （<3%）,亏损重稀土元素（HREE）、正Eu异常或弱的负Eu异常,低Y （≤18×10^-6）和Yb （≤1.9×10^-6）,高Sr （>300×10^-6）和Sr/Y值（>20）等埃达克岩独特的地球化学特征。结合区域构造演化分析认为,该侏罗纪埃达克质花岗岩形成于陆内伸展构造背景,为大陆板内加厚（隆起区）的下地壳底部岩石部分熔融的产物,属大陆板内环境I型花岗岩。具有类似于低镁安山岩/闪长岩系列（LMA）和镁安山岩/闪长岩系列（MA）两种高压型TTG亚类的属性,为古俯冲增生带下地壳弧型岩石熔融的继承性特征,与中生代古太平洋俯冲板片熔融过程无关,属非俯冲成因的埃达克/TTG岩类。其空间上与大瑶山东南缘早古生代俯冲增生带高度重合,且与早古生代TTG侵入岩组合紧密相邻,提示它们可能源自于早古生代洋壳俯冲带或大陆边缘弧下地壳玄武质岩石的部分熔融,因而具有洋俯冲成因的特征属性。     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。     

中亚造山带南缘中—新元古代地壳的揭示——来自北山—阿拉善北部钻遇碱性花岗岩的年代学和Hf同位素示踪研究

前寒武纪微陆块是北山—阿拉善北部增生造山带的重要组分,旱山、雅干和珠斯楞—杭乌拉地区的前寒武纪基底是否存在学界尚存争议.居延海介于北山造山带北部和阿拉善地块北缘的构造衔接部位,受限于巴丹吉林沙漠覆盖,岩石露头极少,我们通过钻井工程,钻遇一套晚石炭世碱性花岗岩,锆石U-Pb年龄和Hf同位素特征揭示,该花岗质岩浆锆石结晶年龄为(312±1)Ma(MSDW=0.46,n=18)和(315±2)Ma(MSWD=0.93,n=15),具有正的εHf(t)值,介于+0.8～+4.4之间,平均值为+2.2,对应二阶段模式年龄TDM2为1048～1267 Ma,平均值为1183 Ma,具有古老地壳的源区属性.通过与旱山构造带、雀儿山构造带、雅干构造带和珠斯楞—杭乌拉构造带的晚石炭世花岗质岩浆对比分析,结合旱山构造带、雅干构造带和珠斯楞—杭乌拉构造带0.9 Ga花岗质岩石的出露以及区域上的重磁资料解译,我们认为旱山、雅干和珠斯楞—杭乌拉构造带存在中—新元古代地壳,且可开展进一步的衔接关系研究.     

河北阜平地区太古宙变质深成岩与金矿的关系初探

区内变质深成岩由阜平岩群变质表壳岩经深部重熔作用形成,典型特征是低钾富钠,具有TTG岩石特点.经对变质深成岩成矿元素的研究表明:①Au元素丰度值很高(平均2.10×10-6),远远高于世界中性-中酸性侵入岩及地壳中Au元素的丰度值;②Au元素浓集克拉克值(488.37)远远大于1,呈非常强的富集状态;③Au元素在变质深成岩中的变异系数(0.65)几乎是区内变质表壳岩中Au元素的2倍,有利于Au元素的聚集成矿.故变质深成岩应是成矿物质的主要提供者.     

Single Zircon LA-ICP-MS U-Pb Dating of the Guandimiao and Wawutang Granitic Plutons in Hunan, South China and Its Petrogenetic Significance

1 Introduction The South China Block (SCB), located between the Qinling-Dabie and Songma Indosinian sutures, experienced successively two important tectonic movements during the Mesozoic, i.e. the Indosinian movement (early Mesozoic) and the Yanshanian movement (late Mesozoic). Therefore, the generally accepted viewpoint is that the key geological problems during the Mesozoic are essentially the dynamics and material expression of these two tectonic movements in South China (Chen et al.…     

柴北缘元古宙鹰峰环斑花岗岩及其共生岩石的地球化学特征、成因及地质意义

中元古代鹰峰岩体的主体是环斑花岗岩,与其共生的岩石有石英闪长岩-奥长花岗岩和辉绿岩。环斑花岗岩高碱（Na2O＋K2O=8.49%～9.39%）、富钾（K2O/Na2O=1.12～1.43）,铝近饱和,高铁镁比值[（ΣFeO）/MgO=4.91～7.19];富Rb、Ba、Ga、Th、Zr、Nb、Ta,贫Cr、Ni、V;高ΣREE（392.24×10-6～594.76×10-6）,稀土元素强分异[（La/Lu）N=12.67～17.09],弱铕负异常（δEu=0.58～0.78）,显示碱性花岗岩的特征,与密云环斑花岗岩相似。石英闪长岩-奥长花岗岩具钙碱性系列岩石的特征;与环斑花岗岩相比,其Rb、Ba、Ga、Nb、Ta、Th、Hf、Zr低,而Ni、Cr、V高;ΣREE较低（ΣREE=77.04×10^-6～129.85×10^-6）,轻重稀土分异明显,但（La/Lu）N的比值较小（11.62～14.06）,铕异常更弱（δEu=0.69～0.93）。辉绿岩具低碱、高ΣFeO的特征,属拉斑玄武质,与洋中脊拉斑玄武岩相比,K2O等不相容元素高,具大陆拉斑玄武质的特征。辉绿岩的ISr（1776Ma）为0.7066,εNd（1776Ma）为＋3.6,环斑花岗岩的ISr（1776Ma）为0.7181,εNd（1776Ma）为-5.5,显示辉绿岩起源于年轻的地幔,花岗质岩浆主要源自古老的地壳。综合分析显示,这些侵入岩形成于伸展背景,是北半球中元古代非造山环斑花岗岩的成员之一,在加里东期卷入到柴北缘造山带的古老地壳中。这在世界上提供了一个古老克拉通及环斑花岗岩卷入古生代造山带的一个实例。     

Regional variations in cleavage and fold development in North Wales

The arcuate pattern of the main Caledonian cleavage and associated fold axial plane traces in North Wales is due partly to NW-SE compression with tectonic transport to the southeast against the concealed crop of the Tan y grisiau Microgranite. Low-angle cleavage close to the microgranite is shown to be a local variant of the regional cleavage formed during the main deformation and not an earlier phase as previously supposed. Transcurrent movements along several major fault systems are also related to compression around the microgranite and the Harlech Dome block.     

Geochemistry and Petrogenesis of Late Ediacaran Rare-metalAlbite Granites of the Arabian-Nubian Shield

The Abu Dabbab albite granite(ADAG), in the central Eastern Desert of Egypt, hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield. Here, we report detailed field,petrographic, mineralogical and geochemical investigation of the ADAG, an isolated stock-like granitic body with sharp intrusive contacts against metamorphic country rocks, probably emplaced at about 600 Ma. The fine-grained porphyritic upper unit is a preserved remnant of the shallowly-emplaced apex of the magma chamber, whereas the medium-grained lower unit crystallized at deeper levels under subvolcanic conditions. The peraluminous leucocratic ADAG shares common geochemical characteristics with post-collisional intraplate A-type magmas. In addition to the conspicuous enrichment in Na2 O, the ADAG is remarkable for its anomalous concentrations of Ta, Nb, Li, Hf, Ga, Sn, Zn and heavy rare-earth elements. Nb-Ta minerals in the ADAG are mixed with Fe-Mn oxides, forming black patches that increase in abundance toward of the base of the intrusion. Columbite-tantalite, cassiterite and wolframite are the most important ore minerals.Pronounced negative Eu anomalies(Eu/Eu* = 0.10–0.24) reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interaction. The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness. Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes, late-stage metasomatism caused limited redistribution of rare metals. Fluid-driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen, amazonite, and quartz veins along fracture systems.     

兴安地块南段晚泥盆世包格德岩体时代的厘定及地质意义

中亚造山带东端兴安地块南段的包格德岩体由石英二长岩、二长花岗岩和花岗斑岩3种岩性组成,岩体锆石LA-ICP-MS U-Pb定年结果分别为368±+1 Ma、364±1 Ma、355±1 Ma,为晚泥盆-早石炭世岩浆活动的产物;岩体的(Na2O+K2O)含量为7.62％～8.82％,K2O/Na2O值为0.93～4.21...